全文获取类型
收费全文 | 158638篇 |
免费 | 18274篇 |
国内免费 | 14381篇 |
专业分类
化学 | 72613篇 |
晶体学 | 1136篇 |
力学 | 5883篇 |
综合类 | 669篇 |
数学 | 12622篇 |
物理学 | 39650篇 |
综合类 | 58720篇 |
出版年
2024年 | 679篇 |
2023年 | 2695篇 |
2022年 | 4536篇 |
2021年 | 5039篇 |
2020年 | 4832篇 |
2019年 | 4246篇 |
2018年 | 4237篇 |
2017年 | 3918篇 |
2016年 | 5708篇 |
2015年 | 6210篇 |
2014年 | 8075篇 |
2013年 | 9654篇 |
2012年 | 11384篇 |
2011年 | 11694篇 |
2010年 | 8848篇 |
2009年 | 8786篇 |
2008年 | 9444篇 |
2007年 | 8708篇 |
2006年 | 7950篇 |
2005年 | 7112篇 |
2004年 | 5451篇 |
2003年 | 4685篇 |
2002年 | 4505篇 |
2001年 | 4167篇 |
2000年 | 3654篇 |
1999年 | 4719篇 |
1998年 | 3984篇 |
1997年 | 3810篇 |
1996年 | 3669篇 |
1995年 | 3153篇 |
1994年 | 2875篇 |
1993年 | 2350篇 |
1992年 | 2073篇 |
1991年 | 1889篇 |
1990年 | 1553篇 |
1989年 | 1391篇 |
1988年 | 1072篇 |
1987年 | 755篇 |
1986年 | 580篇 |
1985年 | 341篇 |
1984年 | 207篇 |
1983年 | 156篇 |
1982年 | 126篇 |
1981年 | 78篇 |
1980年 | 59篇 |
1979年 | 26篇 |
1978年 | 22篇 |
1976年 | 24篇 |
1975年 | 22篇 |
1957年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
介绍了一种新型钢筋冷拉机的工作原理和主要参数:变形速度V△L、单位时间伸长率ε、送进速度V2、冷拉速度V1及其之间的关系.这种冷拉机具有生产率高、冷拉质量稳定等特点. 相似文献
32.
33.
本文研究执防护发汗冷却控制中的自由边界解的存在性、唯一性,应用算子半群方法得出了解的存在性、唯一性,所用的方法对一般非线性、抛转型偏微分方程和高维情形也适用. 相似文献
34.
Zi‐Cai Li Tzon‐Tzer Lu Hung‐Tsai Huang Alexander H.‐D. Cheng 《Numerical Methods for Partial Differential Equations》2007,23(1):93-144
In this article we survey the Trefftz method (TM), the collocation method (CM), and the collocation Trefftz method (CTM). We also review the coupling techniques for the interzonal conditions, which include the indirect Trefftz method, the original Trefftz method, the penalty plus hybrid Trefftz method, and the direct Trefftz method. Other boundary methods are also briefly described. Key issues in these algorithms, including the error analysis, are addressed. New numerical results are reported. Comparisons among TMs and other numerical methods are made. It is concluded that the CTM is the simplest algorithm and provides the most accurate solution with the best numerical stability. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2007 相似文献
35.
We develop a lattice-dynamical model based on the screw symmetry of single-walled carbon nanotubes that allows for reducing the size of the dynamical matrix to six, for all tube chiralities. The model uses force constants derived from fitting to the phonon dispersion of 2D graphite. We present the calculation procedure in a clear and transparent way, making the model easier to follow. We calculate the phonon dispersions of a number of nanotubes of different chiralities. The splitting of two highest Raman active modes and the radial breathing mode frequency are studied by changing the tube diameter and chirality. 相似文献
36.
Ke Sha Dongshuang Li Yapeng Li Xiaotian Liu Shuwei Wang Jingqi Guan Jingyuan Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5037-5049
Amphiphilic diblock copolymer polycaprolactone‐block‐poly(glycidyl methacrylate) (PCL‐b‐PGMA) was synthesized via enzymatic ring‐opening polymerization (eROP) and atom transfer radical polymerization (ATRP). Methanol first initiated eROP of ?‐caprolactone (?‐CL) in the presence of biocatalyst Novozyme‐435 under anhydrous conditions. The resulting monohydroxyl‐terminated polycaprolactone (PCL–OH) was subsequently converted to a bromine‐ended macroinitiator (PCL–Br) for ATRP by esterification with α‐bromopropionyl bromide. PCL‐b‐PGMA diblock copolymers were synthesized in a subsequent ATRP of glycidyl methacrylate (GMA). A kinetic analysis of ATRP indicated a living/controlled radical process. The macromolecular structures were characterized for PCL–OH, PCL–Br, and the block copolymers by means of nuclear magnetic resonance, gel permeation chromatography, and infrared spectroscopy. Differential scanning calorimetry and wide‐angle X‐ray diffraction analyses indicated that the copolymer composition (?‐CL/GMA) had a great influence on the thermal properties. The well‐defined, amphiphilic diblock copolymer PCL‐b‐PGMA self‐assembled into nanoscale micelles in aqueous solutions, as investigated by dynamic light scattering and transmission electron microscopy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5037–5049, 2007 相似文献
37.
This article focuses on discontinuous Galerkin method for the two‐ or three‐dimensional stationary incompressible Navier‐Stokes equations. The velocity field is approximated by discontinuous locally solenoidal finite element, and the pressure is approximated by the standard conforming finite element. Then, superconvergence of nonconforming finite element approximations is applied by using least‐squares surface fitting for the stationary Navier‐Stokes equations. The method ameliorates the two noticeable disadvantages about the given finite element pair. Finally, the superconvergence result is provided under some regular assumptions. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 23: 421–436, 2007 相似文献
38.
Xiao‐Hui Liu Yan‐Guo Li Ying Lin Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1272-1281
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007 相似文献
39.
A generalized formulation is applied to implement the quadratic upstream interpolation (QUICK) scheme, the second-order upwind (SOU) scheme and the second-order hybrid scheme (SHYBRID) on non-uniform grids. The implementation method is simple. The accuracy and efficiency of these higher-order schemes on non-uniform grids are assessed. Three well-known bench mark convection-diffusion problems and a fluid flow problem are revisited using non-uniform grids. These are: (1) transport of a scalar tracer by a uniform velocity field; (2) heat transport in a recirculating flow; (3) two-dimensional non-linear Burgers equations; and (4) a two-dimensional incompressible Navier-Stokes flow which is similar to the classical lid-driven cavity flow. The known exact solutions of the last three problems make it possible to thoroughly evaluate accuracies of various uniform and non-uniform grids. Higher accuracy is obtained for fewer grid points on non-uniform grids. The order of accuracy of the examined schemes is maintained for some tested problems if the distribution of non-uniform grid points is properly chosen. 相似文献
40.