Effect of end groups on complexation kinetics between cyclodextrins and guest polymers

α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006     

上皮生长因子预防心脏术后心包粘连的实验及临床研究

目的探讨上皮生长因子(EGF)对心脏术后心包粘连的预防作用.方法术中对犬心包内喷洒上皮生长因子3个月后,观察心包粘连情况;选先天性心脏病、房缺及室缺病人40例,术中心包内喷洒上皮生长因子,术后6个月、12个月经CT检查,判定心包粘连、增厚结果.结果在动物实验和临床研究中,实验组粘连程度显著低于对照组(P<0.01).结论 EGF心包内应用有明显预防心脏术后心包粘连的作用.     

非对称度量空间上不动点定理

提出建立在非对称度量空间之间的上收缩映射和下收缩映射的概念.考虑到非对称度量的不对称性,进一步定义了非对称度量空间到自身映射的左不动点和右不动点.最后,给出了非对称度量空间上的两个不动点定理.     

Functional magnetic resonance imaging of amphetamine craving

The aim of this study is to identify the brain activity associated with amphetamine craving for understanding the neurobiology of addiction by watching pictures of happy, sad or amphetamine. Brain activity was measured in 12 amphetamine addicts and 12 healthy subjects by fMRI while the subjects watched pictures designed to elicit happy feelings, sad feelings, or the desire to use amphetamine. The result demonstrated that amphetamine cues led to abnormally high cingulate and low frontal lobe activation in amphetamine addicts, who showed abnormalities in affect-related brain activation.     

Determination of carbamazepine by chemiluminescence detection using chemically prepared tris(2,2'-bipyridine)ruthenium(III) as oxidant.

A new chemiluminescence method for the determination of carbamazepine (CBZ) has been developed. The method is based on the chemiluminescence produced in the reaction of tris(2,2'-bipyridine)ruthenium(III) and CBZ in an acidic medium. The chemiluminescence intensity was enhanced by organic solvents in the reaction system. Under the optimum experimental conditions, the calibration curve was linear over the range 4.0 x 10(-3)-8.6 x 10(-7) mol/L for CBZ. The detection limit (S/N = 3) was 2.5 x 10(-7) mol/L and the relative standard deviation of six replicate measurements was 2.6% for 4.0 x 10(-4) mol/L of CBZ. The possible reaction mechanism were also discussed. The chemiluminescence method was successfully applied to assay the CBZ contents in pharmaceutical tablets.     

Development of Full Automatic External Welding Machine for Annular Welds of Pipeline

To meet the demands of rapid development of pipeline constructions in China, a complete set of full automatic external welding machine for annular welds of pipeline and welding procedure have been developed thereof. The system has been applied in the “West-East Pipeline Project” and its performance is proven. With this welding machine the welding parameters can be either preset before or adjusted in real time during the welding process, which avoids the blemishes of same type domestic and international products. Thus it is best propitious to in-situ construction conditions and workers‘ technical level in China. In this article the development of mechanical and control systems of this product is introduced and typical welding procedure parameters are provided.     

汽车碰撞事故的速度分析

通过对交通事故中汽车的碰撞问题的简化 ,运用动量守恒定理和能量守恒定律着重研究了正面碰撞、追尾碰撞和侧面碰撞三种情况下 ,汽车碰撞前动量和速度的求解方法 ,为交通事故模拟和再现提供了一种更为实用的方法 ,并为科学处理交通事故、明确事故责任提供了重要参考。     

APPLICATION OF BORON MODIFIED SILICA SOL ON RETENTION AND DRAINAGE

INTRODUCTIONRecently with the high speed, large-scale develop-ment of papermaking, in the manufacture of paper and paperboard conventional single and dual reten-tion and drainage systems cannot obtain satisfying re-tention and drainage. So in 1980 microparticulate systems appeared. Because of its superiority such as good retention effectiveness on fine and chemicals, improving drainage and paper formation, reducing waste water and enhancing the concentration of white water for good recover…     

广义不确定原理对一般静态黑洞熵的影响

把广义不确定原理引入黑洞熵的计算,采用薄膜brick-wall模型,对一般静态黑洞外部标量场的熵进行了计算,得到了熵计算公式.应用该公式结果表明,可以得到已知所有静态黑洞的Bekenstein-Hawking熵.作为比较和进一步研究,对视界面上的二维膜的熵进行计算,可以更方便和一般性地得到熵与视界面积成正比的结论,该讨论可直接表明黑洞熵就是其视界面上的量子态的熵.与原始brick-wall模型不同的是,这一结论是有限的,计算中无需引入截断,且小质量近似也可以避免.     

关于"当事人承认"的基本问题

在民事诉讼中，当事人承认作为当事人陈述的一种，有其独特的作用，它既可免除对方当事人的举证责任，也对法院的判决起着约束作用。