含铝炸药爆轰数值模拟研究

对含铝炸药25nm和50nm圆试验进行了二维爆轰数值模拟,标定了含铝炸药JWL状态方和反应速率方程参数,为检验含铝炸药爆轰模型及其相关参数的合理性,对含铝炸药驱动金属平板试验进行了二维爆轰数值模拟,得到了与实验值相符合的结果,分析了铝粉在炸药爆轰中的反应情况和约束条件对含铝炸药爆轰性能的影响。结果表明,铝粉主要在爆轰后期与炸药爆轰产物反应释放能量。     

Crystal growth and magnetic properties of the copper coordination polymer [Cu(µ ‐C2O4)(4‐aminopyridine)2(H2O)]n

In this paper, we consider various ways of crystal growth of the polymer [Cu(µ ‐C₂O₄)(4‐aminopyridine)₂(H₂O)]_n. Single crystals of the size of 1.5×1.5×0.2 mm³ have been grown by a slow diffusion technique from solutions of the monoammine copper complex and of the mixture of potassium oxalate and aminopyridine with the stoichiometric ratio. Magnetic susceptibility and ESR measurements have been performed on single crystals large enough for investigating anisotropic properties. The susceptibility can be well described within the model of a Heisenberg antiferromagnetic spin chain. The magnetic measurements reveal a small concentration of paramagnetic moments reflecting the high quality of the single crystals. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

有机盐制备的Fe3O4-葡聚糖纳米粒子的磁性能及表征

By means of chemical co-deposition method in which added Ferric citrate and Ferrous Gluconate, Fe3O4-Dextran composite nano-particles having average diameter 26 nm, was obtained. The particles had a core of diameter 4.1 nm Fe3O4 with a shell of thickness 11 nm Dextran. In the experiment the critical structure of Fe3O4 inorganic particles abstained without N2 protection had no changes. From the result, it can be proven that organic salt has anti oxidation properties and the composite particles have superparamagnetic whose good magnetization is 52 emu/g at 300 K, and 63 emu/g at 5 K. The structure, pattern diameter and magnetic properties of the Fe3O4-Dextran composite particles were examined by means of TEM, XRD, DLS and VSM.     

Effect of dust charge variation on dust—acoustic solitary waves in a magnetized two—ion—temperature dusty plasma

The effect of dust charge variation on the dust-acoustic solitary structures is investigated in a warm magnetized two-ion-temperature dusty plasma consisting of a negatively and variably charged extremely massive dust fluid and ions of two different temperatures. It is shown that the dust charge variation as well as the presence of a second component of ions would modify the properties of the dust-acoustic solitary structures and may exite both dust-acoustic solitary holes (soliton waves with a density dip) and positive solitons (soliton waves with a density hump).     

海浪的数值模拟及其仿真

研究了海浪的频谱模型 .依据海浪的数学模型和海浪的频谱特性 ,对海浪反演的线性叠加法进行了研究 .大量仿真结果说明 ,线性叠加法是反演海浪的一种有效方法 .     

添加稀土氧化物助剂的CeO2-ZrO2固溶体的储氧性及热稳定性研究

大多数工业催化剂都是在稳定的操作条件下进行的,然而汽车尾气净化催化剂却被暴露在大气中,使用条件经常变化,尤其是空燃比(A/F)的变化,直接影响了对氧敏感的三效催化剂的氧化和还原性能[1].CeO2则是一种具有储氧/释氧能力的催化材料,它作为助剂加入三效催化剂中,可在贫况下储存氧(以Ce4+存在)利于NOx的还原,在富况下释放氧(以Ce3+存在),利于HC、CO的氧化,从而提高了催化剂的活性.然而,CeO2 的储氧性通常局限在表面上,当温度超过400℃以上时,其比表面积降低从而引起储氧性能急剧下降,直接影响催化剂的性能和寿命.     

Highly Efficient Photoreduction of Low-Concentration CO2 to Syngas by Using a Polyoxometalates/RuII Composite

At present, the fixation of CO₂ always requires it to be extracted from the atmosphere first, which leads to more energy consumption. Thus, direct photoreduction of low-concentration CO₂ to useful chemicals (e.g., syngas) under sunlight is significant from an energy-saving and environmentally friendly perspective. Here, the design and fabrication of a [Ru(bpy)₃]/[Co₂₀Mo₁₆P₂₄] composite is demonstrated for visible-light-driven syngas production from diluted CO₂ (3–20 %) gas with a high yield of approximately 1000 TONs (turnover number of syngas). This activity is an order of magnitude higher than the reported system with [Ru(bpy)₃]²⁺ participation. With evidence from ultrafast transient absorption, GC-MS, ¹H NMR spectroscopy and in situ transient photovoltage tests, a clear and fundamental understanding of the highly efficient photoreduction of CO₂ by the [Ru(bpy)₃]/[Co₂₀Mo₁₆P₂₄] composite is achieved. Making use of the structure and property designable polyoxometalates towards the photo-fixation of CO₂ is a conceptually distinct and commercially interesting strategy for making useful chemicals and environmental protection.     

Plasma Nitrogen Oxides Synthesis in a Milli-Scale Gliding Arc Reactor: Investigating the Electrical and Process Parameters

Nitrogen fixed in the form of nitrogen oxides is essential to produce fertilizers and many other chemical products, which is vital to sustain life. The performance of a milli-scale gliding arc reactor operated under atmospheric pressure has been studied for nitrogen oxides synthesis. In this work, the electrical and process parameters of the gliding arc reactor, such as frequency, pulse width, amplitude and feed ratio were investigated respectively. The experiments were performed at 1 L/min in a gliding arc discharge regime. The highest concentration of NO_x was found to be ~1 % at energy consumption of 10 kWh/kg of NO_x. Increase in frequency, pulse width and amplitude resulted in an increased specific energy input and NO_x concentration. The feed ratio (N₂/O₂) affected the amount of NO and NO₂ produced, which gives possibility to independently obtain the desired ratio of NO/NO₂ by tuning the electrical and process parameters.