Reactivity of monolayer-protected gold nanoclusters at dye-sensitized liquid/liquid interfaces

Hexanethiolate monolayer-protected gold nanoclusters (MPCs) were used as redox quenchers at the polarizable water/1,2-dichloroethane (DCE) interface. Photocurrent responses originating from the heterogeneous quenching of photoexcited water soluble porphyrin complexes by MPCs dissolved in the DCE phase were observed. As MPCs can function as both electron acceptors and donors, the photocurrent results from the superposition of two simultaneous processes, which correspond to the oxidation and reduction of MPCs. The magnitude of the net photocurrent is essentially determined by the balance of the kinetics of these two processes, which can be controlled by tuning the Galvani potential difference between the two phases. We show that, within the available potential window, the apparent electron-transfer rate constants follow classical Butler-Volmer dependence on the applied potential difference.     

Synthesis, Structure and Characterization of [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O40(H2)]·4H2O

An organic-inorganic compound [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O4o(H2)]·4H2O (Mr = 4048.00) was prepared from the hydrothermal reaction of Na2WO4·2H2O, CuCl2·2H2O,2,2'-bipyridine (2,2'-bpy) and H2O at 160 ℃ for 4 days. The compound crystallizes in the monoclinic system, space group P21/n with a = 18.9196(8), b = 20.4212(8), c = 21.8129(9)(A), β=96.992(3)°, V= 8365.0(6) (A)3, Dc= 3.214 g/cm3, Z = 4,μ(MoKα) = 17.269 mm-1 and F(000) = 7324.Of the 119837 total reflections, 17315 were unique (Rint = 0.0489). The final R = 0.0385 and wR =0.0770 for 11142 observed reflections with I ＞ 2σ(I). Single-crystal X-ray diffraction reveals that the structure is composed of [{Cu(2,2'-bpy)2}2W12O40(H2)]2- anions, discrete [Cu(2,2'-bpy)2]2 cations and lattice water molecules, and the anion is made up of a {W12O40(H2)}6- α-Keggin core decorated with two {Cu(2,2'-bpy)2}2 groups through bridging oxygen atoms.     

价值提取能力与企业的智力资本管理

企业拥有的智力资本存量并不一定会增加企业的价值,在存量即定的情况下,智力资本会对企业价值产生什么样的影响主要取决于智力资本的投资效率。智力资本管理不能只片面注重存量管理,还必须采取有效措施,提升智力资本的价值提取能力。     

在物理实验教学中开发学生的非智力因素

充分发挥学生的主观能动性,变被动教育为主动教育历来是教师面临的一大难题,在大力提倡素质教育的今天这显得尤为重要,本文讨论了如何于物理实验教学中,有效地开发学生的非智力因素,从而使学生“要学”、“乐学”、“会学”。     

会计学专业实践性教学模式的探讨

知识经济时代 ,对会计人员的素质要求越来越高。文章主要探讨如何加强会计专业实践性教学环节 ,寻求有效的实践性教学模式 ,从而培养出具有熟练会计核算能力、利用会计资料进行会计监督、参与企业经营管理预测和决策能力的会计人才     

抛射体运动的两个几何特性

讨论了抛射体运动的两个几何特性     

科技声像工作现状及新定位

作为具有中国特色的科技情报工作，科技声像工作曾为我国的社会主义经济建设作出了极有成效的贡献。但在改革开放的新形势下它却面临严峻的挑战。文章简述了科技声像工作的现状，并就开拓科技声像服务新领域——多媒体制作，提出了作者的见解     

基于树形结构酉空时星座设计的译码方法

针对酉空时码最大似然检测复杂度高的问题，提出了一种酉空时星座的设计及低复杂度译码方法．根据酉空时信号失真测度的定义，依照最邻近原则对星座进行划分，以最小失真准则计算各个星座子集中信号的最佳中心，再通过迭代算法，交替使用两个局部最佳准则，生成由各个信号子集与对应中心所构成的若干子树，形成树形结构的酉空时星座．接收方以接收信号为树根，选择具有最小失真的中心信号．对选定的中心信号对应的子树进行遍历搜索得到对发送信号的估值．该译码方法仅需要对某一中心信号及其对应子树的叶子节点进行计算，避免了最大似然方法对整个星座的全搜索，从而有效地降低了译码复杂度．仿真实验表明，相对于最大似然检测方法，该方法能够以有限的性能损失换取译码计算的有效简化．     

企业内部控制制度建立与完善的探讨

内部控制作为一项系统工程,已经在发达国家形成了一整套完善的有机结合的理论体系和严谨的操作方法。在我国,作为单位内部管理的重要内容也越来越受到社会各界的重视。阐述了内部控制制度的涵义与构成要素,探讨了制定我国企业内部控制制度的目标定位及内容,提出了完善我国企业内部控制制度的对策与构想。     

Reconstruction of Temperature Field in 3-D, Absorbing, Emitting, and Anisotropically Scattering Medium

IntroductionRecently ,theinvestigation on numerical radiative heattransfer has been focused onthe reconstruction of temperatureprofile in target space according to its boundary heat fluxgained by detectors[1 8], whichis a kind of inverse problemofradiation. Among these investigation, Li HY[1 4]hasresearched on one-di mension or two-di mension rectangular ,spherical or cylindrical medium which is absorbing ,emitting , and isotropically scattering ; Liu LH[5,6]hasresearched on the semitranspar…