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991.
Fangyuan Gao Quanqing Zhang Xiuqin Li Qinghe Zhang Ting Mao Yong Lu Weibing Zhang Hongmei Li 《Accreditation and quality assurance》2016,21(6):395-401
In this study, a standard addition–isotope dilution mass spectrometry (SA-IDMS) method for quantification of endogenous progesterone in milk has been described. The method validation results, linearity, limits of detection and quantification, recovery and uncertainty were fit for the purpose of assigning reference mass fractions to proficiency testing schemes. The developed technique was compared to the isotope dilution mass spectrometry (IDMS) method already existing in the laboratory. Analytical results of two milk samples were (1.377 ± 0.048) μg/kg and (4.457 ± 0.155) μg/kg by SA-ID-LC/MS method, while the results were (1.355 ± 0.019) μg/kg and (4.359 ± 0.059) μg/kg by ID-LC/MS, respectively. Since SA-IDMS was an effective quantitative method that overcame matrix effect, similar quantitative results from IDMS and SA-IDMS indicated that the quantification of progesterone in milk was barely influenced by matrix. Both IDMS and SA-IDMS could be used to assign reference mass fractions to progesterone in milk inter-laboratory proficiency testing schemes. 相似文献
992.
该研究致力于建立台风路径模拟模型,目的在于提高风险评估的稳健性和实用性。首先,采用中国台风网提供的CMA-STI热带气旋最佳路径数据集,以广东省为研究区域,通过引入空间统计模型,结合马尔可夫—蒙特卡罗方法模拟了西北太平洋的热带气旋路径。进一步,参数和非参数假设检验结果表明模拟结果是合理的,可以作为风险评估的数据来源。在此基础上,本研究模拟出620年的台风路径,给出了以地级市为基础的重现期估计和风险图绘制方法。研究发现,模拟数据克服了历史数据的时空局限性,与历史数据相比较,基于模拟数据估计的重现水平更具准确性和稳定性;其次,采用模拟方法还可以绘制出历史数据无法实现的大比例风险图,很大程度上提高了风险评估的实用性.研究结果可以作为保险行业开展巨灾保险业务,政府部门制定防灾减灾规划的科学依据. 相似文献
993.
引入进口国关税,基于外国企业与进口国企业的古诺数量竞争结构,考察不同技术授权模式对外国企业利润和进口国社会福利影响,形成跨国环境下的技术授权机制分析.研究表明:固定收费方式对外国企业利润具有不确定性,但可能损害进口国社会福利;特许权收费方式增加了外国企业利润,但却在一定条件下损害了进口国社会福利;双重收费方式同时增加了外国企业利润和进口国社会福利,实现企业目标和社会目标的一致;关税水平较高时,双重收费方式可以特化为固定收费方式. 相似文献
994.
995.
996.
通过雄激素"浸泡法"诱导尼罗罗非鱼Oreochromis niloticus仔鱼雄性化的研究,探索一种雄激素浸泡诱导尼罗罗非鱼仔鱼雄性化的技术方法。选用了可芳化的MT(17α-methyltesosterone)和不可芳化的MDHT(17α-methyldihydrotestosterone)两种雄激素进行对比试验。进行了处理时期(1,7,13 DPH,Days Post Hactching),激素剂量(200,600,1 800,5 400μg·L-1),持续时间(2,4,8 h)3个因素的简单比较法正交试验。结果如下:当诱导7 DPH仔鱼、持续时间为4 h时,MT剂量为600μg·L-1时雄性率最高,为98.81%,而剂量1 800,5 400μg·L-1时雄性率明显下降(P0.05);MDHT剂量为600,1 800μg·L-1时,雄性率最高,分别为98.34%和98.39%,剂量为200,5 400μg·L-1时雄性率没有明显下降(P0.05)。当用MT诱导7 DPH仔鱼,剂量为600μg·L-1时,持续时间为4 h的雄性率最高、而8 h的雄性率明显下降(P0.05);当用MDHT时,3种持续时间(2,4,8 h)的雄性率无明显差异(P0.05)。总体来看,应用MT和MDHT的雄性率都能达到生产应用需求,但MDHT效果更稳定、表现出更好的应用潜力。 相似文献
997.
洪勇 《吉林大学学报(理学版)》2017,55(2):189-194
利用实分析技巧,研究具有齐次核的Hilbert型积分不等式的构造特征及取最佳常数因子的充要条件,得到了最佳常数因子的解析表达式. 相似文献
998.
Jing Luo Sisi Jiang Yong Wu Meiling Chen Xiaoya Liu 《Journal of polymer science. Part A, Polymer chemistry》2012,50(23):4888-4894
A facile method of producing stable aqueous dispersion of graphene/polyaniline (PANI) composite is described, which involves the in situ polymerization of aniline on the surface of graphene with the aid of polystyrene sulfonic acid (PSS). The prepared aqueous graphene/PANI composite dispersion was very stable and no aggregation or precipitation was observed for several weeks. The excellent aqueous dispersibility and stability of the graphene/PANI composite is attributed to the cooperative interactions of π stacking interaction between PSS, PANI, and the graphene basal planes, and the electrostatic repulsions between negatively charged PSS bound on graphene/PANI composite. Fourier transform‐infrared spectrometry (FTIR), ultraviolet‐visible spectra (UV–vis), and Raman spectra confirmed the interaction of PANI and graphene in the composite, which effectively delocalize the electrons. In addition, the composite showed three orders of magnitude of conductivity increase compared with pure PANI. This new approach is simple, fast, and straightforward, representing a significant improvement in the processing of graphene/PANI composites. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
999.
Fengyang Deng Bin Xu Yong Gao Zheng Liu Duanguang Yang Huaming Li 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3767-3774
In this study, a series of linear poly(triazole)s (PTAs) were successfully synthesized by the metal‐ and solvent‐free, thermal click polymerization of diazide and dialkyne (A2 + B2) monomers. All click polymerizations proceeded smoothly at 80 °C in an open atmosphere without protection from oxygen and moisture. After being polymerized for 36 h, the crude polymer was further fractionated into three fractions using a multistep precipitation method. By selectively choosing precipitating agents, this process produced poly(triazole) fractions with low polydispersity index (<1.30). The resulting PTAs are soluble in common organic solvents and stable at a temperature up to 320 °C. Furthermore, the methyl benzoate moieties in the main chain can serve as useful building blocks for further postpolymerization functionalization, yielding 1,2,4‐triazole derivatives. This functionalization strategy offers potential for the development of novel triazole‐based materials. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
1000.
Zhaojie Gu Lijun Deng Hao Luo Xia Guo Haohao Li Zhencai Cao Xunshan Liu Xinwei Li Hongyan Huang Yingzi Tan Yong Pei Songting Tan 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3848-3858
A series of novel low band gap polymers containing conjugated side chains with 4,7‐dithien‐5‐yl‐2,1,3‐benzodiathiazole and different electron‐withdrawing end groups of aldehyde ( PT‐DTBTCHO ), 2‐ethylhexyl cyanoacetate ( PT‐DTBTCN ), 1,3‐diethyl‐2‐thiobarbituric acid ( PT‐DTBTDT ), and electron‐donating end group of 2‐methylthiophene ( PT‐DTBTMT ) have been designed and synthesized. All polymers exhibit good solubility in common organic solvents, film‐forming ability, and thermal stability. These conjugated polymers show the broad ultraviolet‐visible absorption and the narrow optical band gaps in the range of 1.65–1.90 eV. Through changing the end group of conjugated side chains, the photophysical properties and energy levels of the polymers were tuned effectively. Bulk heterojunction solar cells based on the blend of these polymers and (6,6)‐phenyl‐C61‐butyric acid methyl ester (PC61BM) reached the best power conversion efficiency (PCE) of 2.72%. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献