Nanoparticles consisting of optically active helical polymers: Preparation via aqueous catalytic miniemulsion polymerization and the effects of particles size on their optical activity

This article reports a class of nanoscale materials, that is, optically active nanoparticles consisting of helical‐substituted polyacetylenes. Such nanoparticles were prepared via aqueous catalytic miniemulsion polymerization, by which nanoparticles with a wide range of size (diameter: 60–400 nm) can be easily prepared. The nanoparticles could be obtained in quantitative monomer conversions. Large specific rotations and intense circular dichroism effects demonstrated that the nanoparticles possessed large optical activities; moreover, the optical activities were found to increase with a decrease in particle size. From the obtained polymer nanoparticles and with poly(vinyl alcohol) (PVA) as supporting material, composite films were further prepared and also exhibited considerable optical activities. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1661–1668, 2010     

用微扰理论计算双原子分子的振动能级

理论推导出双原子分子其势能函数为Ｕ（ ｘ） ＝ ｆ２２ ！ｘ２ ＋ ｆ３３ ！ｘ３ 形式下的振动能级，并与光谱经验公式比较得出ｆ２ ，ｆ３ 与光谱常数ωｅ ，ωｅｘｅ 的关系     

长春市空气中气相有机烃污染物的时空分布规律

从1997年9月～1998年7月对长春市空气中气相有机烃污染物进行布点监测.实测结果表明，气相有机烃类污染值冬季最高，春季最低．交通路口非甲烷总烃（NMHC）值目变化呈双峰规律，工业区NMHC值日变化呈单峰．随着采样高度的增加，NMHC值逐渐减小．     

Synthesis,Crystal Structure and Electrochemical Behavior of a Fe(II) Complex of 8-Mercaptoquinoline (Hmtq) with Trimethylphosphite Participation

The mononuclear complex Fe(II)(mtq)₂{P(OCH₃)₃}₂ (Hmtq = 8-Mercaptoquinoline) with mixed N-heterocyclic thiolato and phosphite ligands was synthesized and characterized by X-ray crystallography and cyclic voltammetric measurement. The title complex crystallizes in the triclinic space group P-1 with a = 8.929(4), b = 9.965(3), c = 16.913(11) Å, α = 76.21(10), β = 80.89(10), γ= 68.010(10)°, V = 1351.2(11) ų. The Fe(II) atom exhibits an elongated octahedral geometry composed of N₂S₂P₂ donors. The equatorial plane is made up of two cis-oriented N donors from the thiolato ligands and two cis-oriented monodentate P(OCH₃)₃ ligands. The apical sites are occupied by two trans-oriented S atoms from the mtq^? ligands. The thione form is predominant coordination mode of 8-mercaptoquinoline with the N and S donors bound to the Fe(II) to form five-membered chelate rings. The structural feature of the mononuclear Fe(II) complex with mixed phosphite and thiolate ligands is summarized.     

基于自组织特征映射的矢量量化方法

对自组织特征映射神经网络的特性进行分析，并将其与矢量量化问题的实质进行比较，提出了一个实现矢量量化的自组织特征映射算法。分析与实验表明，该算法是稳定收敛的。算法的学习结果与网络的初始状态无关，并且十分接近于全局最优解的下限。将该算法应用于图像数据的压缩，取得了很好的结果     

浅论如何提高发电厂厂用电设计效率

论述了提高厂用电设计效率的必要性,分析了制约厂用电设计效率的因素,提出了统一厂用电设计方案、实现厂用电通用设计图集的具体对策。     

三层介质长圆柱界面上极化电荷和磁化电流的分立镜像

计算表明，三层介质无工圆柱界面上的极化电荷和磁化电流可用多个分立镜像代替，从而使电场和磁场的计算更简单和直观。     

并元码的若干性质

采用Ｗａｌｓｈ谱技术对并元码进行研究，得到了有关并元码谱特性的一些结果，应用这些谱特性容易得到二元并元码的重量分布。