High-fidelity Recognition of Organotrifluoroborate Anions (R−BF3−) as Designer Guest Molecules

The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF₃⁻). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF₃⁻, by cyanostar macrocycles that are size-complementary to the inorganic BF₄⁻ progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K⁺ salts of R−BF₃⁻ anions.     

Additive Results for Moore-Penrose Inverse of Lambert Conditional Operators

Analysis Mathematica - In this paper, we discuss measure theoretic characterizations for Moore-Penrose inverse of Lambert conditional operators, denoted by (MwEMu)?, in some operator classes...     

Investigation of Thermal Gradient Mechanical Fatigue Test Methods for Nickel-based Superalloys

Experimental Mechanics - Temperature gradients significantly affect the material fatigue process. A reliable and robust test procedure is needed for quantifying the effects of temperature gradients...     

Phase Transitions in Ferroelectric KNO3/Al2O3 Nanocomposites

Russian Physics Journal - The temperature dependences of the linear dielectric permittivity ε′ and the third harmonic coefficient γ3ω for nanocomposites obtained by embedding a...     

Column-oriented algebraic iterative methods for nonnegative constrained least squares problems

Numerical Algorithms - This paper considers different versions of block-column iterative (BCI) methods for solving nonnegative constrained linear least squares problems. We present the convergence...     

SPLITTING ALGORITHMS FOR NUMERICAL SOLUTION OF NAVIER — STOKES EQUATIONS IN FLUID DYNAMICS PROBLEMS

Journal of Applied Mechanics and Technical Physics - Implicit finite-volume predictor-corrector algorithms based on the splitting method are proposed for the numerical solution of the...     

Advances in the computational analysis of SARS-COV2 genome

Nonlinear Dynamics - Given a data-set of Ribonucleic acid (RNA) sequences we can infer the phylogenetics of the samples and tackle the information for scientific purposes. Based on current data and...     

Propagating and Standing Rayleigh Waves near Rivet Chains Connecting Kirchhoff Plates

We show that near periodic rivet chains that connect two Kirchhoff plates and are modeled by point Sobolev transmission conditions, Rayleigh waves arise, propagate along the chains, and decay exponentially in the orthogonal direction. Under additional geometric conditions we discover the standing (periodic) waves that carry no energy.

     

Fock–Schwinger Method in the Case of Different Masses

JETP Letters - The result of removing heavy particles with different mass from the theory spectrum can be described at low energy by the effective action, which is an asymptotic series in inverse...     

On the Use of Indium Arsenide as the Waveguide Material in the Measurements by Attenuated Total Reflectance

Optics and Spectroscopy - The current–voltage characteristics and photocurrent of “monolithic” diode optical pairs optically coupled by a substrate made of InAs common for them...