碳量子点/纳米金@碳纳米管修饰电极同时检测鸟嘌呤和腺嘌呤

制备了一种碳量子点(CQDs)/金纳米颗粒(AuNPs)@羟基化多壁碳纳米管(MWCNT-OHs)复合膜修饰电极用于鸟嘌呤(GA)和腺嘌呤(AE)的同时检测.与裸电极和其它修饰电极相比,复合膜修饰电极能显著提高GA和AE的氧化峰电流及峰电位差,能够对GA和AE同时高灵敏检测.研究了GA和AE在复合膜修饰电极上的电化学行为,结果表明,在0.2 mol/L PBS(pH 7.0)中,GA和AE的氧化峰电流与浓度分别在1～200 μmol/L和2～80μmol/L范围内呈良好的线性关系,检测限分别为0.9和1.8 μmol/L.将该修饰电极用于人体血清样品中GA和AE的同时电化学检测,加标回收率在90.4％～107.4％之间,证明了该修饰电极在生物样品分析领域的应用潜力.     

聚L-谷氨酸苄酯固定相的制备及色谱评价

利用L-谷氨酸苄酯开环聚合得到聚L-谷氨酸苄酯,对其进行表征,将聚L-谷氨酸苄酯溶于四氢呋喃后涂敷在3-氨丙基三乙氧基硅胶上制得液相色谱固定相,研究了正相色谱条件下聚L-谷氨酸苄酯涂敷型固定相对9种位置异构体及10种手性化合物的拆分能力。以不同比例的正己烷/异丙醇为流动相,有6种位置异构体(o,m,p-氯苯胺、o,m,p-溴苯胺、o,m,p-碘苯胺、o,m,p-硝基苯胺、o,m,p-二硝基苯和o,m,p-苯二胺)和4种手性化合物(1-(对氯苯基)乙醇、5-二硝基-N-(1-苯乙基)苯甲酰胺、华法林和四咪唑)得到不同程度的拆分,表明聚L-谷氨酸苄酯涂敷型固定相对位置异构体具有较好的识别作用,同时也表现出良好的手性拆分能力。     

In situ Carbon Modification of g-C3N4 from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light

An in situ strategy was introduced for synthesizing carbon modified graphitic carbon nitride(g-C₃N₄) by using urea/4-aminobenzoic acid(PABA) co-crystal(PABA@Urea) as precursor materials. Via co-calcination of the PABA co-former and the urea in PABA@Urea co-crystals, C guest species were generated and compounded into g-C₃N₄ matrix in situ by replacing the lattice N of the carbon nitride and forming carbon dots onto its layer surface. The carbon modification dramatically enhanced visible-light harvesting and charge carrier separation. Therefore, visible light photo-catalytic oxidation of methylene blue(MB) pollution in water over the carbon modified g-C₃N₄(C/g-C₃N₄) was notably improved. Up to 99% of methylene blue(MB) was eliminated within 60 min by the optimal sample prepared from the PABA@Urea co-crystal with a PABA content of 0.1%(mass ratio), faster than the degradation rate over bare g-C₃N₄. The present study demonstrates a new way to boost up the photocatalysis performance of g-C₃N₄, which holds great potential concerning the degradation of organic dyes from water.     

Meta-DNA Strategy to Assemble DNA Structures in Submicrometre and Micrometre Scale

To break through the size limitation in DNA structure assembly and to achieve the construction of DNA structures with submicrometre and micrometre scale, Fan and Yan et al. proposed a versatile DNA structure assembly strategy, named as meta-DNA(M-DNA) strategy. Submicrometre-sized M-DNA, which has a six-helix bundle DNA origami nanostructure, is used as building block to precisely assemble a series of submicrometre-to-micrometre-sized DNA architectures with customed shapes, including meta-multi-arm junctions, polyhedrons and closely packed lattices. Besides static assembly, the proposed M-DNA strategy was also demonstrated to work well for the programmed dynamic rearrangement of DNA structures. This work has been published online in the Nature Chemistry on September 7, 2020.     

亚微米Fe包Co空心微球的制备

研究了一种制备Fe包Co空心微球的新方法.以纳米铁粒子为模板,水合肼为还原剂,通过化学镀制备出具有核-壳结构的Co包Fe纳米粒子,用HCl溶去Fe核制备出空心Co微球,以空心Co微球为模板,NaBH4为还原剂,通过化学镀Fe制备了亚微米Fe包Co的空心微球.研究发现,在化学镀Fe过程中,Fe包Co空心微球之间极易形成硬黏结,通过降低反应物浓度和反应温度,增大反应液pH值抑制镀液中Fe粒子的独立形核,则可明显防止Fe包Co空心微球之间硬黏结的发生.     

污水处理厂出水维甲酸X受体干扰效应研究

应用重组维甲酸X受体(RXR)基因酵母筛选南方某污水处理厂进水、不同工艺出水的维甲酸干扰活性;结合大鼠肝均浆(S9)体外代谢方法,检测样品间接维甲酸干扰活性.结果表明:进水、出水样品均不能诱导RXR介导酶活性,但在高富集倍数下,样品与空白对照相比显著抑制9-顺维甲酸诱导酶活性,表现出维甲酸拮抗效应;在添加S9体外代谢活化后,所有样品均检出类维甲酸干扰活性,部分样品还检测出抗维甲酸活性,表明城市污水样品中存在大量具有类/抗维甲酸干扰活性的化合物.研究结果证实,现行处理工艺对类/抗维甲酸干扰物有一定的去除效果;重组基因酵母结合S9体外代谢活化体系可用于水环境样品类/抗维甲酸干扰效应的快速筛选.     

图的符号边全k控制数

通过对图G边集分折的方法,对图的符号边全k控制问题进行了研究,得到了连通图G的符号边全k控制γskt(G)的2个下限,并确定了所有路符号边全k控制数.     

反胶束体系中纤维素酶降解纤维素的研究

为减小酶与表面活性剂之间的静电作用,提高酶的活性,在丁二酸二异辛酯磺酸钠(AOT)/异辛烷反胶束体系中加入了正辛醇,并用微量量热法研究了AOT/正辛醇/异辛烷反胶束体系中正辛醇浓度(c),含水量(wo),pH及温度(T)对纤维素酶降解纤维素的影响.结果表明,正辛醇的加入确实有利于纤维素酶活性的提高,而在上述反胶束体系中纤维素酶降解纤维素的最佳条件是c=0.11mol·L-1,w0=3.1,pH=5.01,T=315.57 K.     

Rolling-induced microstructure change in Zr_(65)Al_(7.5)Ni_(10)Cu_(12.5)Ag_5 bulk metallic glass

The microstructures and free-volume evolutions of as-cast and pre-annealed Zr65Al7.5Ni10Cu12.5Ag5 bulk metallic glasses during rolling deformation have been investigated. No phase transformation is detected in the as-cast/rolled specimen. However,the structural stability of the glass against plastic deformation is worse after pre-annealing,indicated by nanocrystallization in preannealed/rolled specimens with large deformation degrees. Moreover,with increasing deformation degree,the free-volume content in a ...     

Stokes 方程的压力梯度局部投影稳定化方法

作者将压力梯度投影方法和宏元剖分相结合,对Stokes 方程提出了一种新的局部稳定化方法,该方法的稳定项只与压力梯度投影和宏元内部边界跳跃有关,而且不需要修改右端,实现起来更容易.