Accurate ab initio anharmonic force field and heat of formation for silane

From large basis set coupled cluster calculations and a minor empirical adjustment, an anharmonic force field for silane has been derived that is consistently of spectroscopic quality (±1 cm^?1 on vibrational fundamentals) for all isotopomers of silane studied. Inner-shell polarization functions have an appreciable effect on computed properties and even on anharmonic corrections. From large basis set coupled cluster calculations and extrapolations to the infinite-basis set limit, we obtain TAE₀ = 303.80 ± 0.18 kcal mol^?1, which includes an anharmonic zero-point energy (19.59 kcal mol^?1), inner-shell correlation (—0.36 kcal mol^?1), scalar relativistic corrections (— 0.70 kcal mol^?1) and atomic spin-orbit corrections (—0.43 kcal mol^?1). In combination with the recently revised ΔH ^o _{f, o}[Si(g)], we obtain ΔH ^o _f.o[SiH₄(g)] = 9.9 ± 0.4 kcal mol^?1 in between the two established experimental values.     

Perturbation theory for the square-well dimer fluid

An analytical equation of state is presented for the square-well dimer fluid of variable well width (1 ≤ λ ≥ 2) based on Barker-Henderson perturbation theory using the recently developed analytical expression for radial distribution function of hard dimers. The integral in the first- and the second-order perturbation terms utilizes the Tang, Y and Lu, B. C.-Y., 1994, J. chem. Phys., 100, 6665 formula for the Hilbert transform. To test the equation of state, NVT and Gibbs ensemble Monte Carlo simulations for square-well dimer fluids are performed for three different well widths (λ = 1.3, 1.5 and 1.8). The prediction of the perturbation theory is also compared with that of thermodynamic perturbation theory in which the equation of state for the square-well dimer is written in terms of that of square-well monomers and the contact value of the radial distribution function.     

Distributed location-based query processing on large volumes of moving items

Recently,new techniques to efficiently manage current and past location information of moving objects have received significant interests in the area of moving object databases and location-based service systems. In this paper,we exploit query processing schemes for location management systems,which consist of multiple data processing nodes to handle massive volume of moving objects such as cellular phone users. To show the usefulness of the proposed schemes,some experimental results showing performance factors regarding distributed query processing are explained. In our experiments, we use two kiids of data set：one is generated by the extended GSTD simulator and another is generated by the real-time data generator which generates location sensing reports of various types of users having different movement patterns.     

ANALYTICAL AND NUMERICAL STUDY ON SPATIAL FREE VIBRATION OF NON-SYMMETRIC THIN-WALLED CURVED BEAMS

For spatial free vibration of non-symmetric thin-walled circular curved beams, an accurate displacement field is introduced by defining all displacement parameters at the centroidal axis and three total potential energy functionals are consistently derived by degenerating the potential energy for the elastic continuum to that for thin-walled curved beams. The closed-form solutions are newly obtained for in-plane and out-of-plane free vibration analysis of monosymmetric curved beams respectively. Also, two thin-walled curved beam elements are developed using the third and fifth order Hermitian polynomials. In order to illustrate the accuracy and the practical usefulness of the present method, analytical and numerical solutions by this study are presented and compared with previously published results or solutions by ABAQUS' the shell element. Particularly, effects of the thickness curvature as well as the inextensional condition are investigated on free vibration of curved beams with monosymmetric and non-symmetric cross-sections.     

HEALTH-MONITORING METHOD FOR BRIDGES UNDER ORDINARY TRAFFIC LOADINGS

A method for damage estimation of a bridge structure is presented using ambient vibration data caused by the traffic loadings. The procedure consists of identification of the operational modal properties and the assessment of damage locations and severities. An experimental study is carried out on a bridge model with a composite cross-section subjected to vehicle loadings. Vertical accelerations of the bridge deck are measured while vehicles are running. The modal parameters are identified from the free-decay signals extracted using the random decrement method. The damage assessment is carried out based on the estimated modal parameters using the neural networks technique. As input to the neural networks, the ratios of the resonant frequencies between before and after damages and the mode shapes after the damages are used to take into account the mass effect of the traffic on the bridge. The identified damage locations and severities agree reasonably well with the inflicted damages on the structure.     

TiO2对共沉淀法制备Pd/Al2O3-TiO2催化活性的影响

文中采用共沉淀法制备了混合载体质量分数为1%的Pd/Al₂O₃-TiO₂催化剂，借助XRD和XPS对样品进行了表征，结果表明：混合载体Al₂O₃-TiO₂为无定形结构；TiO₂降低了Pd和Al₂O₃的相互作用能力。将样品应用于C₃H₆选择催化还原NO反应，以NO转化率为活性评价指标对催化剂的活性进行了对比，发现TiO₂的含量对催化剂活性有显著影响：随着TiO₂质量分数从0增加至50%，催化剂活性迅速增加；TiO₂质量分数超过50%，催化剂活性增加趋势变缓。     

Version based spatial record management techniques for spatial database management system

The search operation of spatial data was a principal operation in existent spatial database management system，but the update operation of spatial data such as tracking are occurring frequently in the spatial database management system recently. So，necessity of concurrency improvement among transactions is increasing. In general database management system，many techniques have been studied to solve concurrency problem of transaction. Among them，multi-version algorithm does to minimize interference among transactions. However，to apply existent multi-version algorithm to improve concurrency of transaction to spatial database management system， the waste of storage happens because it must store entire version for spatial record even if only aspatial data of spatial record is changed. This paper has proposed the record management techniques to manage separating aspatial data version and spatial data version to decrease waste of storage for record version and improve concurrency among transactions.     

全球当地化:中国家电企业攻克韩国市场的必由之路

中国正在从家电制造大国向家电技术强国方向迈进,其家电产品已销往世界各地,但韩国市场却仍是中国家电企业的"软肋"。究其因一是难敌韩国家电品牌,二是韩国消费者高度忠诚于本国品牌。因此,中国家电在韩国市场上必须采取相应的目标市场和定位战略,在迎合韩国家电市场消费需求和偏好的基础上,强化当地化营销策略和行动。     

柠檬酸盐法制备(Na0.5 Bi0.5)1-xBaxTiO3压电陶瓷的极化特性研究

采用柠檬酸盐法合成了具有单一钙钛矿结构的(Nao5Bio5)1-xBaxTiO3(x=0,x=0.04)超细粉料,并研究了陶瓷样品的极化特性、压电性能和铁电性能.研究结果表明,柠檬酸与金属离子的摩尔比(C/M)控制在1.2～1.6、前驱体液的pH值控制在7～9范围内可以得到均匀透明的溶胶和凝胶,凝胶在600℃下热处理1h后可形成单一钙钛矿结构的超细粉料.XRD研究结果表明,x=0和x=0.04时陶瓷样品均为三方钙钛矿结构.极化电压和极化温度对陶瓷样品的压电性能有很大影响,而极化时间对压电性能的影响则不显著.Ba2+的固溶改善了陶瓷样品的铁电性能,有利于材料极化性能和压电性能的提高.与常规固相法制备的同种组成样品相比,柠檬酸盐法制备的(Nao5Bi0.5)1-xBaxTiO3(x=0,x=0.04)陶瓷具有较好的压电性能.     

Demi-linear analysis Ⅱ——demi-distributions

In this paper, we develop the theory of demi-distributions which generalizes the usual distribution theory. In particular, we show that many results on differentiations, Fourier transforms, and convolutions can be generalized to demi-distributions theory.