Sensitive chemically amplified electrochemical detection of ruthenium tris-(2,2′-bipyridine) on tin-doped indium oxide electrode

Optimized combination of chemical agents was selected for sensitive electrochemical detection of dissolved ruthenium tris-(2,2′-bipyridine) (Ru-bipy). The detection was based on the chemical amplification mechanism, in which the anodic current of a redox-active analyte was amplified by a sacrificial electron donor in solution. On indium-doped tin oxide (ITO) electrodes, electrochemical reaction of the analyte was reversible, but that of the electron donor was greatly suppressed. Several transition metal complexes, such as ferrocene and tris-(2,2′-bipyridine) complexes of osmium, iron and ruthenium, were evaluated as model analyte. A correlation between the amplified current and the standard potential of the complex was observed, and Ru-bipy generated the largest current. A variety of organic bases, acids and zwitterions were assessed as potential electron donor. Sodium oxalate was found to produce the largest amplification factor. With Ru-bipy as the model analyte and oxalate as the electron donor, the analyte concentration curve was linear up to 50 μM, with a lower detection limit of approximately 50 nM. Preliminary work was presented in which a Ru-bipy derivative was attached to bovine serum albumin and detected electrochemically. Although the combination of Ru-bipy, oxalate and ITO electrode has been used before for electrochemiluminescent detection of Ru-bipy and oxalate, as well as electrochemical detection of oxalate, its utility in amplified voltammetric detection of Ru-bipy as a potential electrochemical label has not been reported previously.     

VSAT系统改进冲突分解算法研究

文章提出一种新的改进隔离型随机N叉树形冲突分解算法,对VSAT随机接入多址接入系统中冲突分解进行了研究。给出了冲突信息分组分解所需平均时隙数和系统吞吐量的解析式,进一步给出了信息分组冲突分解的实验值。     

An Efficient Selective Oxidation of Alcohols with Potassium Permanganate Adsorbed on Aluminum Silicate under Solvent-free Conditions and Shaking

A new procedure for the selective oxidation of alcohols to the corresponding aldehydes and ketones with potassium permanganate supported on aluminum silicate at room temperature under solvent-free conditions and shaking is reported.     

浅谈饭店"环境入世"

环境恶化，生态平衡破坏，使对可持续发展的研究愈来愈重要．通过对饭店经营观念的转变。创建绿色饭店环境成本和效益的分析，提出实现饭店可持续发展的途径．     

发动机传感器的测试

发动机传感器的测试是进行控制和诊断的基础,故有必要对传感器输出信号的性质、特征及电路加以阐述.     

论知识经济条件下图书馆效益的提高

阐明了知识经济条件下图书馆效益可大致用知识的使用状况即文献借阅率、网页点击率、咨询解答率和知识创新率来表示。从知识运动的角度，分析了影响图书馆效益的主要因素。并探讨了提高图书馆效益的有效途径。     

Analysis on X-Ray Laser Generation with EM-Wave Wiggler

The possibility of realizing SASE Free Election Laser in x-ray waveband with EM-wave wiggler is studied in this paper. SASE effect including saturation length, saturation power and nonlinear process is explored through a 3-D simulation code. A utilization of seed light from laser plasma x-ray is also analyzed, which demonstrates the feature of shortening the interaction length for saturation. The results show that sizeable output power of x-ray laser would be generated with a middle energy electron beam.     

浅谈体育教育专业学生试教的指导

“试教”是从学生到教师进行角色转换的必修课 .本文从实践中提炼出试教的指导方法 ,旨在为教师在试教过程中有针对性地指导学生提供帮助 ,从而达到提高学生教学能力的目的 ,使学生从心理、教学能力等诸方面顺利完成从学生到教师的角色过渡 .     

谈家庭害虫的危害及防治

家庭是人们生活居住的重要场所，伴人而居的害虫影响到人们的生活质量。因此，采用环境卫生防治、保管技术防治、化学防治、物理与机械防治、人工捕杀害虫等措施，能够有效地改善家庭生活环境。     

Earthquake Resistant Engineering and Application of Seismic Zonation Map of China

China is a country with high seismieity. It is very important for industry and structure to fortify against earthquakes. In this paper the outline of seismicity in China, the criteria for fortification against earthquakes and the contents of seismic zonation map of China are described. The contents of seismic safety evaluation for major construction projects, such as large dams, large bridges, long distance pipe lines for transporting oil and natural gas, nuclear plants, petrochemical enterprises and so on, are presented. Some geological disasters caused by destructive earthquake, such as earthquake-caused collapse and landslide, liquefaction of saturated soll and earthquake fault and so on, are also presented. Preventive countermeasures for these disasters are discussed.