一种产长春碱真菌的分离

从云南巍山长春花（树皮）中分离到６株真菌,用高效液相色谱（ＨＰＬＣ）对其中一株真菌（９７ＣＧ１）培养物进行了分析,初步结果表明此真菌能合成抗癌药物长春碱．经鉴定９７ＣＧ１为交链孢属（Ａｌｔｅｒｎａｒｉａｓｐ．）     

巴谢河中游那勒寺灌区环境水文地质影响预测评价

采用水文地质学的数值法,对南阳渠灌溉工程实施后巴谢河河谷那勒寺灌区地下水位的变化及由其产生的环境水文地质问题进行了预测评价。结果表明,地下水流的数学模型及其边界条件概化正确,参数选取合理,预测精度较高。对实际生产问题有一定的指导作用。     

电力系统潮流计算的模拟进化方法

将模拟进化方法引入电力系统潮流计算。与传统方法比较结果表明,模拟进化方法中的进化策略法可以有效地解决电力系统病态潮流问题。文中还对几种模拟进化方法进行了比较,结果表明：进化策略法用地潮流计算比较成功;基因算法和进化规划法由于方法本身的缺陷,不太适合于潮流计算。     

四元体系Na2B4O7—Na2CO3—NaCl—H2O在0℃时的等温溶度研究

第一次用等温方法测定了含硼酸盐的三元边界体系Ｎａ２Ｂ４Ｏ７－ＮａＣｌ－Ｈ２Ｏ和四元体系Ｎａ２Ｂ４Ｏ７－Ｎａ２ＣＯ３－ＮａＣｌ－Ｈ２Ｏ在０℃时的溶度。结果发现它们都是低共饱型体系。在三元体系中共饱点组成为ＮａＣｌ２６．１９％,Ｎａ２Ｂ４Ｏ７０．３６％（质量）;四元体系中共饱点组成为ＮａＣｌ２３．５５％,Ｎａ２Ｂ４Ｏ７０．６２％,Ｎａ２ＣＯ３４．０７％（质量）,并且绘出了四元体系中的溶度图和等水线。     

Structure and hydrodynamics of polyamic acid chains in solutions. Effect of “pin-joint” oxygen atom

The hydrodynamic characteristics and weight-average molecular weights of some samples of poly-(4,4′-oxydiphenylene) pyromellitamic acid (I) and poly (4,4′-phenylene) pyromellitamic acid (II) in DMF have been obtained by sedimentation, viscometry and light scattering. For (I) the dependence of S₀ on M was obtained and it was found that the hydrodynamic parameters $\text{F}{}^{\mathrm{<mtext>1</mtext><mtext>3</mtext>}}\text{P}{}^{\mathrm{?1}}$ depend on M up to M = 10⁵. The experimental results were treated by using two models, viz. a Yamakawa-Fujii persistent chain and a rotational isomeric chain with free rotation about valence bonds. It was shown that the hydrodynamic behaviour of macromolecules of (I) with a pin-joint oxygen atom in the main chain is satisfactorily described by the rotational isomeric chain model with free rotation about valence bonds. The dependence of [η] on M was obtained and the constants K and a in an equation of the Mark-Kuhn-Houwink type were determined for (II). The flexibility of the chain was estimated and the Kuhn segment was found to be 200 Å using the Yamakawa-Fujii theory. The flexibilities of the chains of (I) and (II) are compared; it is shown that the rigidity of the chain of (II) without a pin-joint oxygen atom in the monomer unit is much higher than that of the chain of (I). The dependence of S₀ on M obtained for (II) suggests that its macromolecules show a more pronounced tendency for formation of aggregates than those of (I).     

激光光散射研究丙烯酰胺-二甲基二烯丙基氯化铵共聚物的溶液行为

用激光光散射技术表征了阳离子含量受控的丙烯酰胺 二甲基二烯丙基氯化铵共聚物 (简称P(AM DMDAAC) )在 0 1mol LNaCl溶液中的基本参数和溶液行为 .表观基本参数 : Mw ,app =5 0 4× 10 5g·mol- 1 、app =39 9nm和A2 ,APP =1 5× 10 - 4cm3·mol·g- 2 .动态光散射研究结果表明 ,扩散系数Dt 与角度、浓度皆呈非线性依赖关系 ,当C >C 或在较大的散射角域 ,Dt 偏离线性关系所预示的理论值而向减小的方向发展 ,表明存在缔合物 ;流体力学半径Rh 分布有大、小两个范围 ,并随温度升高向小尺寸方向发展 ,证明了体系中存在缔合行为以及升温的解缔合作用 .在一定条件下 ,“亚稳定性”的存在有力地旁证了体系的缔合行为     

Stereo- and regioselective synthesis of 1,3-diaryl-3-chloro-1-propanols via the reaction of aryl aldehydes with styrene and (E)-β-methylstyrene

Reactions of aryl aldehydes with styrene and (E)-β-methylstyrene in the presence of phenylboron dichloride regioselectively generate 1,3-diaryl-3-chloro-1-propanols and 1,3-diaryl-3-chloro-2-methyl-1-propanols in good to excellent yields with high stereoselectivity.     

二氧化硫的电化学氧化过程：Ⅲ.SO2在聚钴卟啉电极上的氧化机理

采用循环伏安法，稳态法，计时电位法等研究了ＳＯ２在聚钴卟啉膜电极上的电化学氧化过程，并和ＳＯ２在贵金属电极上的行为进行了比较。     

Calix[4]crown in dual sensing functions with FRET

A new calix[4]crown chemosensor based on dual sensing probes reveals Pb²⁺ ion selectivity over other metal ions, which arises from a hypsochromic shift of azo units in UV spectrum as well as a fluorescence enhancement of pyrenyl parts in fluorescence spectrum via a suppressed FRET.