Fluorescent sensors for the enantioselective recognition of mandelic acid: signal amplification by dendritic branching

Novel chiral bisbinaphthyl compounds have been synthesized for the enantioselective fluorescent recognition of mandelic acid. By introducing dendritic branches to the chiral receptor unit, the fluorescence signals of the receptors are significantly amplified because of the light-harvesting effect of the dendritic structure. This has greatly increased the sensitivity of the sensors in the fluorescent recognition. Study of the three generation sensors demonstrates that the generation zero sensor is the best choice for the recognition of mandelic acid because of its greatly increased fluorescence signal over the core and its high enantioselectivity. This sensor is potentially useful for the high throughput screening of chiral catalysts for the asymmetric synthesis of alpha-hydroxycarboxylic acids.     

化学键合吸附剂的合成及吸附行为

在无定型硅胶上化学键合十八烷基三氯硅烷，键合率17%-20％，粒度5μm-10μm，以此键合的吸附剂可有效地吸附香烟烟气中的焦油、亚硝胺，吸附率分别为15%-18％和37%-43％，研究了化学键合吸附剂的粒度和加入量对吸附性能的影响。     

浅谈花生壳的综合开发利用

本文对花生壳的一些生用途如 农用肥料,饲料,胶粘剂,复合材料,活性炭以及提取医药和化原料等作了简要介绍。     

集成化企业网络需求分析信息量化模型

集成化企业网络需求分析信息量化模型冯径沈苏彬顾冠群（东南大学计算机科学与工程系,南京２１００９６）集成化企业网络是ＣＩＭＳ网络的典型网络,包括设计制造、控制和管理等各方面的网络集成［１,２］．网络需求分析是网络设计的第一步［３］,它不仅是整个网络设...     

On some tests-based projection pursuit for elliptical symmetry of a high-dimensional distribution

Some test statistics of Kolmogorov type and Cramér-von Mises type based on projection pursuit technique are proposed for the testing problem of sphericity of a high-dimensional distribution. The limiting distributions of the test statistics are derived under the null hypothesis and under any fixed alternative. The asymptotic properties of bootstrap approximation are investigated. Furthermore, for computational reasons, an approximation for the statistics, based on the number theoretic method, is suggested. An erratum to this article is available at .     

稀土元素(镝、钬、铒、铥、镱、镥、钇和钪)高分辨率ICP光谱谱线表与光谱图的编制

讨论并建立了高分辨率光谱仪参数,在带宽为3pm的光谱条件下摄取了稀土元素的高分辨率等离子发射光谱（ICP）,鉴定了在240～450um波长范围内的谱线,和估测了这些谱线的强度．在实验中也观测到了谱线复杂的物理轮廓,包括超精细结构和未完全分辨的定线轮廓．     

一级反应网络法求单底物酶促反应的米氏常数

以可溶性淀粉为底物,研究了糖化酶（ＥＣ３．２．１．３）的动力学规律。淀粉水解反应具有单底物酶促反应的特征,且当［ｓ］Ｋｍ时,服从拟一级反应规律。根据一级反应网络理论,采用单纯形加速法拟合酶促淀粉水解反应的过程曲线求各速率常数和米氏常数。     

Study of the Fluorescence System of Europium–Enoxacin and its Applications

 This paper is the study of the fluorescence enhancement of Eu³⁺-1-ethyl-6-fluoro-4-oxo-7-(1-piperazinyl)-1,8-naphthyridin-3-carbonic acid (enoxacin, EFLX) system by surfactants. It was found that sodium dodecylbenzenesulfonate (SDBS) exhibits great enhancement on the fluorescence of the Eu-EFLX system. The molar ratio is 1:2:1 for Eu:EFLX: SDBS. Under the optimum conditions, the fluorescence intensity is a linear function of europium in the range of 1.0 × 10⁻⁸ ∼ 5.0 × 10⁻⁶ mol/L, the detection limit is 1.0 × 10⁻⁹ mol/L. The application of the Eu-EFLX-SDBS system for the determination of trace europium in rare earth samples gave satisfactory results. Received October 19, 2000. Revision August 10, 2001.     

Synthesis, Characterization and Crystal Structure of a One-dimensional Diamagnetic Metal-radical Complex: [Zn(NIT4py)2(DTB)2(H2O)2]

A novel one-dimensional complex [Zn(NIT4py)₂(DTB)₂(H₂O)₂] (1), with mixed ligands [where NIT4py is 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide and DTB is 3,5-dinitrobenzoate] has been synthesized and characterized by elemental analyses, i.r., u.v.–vis spectra, thermogravimetric analysis, X-ray single crystal diffraction and magnetic measurements. The complex crystallizes in the triclinic crystal system and space group Pî. The Zn ^II ion is in a distorted octahedral environment: two nitrogen atoms from two NIT4py entities, two oxygen atoms from two DTB units in the basal plane; and two oxygen atoms from the two water molecules in the axial position. The [Zn(NIT4py)₂(DTB)₂(H₂O)₂] units are connected as a one dimension chain by the intermolecular hydrogen bonds. The complex exhibits intramolecular antiferromagnetic interactions between the two radicals.     

二氢茉莉酮酸甲酯的简便合成方法

本文报道二氢茉莉酮酸甲酯的简便合成方法。先由丁二酸和庚酰氯反应得到2-戊基-1,3-环戊二酮(1),再用甲醇醚化1,可得到2-戊基-3-甲氧基-环戊-2-烯酮(2)。2与丙二酸二甲酯反应生成(2-戊基-3-酮-1-环戊烯-)基乙酸甲酮(3)。最后,催化氢化3,便可得到二氢茉莉酮酸甲酯(4)。