全文获取类型
收费全文 | 40968篇 |
免费 | 4499篇 |
国内免费 | 4178篇 |
专业分类
化学 | 20477篇 |
晶体学 | 393篇 |
力学 | 1595篇 |
综合类 | 254篇 |
数学 | 2988篇 |
物理学 | 9226篇 |
综合类 | 14712篇 |
出版年
2024年 | 123篇 |
2023年 | 623篇 |
2022年 | 1035篇 |
2021年 | 1149篇 |
2020年 | 1200篇 |
2019年 | 1143篇 |
2018年 | 981篇 |
2017年 | 1003篇 |
2016年 | 1460篇 |
2015年 | 1616篇 |
2014年 | 2008篇 |
2013年 | 2550篇 |
2012年 | 2942篇 |
2011年 | 3045篇 |
2010年 | 2358篇 |
2009年 | 2195篇 |
2008年 | 2587篇 |
2007年 | 2222篇 |
2006年 | 2086篇 |
2005年 | 1882篇 |
2004年 | 1568篇 |
2003年 | 1412篇 |
2002年 | 1728篇 |
2001年 | 1391篇 |
2000年 | 1114篇 |
1999年 | 1254篇 |
1998年 | 871篇 |
1997年 | 824篇 |
1996年 | 806篇 |
1995年 | 729篇 |
1994年 | 606篇 |
1993年 | 565篇 |
1992年 | 479篇 |
1991年 | 427篇 |
1990年 | 385篇 |
1989年 | 335篇 |
1988年 | 303篇 |
1987年 | 183篇 |
1986年 | 126篇 |
1985年 | 110篇 |
1984年 | 58篇 |
1983年 | 42篇 |
1982年 | 33篇 |
1981年 | 25篇 |
1980年 | 13篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1975年 | 4篇 |
1973年 | 4篇 |
1957年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
31.
Cuixia Cui Yong Gao Dr. Jun Li Chao Yang Meng Liu Prof. Dr. Huile Jin Prof. Dr. Zhenhai Xia Prof. Dr. Liming Dai Prof. Dr. Yong Lei Prof. Dr. Jichang Wang Prof. Dr. Shun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(20):8002-8007
Although tremendous efforts have been devoted to understanding the origin of boosted charge storage on heteroatom-doped carbons, none of the present studies has shown a whole landscape. Herein, by both experimental evidence and theoretical simulation, it is demonstrated that heteroatom doping not only results in a broadened operating voltage, but also successfully promotes the specific capacitance in aqueous supercapacitors. In particular, the electrolyte cations adsorbed on heteroatom-doped carbon can effectively inhibit hydrogen evolution reaction, a key step of water decomposition during the charging process, which broadens the voltage window of aqueous electrolytes even beyond the thermodynamic limit of water (1.23 V). Furthermore, the reduced adsorption energy of heteroatom-doped carbon consequently leads to more stored cations on the heteroatom-doped carbon surface, thus yielding a boosted charge storage performance. 相似文献
32.
Sung Hwan Koo Dong Jun Li Taeyeong Yun Dong Sung Choi Kyung Eun Lee Gil Yong Lee Youngtak Oh Joonwon Lim Suchithra Padmajan Sasikala Ho Jin Lee In Ho Kim Hong Ju Jung Rishabh Jain Sang Ouk Kim 《Particle & Particle Systems Characterization》2019,36(7)
Efficient water electrolysis catalyst is highly demanded for the production of hydrogen as a sustainable energy fuel. It is reported that cobalt derived nanoparticle (CoS2, CoP, CoS|P) decorated reduced graphene oxide (rGO) composite aerogel catalysts for highly active and reliable hydrogen evolution reaction electrocatalysts. 7 nm level cobalt derived nanoparticles are synthesized over graphene aerogel surfaces with excellent surface coverage and maximal expose of active sites. CoS|P/rGO hybrid aerogel composites show an excellent catalytic activity with overpotential of ≈169 mV at a current density of ≈10 mA cm?2. Accordingly, efficient charge transfer is attained with Tafel slope of ≈52 mV dec?1 and a charge transfer resistance (Rct) of ≈12 Ω. This work suggests a viable route toward ultrasmall, uniform nanoparticles decorated graphene surfaces with well‐controlled chemical compositions, which can be generally useful for various applications commonly requiring large exposure of active surface area as well as robust interparticle charger transfer. 相似文献
33.
Chunhong Wang Qi Cui Zhixin Zhang Prof. Zhu-Jun Yao Dr. Shaozhong Wang Prof. Zhi-Xiang Yu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(42):9821-9826
1,3-Azaprotio transfer of propargylic α-ketocarboxylate oximes, a new type of alkynyl oximes featuring an ester tether, has been explored by taking advantage of gold catalysis. The incorporation of an oxygen atom to the chain of alkynyl oximes led to the formation of two different oxa-cyclic nitrones. It was found that internal alkynyl oximes with an E-configuration deliver five-membered nitrones, whereas terminal alkynyl oximes with an E-configuration afford six-membered nitrones. DFT calculations on four possible pathways supported a stepwise formation of C−N and C−H bonds, in which a 1,3-acyloxy-migration competes with the 1,3-azaprotio-transfer, especially in the case of internal alkynyl oximes. The relative nucleophilic properties of oxygen in the carbonyl group and the nitrogen in the oxime, the electronic effects of alkynes, and the influence of the ring system have been investigated computationally. 相似文献
34.
Jiatian Chen Le Yang Ying Li Qinghua Hou Lanlan Li Peng Jin 《International journal of quantum chemistry》2019,119(16):e25961
Inorganic planar ring-shape molecules with 4n + 2 π electrons are always the focus of experimental synthesis and theoretical research due to their potential aromaticity and stability. In this work, the whole series of five-membered heterocycle monoanions X nY5-n− (X, Y = group 15 elements; n = 1-4) were thoroughly investigated by means of density functional theory calculations. They all have large formation energies and HOMO-LUMO gap energies, suggesting the potential thermodynamic and kinetic stability. Their aromaticities are comparable to that of typical aromatic hydrocarbons. Their thermal stabilities were firmly established by the ab initio molecular dynamics simulations. As most of them are predicted for the first time, their various spectra were simulated for experimental characterization. Furthermore, we demonstrate that these five-membered cyclic anions can be employed as η5-ligand to construct novel all-inorganic metallocenes, which may serve as the building blocks of low-dimensional nanomaterials. 相似文献
35.
Dongping Wang Jie Dong Wenjing Fan Prof. Dr. Xiang-Ai Yuan Prof. Dr. Jian Han Prof. Dr. Jin Xie 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(22):8508-8512
An unprecedented Mn(I)-catalyzed selective hydroarylation and hydroalkenylation of unsaturated amides with commercially available organic boronic acids is reported. Alkenyl boronic acids have been successfully employed for the first time in Mn(I)-catalyzed carbon–carbon bond formation. A wide array of β-alkenylated amide products can be obtained in moderate to good yields, which offers practical access to five- and six-membered lactams. This protocol has predictable regio- and chemoselectivity, excellent functional group compatibility and ease of operation in air, representing a significant step-forward towards manganese-catalyzed C−C coupling. 相似文献
36.
Ping Chen Yanhong Hao Xinxin Wang Prof. Dr. Dan Yuan Prof. Dr. Yingming Yao Prof. Dr. Lutz Ackermann 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(30):7292-7297
Highly position selective alkylations of N-alkylindoles at C7-positions have been enabled by cationic zirconium complexes. The strategy provides a straightforward access to install alkyl groups at C7-positions of indoles without a complex directing group. Mechanistic studies provided support for the importance of Brønsted acids in the catalytic manifold. 相似文献
37.
Jin Xie Yun-Wei Song Dr. Bo-Quan Li Dr. Hong-Jie Peng Prof. Jia-Qi Huang Prof. Qiang Zhang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(49):22334-22339
Polysulfide intermediates (PSs), the liquid-phase species of active materials in lithium–sulfur (Li-S) batteries, connect the electrochemical reactions between insulative solid sulfur and lithium sulfide and are key to full exertion of the high-energy-density Li-S system. Herein, the concept of sulfur container additives is proposed for the direct modification on the PSs species. By reversible storage and release of the sulfur species, the container molecule converts small PSs into large organosulfur species. The prototype di(tri)sulfide-polyethylene glycol sulfur container is highly efficient in the reversible PS transformation to multiply affect electrochemical behaviors of sulfur cathodes in terms of liquid-species clustering, reaction kinetics, and solid deposition. The stability and capacity of Li-S cells was thereby enhanced. The sulfur container is a strategy to directly modify PSs, enlightening the precise regulation on Li-S batteries and multi-phase electrochemical systems. 相似文献
38.
姚民雄 《无锡职业技术学院学报》2004,3(4):40-42
研究性学习是实施素质教育和创新教育的一种新型教学方式。在工科类课程的教学中 可采用引入一个工程项目,通过项目设计来学习研究新知识,完成教学计划。 相似文献
39.
本文依据大学生生理、心理的阶段特征,通过变换组织教法以及增强学生主体、教师主导的双边作用,分析排球课的项目特点。使技能学习和人格发展相结合,培养身心健康发展的大学生。 相似文献
40.
科技论文中“关键词”的标引方法 总被引:1,自引:0,他引:1
姚密红 《太原师范学院学报(自然科学版)》2003,2(1):89-91
从关键词在文献检索中的重要作用论述了科技论文的发表,必须重视关键词的标引.明确指出出版专业中关键词的概念,探讨了不同标引方法的利弊,介绍了关键词的标引方法. 相似文献