全文获取类型
收费全文 | 29199篇 |
免费 | 3857篇 |
国内免费 | 2735篇 |
专业分类
化学 | 14719篇 |
晶体学 | 260篇 |
力学 | 1250篇 |
综合类 | 186篇 |
数学 | 2064篇 |
物理学 | 7908篇 |
综合类 | 9404篇 |
出版年
2024年 | 131篇 |
2023年 | 578篇 |
2022年 | 818篇 |
2021年 | 964篇 |
2020年 | 919篇 |
2019年 | 845篇 |
2018年 | 741篇 |
2017年 | 718篇 |
2016年 | 1082篇 |
2015年 | 1165篇 |
2014年 | 1413篇 |
2013年 | 1767篇 |
2012年 | 2152篇 |
2011年 | 2213篇 |
2010年 | 1542篇 |
2009年 | 1428篇 |
2008年 | 1651篇 |
2007年 | 1657篇 |
2006年 | 1454篇 |
2005年 | 1355篇 |
2004年 | 1007篇 |
2003年 | 859篇 |
2002年 | 850篇 |
2001年 | 703篇 |
2000年 | 685篇 |
1999年 | 922篇 |
1998年 | 722篇 |
1997年 | 800篇 |
1996年 | 654篇 |
1995年 | 640篇 |
1994年 | 620篇 |
1993年 | 517篇 |
1992年 | 423篇 |
1991年 | 410篇 |
1990年 | 359篇 |
1989年 | 291篇 |
1988年 | 220篇 |
1987年 | 188篇 |
1986年 | 118篇 |
1985年 | 70篇 |
1984年 | 49篇 |
1983年 | 25篇 |
1982年 | 26篇 |
1981年 | 18篇 |
1980年 | 15篇 |
1975年 | 2篇 |
1957年 | 4篇 |
1936年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
981.
The influences of steady aerodynamic loads on hunting stability of high-speed railway vehicles were investigated in this study.A mechanism is suggested to explain the change of hunting behavior due to actions of aerodynamic loads:the aerodynamic loads can change the position of vehicle system(consequently the contact relations),the wheel/rail normal contact forces,the gravitational restoring forces/moments and the creep forces/moments.A mathematical model for hunting stability incorporating such influences was developed.A computer program capable of incorporating the effects of aerodynamic loads based on the model was written,and the critical speeds were calculated using this program.The dependences of linear and nonlinear critical speeds on suspension parameters considering aerodynamic loads were analyzed by using the orthogonal test method,the results were also compared with the situations without aerodynamic loads.It is shown that the most dominant factors a ff ecting linear and nonlinear critical speeds are different whether the aerodynamic loads considered or not.The damping of yaw damper is the most dominant influencing factor for linear critical speeds,while the damping of lateral damper is most dominant for nonlinear ones.When the influences of aerodynamic loads are considered,the linear critical speeds decrease with the rise of cross wind velocity,whereas it is not the case for the nonlinear critical speeds.The variation trends of critical speeds with suspension parameters can be significantly changed by aerodynamic loads.Combined actions of aerodynamic loads and suspension parameters also a ff ect the critical speeds.The effects of such joint action are more obvious for nonlinear critical speeds. 相似文献
982.
X. J. Cheng B. X. Jiang L. Li J. L. Wang Zh. G. Yang W. B. Cheng X. Ch. Shi Y. B. Pan 《Laser Physics》2012,22(4):652-655
Lasers from Yb:YAG ceramic at different temperature were reported in this paper. The Yb:YAG ceramic laser with active-mirror
structure was end-pumped by a laser diode whose central wavelength was 940 nm. At 80 K, with doping concentration of 5 at
% Yb:YAG ceramic slab, output energy of 0.68 J at 10 Hz repetition rate was obtained under the pump energy of 2.49 J, corresponding
to a slope efficiency of 40% and a conversion efficiency of 27.3%, respectively. 相似文献
983.
984.
Lihua Zuo Heng Meng Jingjing Wu Zhen Jiang Shuying Xu Xingjie Guo 《Journal of separation science》2013,36(3):517-523
In this study, the enantioseparation of zopiclone, repaglinide, chlorphenamine maleate, brompheniramine maleate, dioxopromethazine hydrochloride, promethazine hydrochloride, liarozole, carvedilol, homatropine hydrobromide, homatropine methylbromide, venlafaxine, and sibutramine hydrochloride has been investigated using β‐CD in combination with a chiral ionic liquid (IL), 1‐ethyl‐3‐methylimidazolium‐L‐lactate. The influence of the type of IL and its concentration, BGE pH, and chain length of the IL cations on the resolution are discussed. Finally, the proposed method was successfully applied for the chiral impurity determination of eszopiclone in pharmaceutical tablets after validation with respect to accuracy and precision, linearity range, selectivity, repeatability, LOD and LOQ. It is assessed that the chiral impurity determination in the commercial tables is fewer than 0.1%. 相似文献
985.
以对甲氧基乙二醛一水合物、3-苯氨基-5,5-二甲基-2-环己烯-1-酮和4-硝基苯胺为原料,对甲苯磺酸为催化剂,在乙醇溶剂中,微波辐射下多组分一步法合成标题化合物C29H27N3O4.其结构通过单晶X射线衍射法确定,晶体属三斜晶系,空间群P1,Mr=481.54,晶胞参数:a=0.617 80(5)nm,b=1.291 04(11)nm,c=1.606 78(13)nm,V=1.237 45(18)nm3,Z=2,Dc=1.292 Mg·m-3,μ=0.087mm-1,F(000)=508.晶体结构用直接法解出,经全矩阵最小二乘法对原子参数进行修正,最终的偏离因子R=0.059 3,Rw=0.134 8.在晶体结构中新形成的吡咯环为芳构化的共平面结构. 相似文献
986.
Yi Yuan Zong-Lin Jiang Jia-Ming Yan Ge Gao Albert S. C. Chan Ru-Gang Xie 《合成通讯》2013,43(24):4555-4561
Two new macrobicyclic imidazolium and benzimidazolium phanes were synthesized by direct quaternization of the corresponding tripodal azacycles with tribromide under high dilution condition in excellent yields. The cyclophanes were identified by 1H-NMR, 13C-NMR, FAB-MS, IR, elemental analysis and X-ray diffraction analysis. 相似文献
987.
Jiang Bolong Muddemann Thorben Kunz Ulrich Haupt Dennis Bormann Hinnerk Niedermeiser Michael Schläfer Ottmar Sievers Michael 《Research on Chemical Intermediates》2018,44(1):639-655
Research on Chemical Intermediates - Effective methods for graphite felt (GF) treatment based on Fenton’s reagent treatment and thermal modification have been used to improve microbial fuel... 相似文献
988.
A Pd-catalyzed haloallylation of alkynes with allyl alcohols in ionic liquids has been reported. Both chloroallylation and bromoallylation can be easily carried out with high selectivity. A variety of 1,4-dienes were formed in moderate to excellent yields. The reaction system of the Pd catalyst as well as the ionic liquid can be recycled for several times. And the ionic liquid acts as not only a solvent in the reaction, but also provides the excess halide ions to control Z/E selectivity and acts as a ligand inhibit the β-hydride elimination. 相似文献
989.
Jing Luo Sisi Jiang Yong Wu Meiling Chen Xiaoya Liu 《Journal of polymer science. Part A, Polymer chemistry》2012,50(23):4888-4894
A facile method of producing stable aqueous dispersion of graphene/polyaniline (PANI) composite is described, which involves the in situ polymerization of aniline on the surface of graphene with the aid of polystyrene sulfonic acid (PSS). The prepared aqueous graphene/PANI composite dispersion was very stable and no aggregation or precipitation was observed for several weeks. The excellent aqueous dispersibility and stability of the graphene/PANI composite is attributed to the cooperative interactions of π stacking interaction between PSS, PANI, and the graphene basal planes, and the electrostatic repulsions between negatively charged PSS bound on graphene/PANI composite. Fourier transform‐infrared spectrometry (FTIR), ultraviolet‐visible spectra (UV–vis), and Raman spectra confirmed the interaction of PANI and graphene in the composite, which effectively delocalize the electrons. In addition, the composite showed three orders of magnitude of conductivity increase compared with pure PANI. This new approach is simple, fast, and straightforward, representing a significant improvement in the processing of graphene/PANI composites. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
990.
Shaoyong Ke Zhigang Zhang Ya-Ni Zhang Liqiao Shi Ronghua Zhou Aibing Jiang Ying Liang Ziwen Yang 《Research on Chemical Intermediates》2012,38(8):1827-1837
A novel series of ether functionalization of spiro-tetronic acid derivatives have been designed and conveniently synthesized via three steps, including esterification, one-pot heterocyclization, and etherification reactions. The target molecules have been identified on the basis of analytical spectra data. All newly synthesized compounds have been screened for their potential insecticidal activity against Heliothis armigera and Plutella xylostella compared with spirodiclofen by standard method. 相似文献