Gd激光等离子体的双电子复合过程研究

在自旋-轨道劈裂阵模型下,通过类铜的内壳层激发组态计算了类镍Gd的双电子复合速率系数,其中考虑了共振和非共振辐射平衡跃迁对自电离能级的影响,而忽略了因碰撞跃迁引起的电子俘获,非共振辐射平衡跃迁在低电子温度条件下主要影响双电子复合过程;本文讨论了双电子复合系数及双电子伴线强度比随电子温度的变化.     

Optical Planar Waveguides in KTiOPO4 Crystals by MeV Oxygen Ion Implantation

We report on the optical planar waveguide formation in KTiOPO4 crystals by single or double oxygen ion implantation at energies of 2.4-3.0 MeV and doses of 1015 ions/cm^2. The dark-line spectroscopy properties are investigated by a prism-coupling method. With an effective refractive index method, the refractive index profiles of the waveguides are reconstructed. The program code TRIM＇98 （transport of ions in matter） is used to simulate the implantation process of oxygen ions into the KTiOPO4 crystal. It is found that an inherent relationship exists between the nuclear damage and the refractive index changes induced by the ion-beam implantation.     

圆偏振飞秒激光脉冲与低压氙气体靶相互作用软X射线辐射实验研究

利用平场光栅谱仪,分别在2和3 kPa的低气压下,测量了脉宽35 fs的圆偏振超强超短激光脉冲与5 mm长氙气体靶相互作用产生的波长在5～60 nm范围内的离子谱线。2 kPa时最强的跃迁为XeⅧ：4d105s(2S_1/2)—4d95s5p(2P_3/2)的17.085 6 nm线,3 kPa时最强的跃迁为11.343 nm的XeⅦ 4d105s2(1S0)—4d95s25f(3P₁)跃迁。两种气压下,Xe均被电离到XeⅦ,XeⅧ,XeⅨ态。     

Advances in micro-perforated panel absorbers

Theoretical and experimental investigations on the performance of micro-perforated -panel absorbers are reviewed in this paper. By reviewing recent research work, this paper reveals a relationship between the maximum absorption coefficient and the limit of the absorption frequency bandwidth. It has been demonstrated that the absorption frequency bandwidth can be extended up to 3 or 4 octaves as the diameters of the micro-holes decrease. This has become possible with the development of the technologies for manufacturing micro-perforated panels, such as laser drilling, powder metallurgy, welded meshing and electro-etching to form micrometer order holes. In this paper, absorption characteristics of such absorbers in random fields and in high sound intensity are discussed both theoretically and experimentally. A new absorbing structure based on micro-perforated-panel absorbers demonstrate experimentally high sound absorption capability. This review shows that the micro-perforated-panel absorber has potentials to be one of ideal absorbing materials in the 21st century.     

氧族元素对D-A和D-π-A共聚物光吸收谱红移的第一性原理研究

D-A型共聚物作为有机聚合物太阳能电池的电子给体材料近年来引起广泛关注. 本文以苯并二噻吩(BDT)为电子给体单元, 苯并噻二唑(BT)为电子受体单元来模拟D-A共聚体; 并用噻吩环作为π桥, 构造出D-π-A(PBDT-DTBX, X = O, S, Se, Te)结构. 采用第一性原理的密度泛函理论, 系统地计算相应的电子结构和光吸收谱. 比较不同氧族元素和噻吩π-键桥对聚合物光吸收谱的影响. 研究结果表明: D-A共聚体中当X位元素以O, S, Se, T_e 替换时, 其体系的最高占有分子轨道(HOMO)能级变化不大, 最低未占有分子轨道(LUMO)能级逐渐靠近费米能级, 带隙逐渐减小. 在可见光区有两个较强的吸收峰, 随着X位元素原子序数增大, 位于4.0 eV左右的光吸收峰位基本不变, 另一光吸收峰强度明显增大并发生红移. 与D-A结构相比, D-π-A结构的带隙均有所减小, 其中X为Te时带隙最小; 光吸收峰强度随着氧族元素原子序数的增大也明显增大并发生红移. 通过比较光吸收系数和相应态密度, 结果表明, 4.0 eV 左右的光吸收峰主要是BDT单元的贡献, 氧族元素的改变主要影响519.4-703.9 nm范围的光吸收.     

基于生物视觉center-surround机制的光团目标检测与跟踪

基于生物视觉的center-surround机制,提出一种用改进的LoG(Laplacian of Gaussian)算子检测光团目标的方法。首先明确了光团目标的成像模型,分析了LoG算子的性质及其响应,接着提出了归一化的LoG算子。理论上指出该算子可用于检测光团目标。仿真和实验证明：该算子可以用于检测图像中已知大小和未知大小的光团目标,并且实用性优于其他常规方法。结合Kalman滤波和粒子滤波,该算子还可以用于序列图像中单目标和刚体的跟踪。理论推导和实验结果表明,该方法是稳健和高效的。     

酯基取代的吲哚衍生物的红外和荧光光谱研究

Tryptophan derivatives have long been used as site-specific biological probes. 4-Cyanotryptophan emits in the visible region and is the smallest blue fluorescent amino acid probe for biological applications. Other indole or tryptophan analogs may emit at even longer wavelengths than 4-cyanotryptophan. We performed FTIR, UV-Vis, and steady-state and time-resolved fluorescence spectroscopy on six ester-derivatized indoles in different solvents. Methyl indole-4-carboxylate emits at 450 nm with a long fluorescence lifetime, and is a promising candidate for a fluorescent probe. The ester-derivatized indoles could be used as spectroscopic probes to study local protein environments. Our measurements provide a guide for choosing esterderivatized indoles to use in practice and data for computational modeling of the effect of substitution on the electronic transitions of indole.     

不同启动加速度下离心泵瞬态水力性能的试验研究

为了研究离心泵在不同加速度下的启动特性,对一台小型离心泵进行启动试验研究.介绍了试验装置、数据测试方法以及不同加速度的调节方法.在测试模型泵的稳态性能和基本瞬态性能基础上,测试和分析了不同启动加速度对瞬态性能的影响.结果显示,启动过程中,在转速到达最大值附近,瞬态扬程明显小于准稳态预测值,且不同加速度下两者的偏离明显不同;并且在各加速度条件下,瞬态工况到达泵的最佳效率工况点后瞬态性能得到提高.     

Versatile Nitro-Fluorophore as Highly Effective Sensor for Hypoxic Tumor Cells: Design, Imaging and Evaluation

Based on the characteristics of a nitro-group, which can be partially or totally reduced to an amino-group in hypoxic cells, two series of hypoxic sensors containing 7H-Benzimidazole [2,1-a]benz[de]isoquinolin-7-one cores with nitro groups in different positions were designed, synthesized and evaluated. The target compounds exhibited significantly different fluorescence characteristics (fluorescence enhancement or quenching). The strong fluorescences of some partially reduced compounds could be explained through the examination of their infrared spectra, which showed a restriction of the nitro-group vibration. These compounds exhibited significant hypoxic–oxic fluorescence differences not only in numerical values but also in their fluorescent imaging properties as reported for the first time.      

利用一种偏振方法减小由强反射或弱反射强度引起的植被反演误差

无论是多角度遥感的发展、还是偏振、高光谱遥感的发展,它们有一个相同的目的,即利用电磁波的种种特性、以及空间特性来对地球表面的一切地物进行精确的识别。任何单一的方法和手段不可能完整地描述和反映地物的所有特征。偏振测量是目标测量识别技术中不可缺少的技术之一,并且成为近年来全世界目标识别领域中的研究热点。由于定量遥感的反射强度对植被遥感的影响不可忽视,反射辐射信号呈现饱和或过弱都不能被检测到。而偏振是植被定量遥感的重要手段,因而有必要开发一种克服由反射强度强弱引起的植被反演误差的方法,这也是我们目前的研究目标。如果反射的辐射信号太强或太弱,都会影响遥感的准确性,而来自植被的偏振光可以提供有用的信息,特别是当反射的辐射信号饱和时,使得传感器不能获得足够有用的非偏振信息。本研究采用基于地面的偏振成像光谱仪系统,开发了一种偏振方法来克服反射强度过强过弱引起的植被反演误差。利用FISS-P偏振成像光谱仪系统研究了反射强度对遥感植被NDVI和DoLP效用的影响,实验地点在北京市中国科学院奥林匹克科技园。在对目标采样时对反射率强,反射率弱以及反射率适中的植被分别测量,同时对目标植被的不同波段(470, 555, 670, 864 nm)的DoLP进行计算与分析。地基成像光谱仪系统(FISS-P)提供了具有偏振信息的高空间分辨率图像,我们可以确定在阴影和强反射区域中单个像素的光谱偏振特性。在成像光谱信息的基础上,利用光的偏振性来对地物的物理特性进行分析。本文使用斯托克斯分量来表征反射光的各个偏振分量,使用线偏振度(DoLP)表征反射光偏振程度。信号饱和度和阴影效应导致归一化植被指数(NDVI)植被密集程度非常低,造成严重的反演误差,然而强反射对线偏振度(DoLP)的影响不大。研究结果表明,反射辐射信号饱和时,偏振效应可以通过适当的频带提高植被的反演精度,平均NDVI的相对误差为33.8％,而DoLP(670 nm)的相对误差仅为6.3％,而其他波段的DoLP(555 nm,864 nm)的相对误差要大很多。这项研究结果表明,在植被识别时可以忽略强反射,然而,阴影(弱反射)效应是不容忽视的。FISS-P偏振成像光谱仪是用于计算具有不同反射强度的样品类型的偏振和非偏振参数的有效工具,同时发现在识别植被时,强烈的反射可以忽略不计,但是植被的阴影(弱反射)效应不容忽视。与非偏振方法相比,偏振效应可以提高反射辐射信号饱和时的植被反演精度。这项研究分析了使用偏振法强弱反射强度引起的误差减少。为了进一步揭示植被的阴影(弱反射)效应与DoLP之间的关系,还有一些问题需要解决。