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131.
Parcerisa J Casals I Boatella J Codony R Rafecas M 《Journal of chromatography. A》2000,881(1-2):149-158
We analysed the triacylglycerol, tocopherol and sterol composition of hazelnut oil, olive oil and their mixtures (90% olive oil with 10% hazelnut oil, 70% olive with 30% hazelnut oil and 50% olive oil with 50% hazelnut oil). The main triacylglycerols were 1,2,3-trioleylglycerol, 2,3-dioleyl-1-palmitoylglycerol, 2,3-dioleyl-1-linoleylglycerol and 2,3-dioleyl-1-stearoylglycerol. Non-saponfiable compounds (tocopherols and sterols) were derivatised as O-trimethylsilyl ethers. Alpha-tocopherol was the main vitamin E isomer in all samples; however, small amounts of beta-tocopherol and gamma-tocopherol were also found. Beta-sitosterol and delta5-avenasterol were the principal sterols in all samples; campesterol and stigmasterol were minor sterol compounds in all samples. Obtusifoliol, which was a major sterol in olive oil and oil mixtures, was not found in hazelnut oil. The discriminant analysis showed that hazelnut oil, olive oil and oil mixtures were clearly separated according to their triacylglycerol composition. 相似文献
132.
Yoshikawa M Morikawa T Murakami T Toguchida I Harima S Matsuda H 《Chemical & pharmaceutical bulletin》1999,47(3):340-345
The methanolic extract from the flowers of Chrysanthemum indicum L., Chrysanthemi Indici Flos, was found to show inhibitory activity against rat lens aldose reductase. By bioassay-guided separation, the active components, such as flavone and flavone glycosides, were isolated from the extract together with three new eudesmane-type sesquiterpenes, kikkanols A, B, and C. The structures of kikkanols A, B, and C were elucidated on the basis of chemical and physicochemical evidence, which included application of the modified Mosher's method. 相似文献
133.
Bonvin Y Callens E Larrosa I Henderson DA Oldham J Burton AJ Barrett AG 《Organic letters》2005,7(21):4549-4552
[reaction: see text] Oxidation of alkyl and cycloalkyl arenes with tert-butyl hydroperoxide catalyzed by bismuth and picolinic acid in pyridine and acetic acid gave the corresponding benzylic ketones (48-99%). Alternatively, oxidation of methyl arenes gave the corresponding substituted benzoic acids (50-95%). Preliminary mechanistic studies were consistent with a radical mechanism rather than a bismuth(III)-bismuth(V) cycle. 相似文献
134.
Fuks-Janczarek I Luc J Sahraoui B Dumur F Hudhomme P Berdowski J Kityk IV 《The journal of physical chemistry. B》2005,109(20):10179-10183
We have revealed a substantial enhancement of third-order optical figure of merits by the synthesis of a compact molecule possessing the tetrathiafulvalene (TTF) group with two backside C=O groups. Addition of the saturated methylene chain substantially suppresses the third-order optical figure of merits and even local optical hyperpolarizabilities at lambda = 532 nm. Another TTF-derivative molecule possessing ethylenic and acetylenic chains demonstrates large hyperpolarizabilities; however, generally, the figure of merit factor decreases due to the increasing optical losses as a consequence of enhanced linear absorption. At the same time, both of the chromophores have a large nonlinear optical response. General approaches for search and design of the third-order optical materials with improved properties are given. 相似文献
135.
Matsuda H Morikawa T Toguchida I Harima S Yoshikawa M 《Chemical & pharmaceutical bulletin》2002,50(7):972-975
Two new flavanone glycosides, (2S)- and (2R)-eriodictyol 7-O-beta-D-glucopyranosiduronic acids, and a new phenylbutanoid glycoside, (2S, 3S)-1-phenyl-2,3-butanediol 3-O-beta-D-glucopyranoside, were isolated from the flowers of Chrysanthemum indicum L. cultivated in China together with eight flavonoids. The absolute stereostructures of the new compounds were determined on the basis of chemical and physicochemical evidence. Both of the new flavanone glycosides were found to show inhibitory activity for rat lens aldose reductase. 相似文献
136.
Coldham I Crapnell KM Fernàndez JC Moseley JD Rabot R 《The Journal of organic chemistry》2002,67(17):6181-6187
A synthesis of the core ABC ring system of the manzamine alkaloids is described, starting from arecoline. The key steps involve a Claisen rearrangement to set up a 4-substituted-3-methylenepiperidine and a stereoselective azomethine ylide dipolar cycloaddition reaction. Condensation of the aldehyde 6 and sarcosine ethyl ester hydrochloride salt gives an intermediate azomethine ylide, which undergoes an intramolecular cycloaddition reaction to set up two new rings and three new chiral centers stereoselectively. The aldehyde 6 was not a suitable substrate for related azomethine ylide cycloaddition reactions with other amines. However, the related dimethyl acetal 26 could be condensed with a variety of amines to give the desired tricyclic products. The cycloaddition reaction with N-methyl or N-allyl glycine ethyl ester gave almost exclusively the exo adduct, whereas cycloaddition with glycine ethyl ester gave the endo adduct. 相似文献
137.
Díaz MC Illescas BM Martín N Viruela R Viruela PM Ortí E Brede O Zilbermann I Guldi DM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(8):2067-2077
A new class of pi-extended TTF-type electron donors (11 a-c) has been synthesized by Wittig-Horner olefination of bianthrone (9) with 1,3-dithiole phosphonate esters (10 a-c). In cyclic voltammetry experiments, donors 11 a-c reveal a single, electrochemically irreversible oxidation-yielding the corresponding dicationic products-at relatively low oxidation potentials (approximately 0.7-0.8 V). Theoretical calculations, performed at the DFT level (B3 P86/6-31 G*), predict a highly-folded C(2h) structure for 11 a. In the ground state, the molecule adopts a double saddle-like conformation to compensate the steric hindrance. The calculations suggest that the intramolecular charge transfer associated with the HOMO-->LUMO transition is responsible for an absorption band observed above 400 nm. While the radical cation 11 a*+ retains the folded C(2h) structure predicted for the neutral molecule as the most stable conformation, the dication 11 a(2+) has a fully aromatic D(2) structure, formed by an orthogonal 9,9'-bianthryl central unit to which two singly-charged dithiole rings are attached. The drastic conformational changes that compounds 11 undergo upon oxidation account for their electrochemical properties. By means of pulse radiolysis measurements, radical-induced one-electron oxidation of 11 a-c was shown to lead to the radical cation species (11 a-c*+), which were found to disproportionate with generation of the respective dication species (11 a-c(2+)) and the neutral molecules (11 a-c). 相似文献
138.
Tomazela DM Gozzo FC Mayer I Engelmann FM Araki K Toma HE Eberlin MN 《Journal of mass spectrometry : JMS》2004,39(10):1161-1167
Ten homologous or isomeric singly, doubly, triply and quadruply charged cationic macrocyclic complexes I-Va, bn+ (n = 1-4) formed by the coordination of [Ru(bipy)2Cl]+ to the pyridyl N-atoms of a series of meso-(phenyl)m-(meta or para-pyridyl)n-porphyrins (m + n = 4) were transferred to the gas phase and structurally characterized by electrospray ionization (ESI) mass (MS) and tandem mass (MS/MS) spectrometry. Previously known to be stable in solution and in the solid state, I-Va, bn+ are found to constitute also a new class of stable, long-lived multiply charged gas-phase ions with spatially separated charge sites. Increasing intramolecular electrostatic repulsion from Ia, b+ to IVa, b3+ facilitates in-source and tandem collision-induced dissociation (CID). However, for the quadruply charged ions Va, b4+, electrostatic repulsion is alleviated mainly by ion pairing with the CF3SO3- counterion forming the salt clusters [Va,b/CF3SO3]3+ and [Va,b/(CF3SO3)2]2+ with reduced charge states. Ion-pairing that yields [IVa,b/CF3SO3]2+ is also observed as a minor ESI process for the triply charged ions IVa, b3+. The gaseous ions I-Va, bn+ (n = 2, 3 or 4) dissociate by sequential 'charge partitioning' with the formation of two cationic fragments by the release of [Ru(bipy)2Cl]+. The meta (a) and para (b) isomers and the positional isomers II2+ and III2+ display nearly identical ESI-MS and ESI-MS/MS spectra. ESI-MS/MS of I-Va, bn+ shows that the Ru-py(P) is, intrinsically, the weakest bond since this bond breaks preferentially upon CID. 相似文献
139.
The extraction behaviour of copper(II) and silver(I) with 2-(3,6,10,13-tetrathiacyclotetradec-1-oxy)hexanoic acid (TTCTOHA) was investigated at 25+/-0.1 degrees C and ionic strength of 0.1. The value of the logarithmic distribution coefficient, logK(DR) of TTCTOHA between octan-1-ol and aqueous phases was determined to be 4.13. Copper(II) was extracted with TTCTOHA into octan-1-ol as CuL(2), where L represents the anionic species of TTCTOHA. The logarithmic extraction constant, logK(ex(10)), was determined at -7.42. Silver(I) was extracted with TTCTOHA into octan-1-ol as AgL and Ag(2)L(2). The logarithmic distribution constant, logK(DC), of AgL was estimated to be 0.49. On the other hand, silver(I) was extracted into 1,2-dichloroethane as AgL and the logarithmic extraction constant, logK(ex(10)), was determined to be -2.24. 相似文献
140.
Direct optical detection of singlet oxygen from a single cell 总被引:1,自引:0,他引:1
Zebger I Snyder JW Andersen LK Poulsen L Gao Z Lambert JD Kristiansen U Ogilby PR 《Photochemistry and photobiology》2004,79(4):319-322
Singlet oxygen has been detected in single nerve cells by its weak 1270 nm phosphorescence (a1deltag --> X3sigmag-) upon irradiation of a photosensitizer incorporated in the cell. Thus, one can now consider the application of direct optical imaging techniques to mechanistic studies of singlet oxygen at the single-cell level. 相似文献