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911.
Egyptian Portland Cement in the form of one inch cube was hydrated at different times of hydration. Nine cubes of each period of hydration were heated for five minutes 200, 300, 400 up to 1000°C then were quenched in air. The compressive strength was measured for these samples and related to unheated ones. These cubes were ground and measured by Mössbauer spectrometry to correlate the effect of dehydration of cement pastes on the states of iron, with the decrease of compressive strength. It was observed that starting from 400°C the central doublet characteristic of the hydration process decreased as the dehydration temperature was increased. At 1000°C the dehydration process was complete, the central doublet disappeared and the compressive strength vanished. The hydration process was found to be reversible. The application of Mössbauer spectrometry to estimate the degree of fire in concrete building was demonstrated. 相似文献
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914.
本文给出能在一般单向加载液压疲劳试验机上做双轴等拉低周疲劳实验研究的双向拉伸装置,并对有关影响因素进行了讨论。 本试验是在百吨液压低周疲劳试验机上进行的。双向拉体装置已经受近百万次疲劳载荷,其中交变载荷幅围5.5,t亦经受近20万次。在使用过程,各构件完好合手使用要求,将十字试样进行低周疲劳断裂试验,成功地开出合格裂纹,用它进行超速条件下叶轮材料性能研究亦取得初步结果。可以认为它适用于平而应力集中问题低周疲劳性能的研究。若使用液压高、中周疲劳试验机,它还可用于双轴载荷下裂纹试样裂纹扩展的研究。 本文指出了双向拉伸装置有待改进的方面。 相似文献
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916.
Mironov YV Yarovoi SS Naumov DY Kozlova SG Ikorsky VN Kremer RK Simon A Fedorov VE 《The journal of physical chemistry. B》2005,109(50):23804-23807
The novel vanadium thiobromide, V4S9Br4, with a square-planar metal cluster core was synthesized and characterized by single-crystal X-ray diffraction, measurements of magnetic properties and the heat capacity, and DFT calculations of the electronic structure. At the room temperature, the compound displays paramagnetic properties with an independent spin on each V atom and with a weak exchange constant (J approximately 10 cm(-1)). The paramagnetic state is transformed into a low-spin state (AF-type ordering) at low temperatures. This change is accompanied by a heat-capacity anomaly. The observed magnetic and heat-capacity anomalies can be explained by the thermal excitation of electrons on the closely spaced molecular energy levels in the presence of the Jahn-Teller effect. 相似文献
917.
聚合物电致发光材料研究进展 总被引:5,自引:0,他引:5
本文较详细地综述了聚合物电致发光材料的研究进展,重点介绍了聚对苯撑乙烯(PPV),并提出了有关聚合物电致发光材料及器件构造研究的一些观点。 相似文献
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Xu ZK Dai QW Wu J Huang XJ Yang Q 《Langmuir : the ACS journal of surfaces and colloids》2004,20(4):1481-1488
A novel method for the surface modification of a microporous polypropylene membrane by tethering phospholipid analogous polymers (PAPs) is given, which includes the photoinduced graft polymerization of N,N-dimethylaminoethyl methacrylate (DMAEMA) and the ring-opening reaction of grafted poly-(DMAEMA) with 2-alkyloxy-2-oxo-1,3,2-dioxaphospholanes. Five 2-alkyloxy-2-oxo-1,3,2-dioxaphospholanes, containing octyloxy, dodecyloxy, tetradecyloxy, hexadecyloxy, and octadecyloxy groups in the molecular structure, were used to fabricate the PAP-modified polypropylene membranes. The attenuated total reflectance FT-IR spectra of the original, poly(DMAEMA)-grafted, and PAP-modified membranes confirmed the chemical changes on the membrane surface. Scanning electron microscope pictures showed that, compared with the original membrane, the surface porosities ofpoly(DMAEMA)-grafted and PAP-modified membranes were somewhat reduced. Water contact angles measured by the sessile drop method on PAP-modified membranes were slightly lower than that on the original polypropylene membrane, but higher than those on poly(DMAEMA)-grafted membranes with the exception of octyloxy-containing PAP-modified membranes. However, BSA adsorption experiments indicated that the five PAP-modified membranes had a much better protein-resistant property than the original polypropylene membrane and the poly(DMAEMA)-grafted membranes. For hexadecyloxy- and octadecyloxy-containing PAP-modified membranes, almost no protein adsorption was observed when the grafting degree was above 6 wt %. It was also found that the platelet adhesion was remarkably suppressed on the PAP-modified membranes. All these results demonstrate that the described approach is an effective way to improve the surface biocompatibility for polymeric membranes. 相似文献