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81.
Non-dispersive atomic fluorescence spectrometry (NDAFS) coupled with vapor generation (VG) sample introduction was applied to the determination of the concentrations of hazardous heavy metals, such as arsenic, cadmium, lead and mercury, in seawater, soils and total airborne particulate matter (PM) collected around the Xiamen area in China. Almost 100% sample introduction efficiency was achieved by using thiourea and ascorbic acid for the pre-reduction of As(V) to As(III), K3Fe(CN)6 and tartaric acid for pre-oxidation of Pb(II) to Pb(IV), and masking the interferences arising from the co-existing transition metals to As, Cd, Hg and Pb during their vapor generation process. Moreover, a novel sample pretreatment device was developed to avoid the loss of mercury, lead, cadmium and arsenic during sample pretreatment. With such methods, the detection limit (DL) of arsenic, cadmium, lead and mercury was down to 0.08, 0.03, 0.05, 0.01 ng mL(-1) (3sigma), respectively. The relative standard deviations (RSD, n = 11) for arsenic, cadmium, lead and mercury at 10 ng mL(-1) were 0.9%, 1.6%, 1.3% and 2.0%, respectively. The concentrations of hazardous heavy metals in the environmental samples collected in Xiamen, China are in the range from 0.02 +/- 0.001 ng mL(-1) in seawater to 15.3 +/- 0.2 microg g(-1) in soils. Besides flame/GF-AAS and ICP-AES/MS, VG-NDAFS should be another choice for the determination of hazardous heavy metals in environmental samples. 相似文献
82.
83.
JiangMinCHEN LuLingWU XianHUANG 《中国化学快报》2004,15(2):143-144
2,5-Disubstituted oxazoles were prepared conveniently by treatment of aromatic α-methyl ketones and nitriles with poly[styrene(iodosodiacetate)] in one-pot process. 相似文献
84.
We investigate the problem of locating a set of service facilities that need to service customers on a network. To provide service, a server has to visit both the demand node and one of several collection depots. We employ the criterion of minimizing the weighted sum of round trip distances. We prove that there exists a dominating location set for the problem on a general network. The properties of the solution on a tree and on a cycle are discussed. The problem of locating service facilities and collection depots simultaneously is also studied. To solve the problem on a general network, we suggest a Lagrangian relaxation imbedded branch-and-bound algorithm. Computational results are reported. 相似文献
85.
A polymer-supported diphenylphosphoryl azide was prepared. This polymer-supported version of DPPA is useful due to its lower toxicity, moisture tolerance and ease of workup after reaction. The synthetic application of this solid-phase reagent was explored by conversion of a variety of carboxylic acids to urethanes and ureas through Curtius rearrangement reactions. Carboxylic acids bearing different functional groups (aromatic, aliphatic and heterocyclic carboxylic acids) were subjected to the reaction. The corresponding products were isolated with satisfactory yields. 相似文献
86.
87.
Space time-index plots for probing dynamical nonstationarity 总被引:3,自引:0,他引:3
We propose a simple method to efficiently probe dynamical nonstationarity in observed time series. In a space time-index plot, the density distributions as a function of normalized time-index are V-shaped due to nonstationarity. We show that this method is workable for short data sets and typical examples are illustrated. 相似文献
88.
HANXI'AN HUANGXILI 《高校应用数学学报(英文版)》1998,13(4):445-450
For two rational quadratic B-spline curves with same control vertexes, the cross ratio of four eollinear points are represented; which are any one of the vertexes, and the two points that the ray initialing from the vertex intersects with the corresponding segments of the twocurves, and the point the ray intersecting with the connecting line between the two neighboring vertexes. Different from rational quadratic Beeier curves, the value is generally related with the loeation of the ray, and the necessary and sufficient condition o5 the ratio being independent of the ray‘s loeation is showed. Alsn another cross ratio o5 the following four collinear points are suggested, i.e. one vertex, the points that the ray from the initlal vertex intersects respectivdy with the curve segmentt the line connecting the segments end points, and the line connecting the two neighboring vertexes. This cross ratio is concerned only whh the ray‘s location, butnot with the weights of the curve. Furthermore, the cross ratio is projective invariant under the projective transformation between the two segments. 相似文献
89.
High resolution finite difference schemes for solving the nonlinear model Boltzmann equations are presented for the computations of rarefied gas flows. The discrete ordinate method is first applied to remove the velocity space dependency of the distribution function which renders the model Boltzmann equation in phase space to a set of hyperbolic conservation laws with source terms in physical space. Then a high order essentially nonoscillatory method due to Harten et al. (J. Comput. Phys. 71, 231, 1987) is adapted and extended to solve them. Explicit methods using operator splitting and implicit methods using the lower-upper factorization are described to treat multidimensional problems. The methods are tested for both steady and unsteady rarefied gas flows to illustrate its potential use. The computed results using model Boltzmann equations are found to compare well both with those using the direct simulation Monte Carlo results in the transitional regime flows and those with the continuum Navier-Stokes calculations in near continuum regime flows. 相似文献
90.
报道(一)-AnTx-a关键中间体的四步合成新途径,设计一个新型(一)-AnTx-a类似物并以同法合成其中间体,本法是对以Mannich反应为基础的AnTX-a的合成策略的补充。 相似文献