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991.
δ-Glyconolactams were first synthesized by the intramolecular Schmidt–Boyer reaction using corresponding δ-azidosugars as starting material. The reaction could be efficiently performed in good yields of 61–69% under microwave radiation in acid condition, providing an alternative protocol to iminosugar δ-lactam. 相似文献
992.
L LinHui Ye YanLin Jiang DongXing Hua Hui Zheng Tao Li ZhiHuan Ge YuCheng Li XiangQing Lou JianLing Cao ZhongXin Song YuShou Xiao Jun Li QiTe Qiao Rui You HaiBo Chen RuiJiu Xu HuShan Wang JianSong Guo ZhongYan Zhang XueYing Li Chen Hu ZhengGuo Chen RuoFu Wang Meng Xu ZhiGuo Yue Ke Tang Bin Zang YongDong Zhang XueHeng Yao XiangWu Chen JinDa Bai Zhen 《中国科学:物理学 力学 天文学(英文版)》2011,54(1):136-140
Knockout reaction experiment was carried out by using the 6He beams at 61.2 MeV/u impinging on a CH2 target. The α core fragments at forward angles were detected in coincidence with the recoiled protons at larger angles. From this exclusive measurement the valence nucleon knockout mechanism and the core knockout mechanism can be distinguished by the relation between the polar angles of the core fragments and the recoiled protons, respectively. It is demonstrated that the core knockout mechanism may result in some strong contamination to the real invariant mass spectrum.
相似文献993.
Xuefeng Yang Weibin Li Dao Hua Zhang 《Applied Physics A: Materials Science & Processing》2012,107(1):123-126
We present subwavelength periodic gratings achieved by employing a metallic grating waveguide heterostructure (MGWHS). The
mask can be designed to make one of its diffraction order (±mth) waves resonate with the surface plasmon wave supported by the MGWHS. With a finite-difference time-domain method, we numerically
demonstrate that one-dimensional periodic structure of about 60 nm feature, which is far beyond the diffraction limit, can
be patterned with the interference of the 3rd diffraction order waves of the mask at a wavelength of 546 nm. The technique
can also be extended to two-dimensional patterns using circularly polarized incidence and for the incidence with an angle
θ. 相似文献
994.
995.
996.
The possible inclusion modes of berberine(Berb)with β-cyclodextrin(BCD)in aqueous solution were predicted by molecular docking,molecular dynamics(MD)simulation and binding free energy calculations.Firs... 相似文献
997.
Dean Shi Xiao‐Yang Wang Hengchong Shi Jing‐Hua Yin Robert K. Y. Li Guo‐Hua Hu 《Journal of Polymer Science.Polymer Physics》2010,48(1):65-73
TEM micrographs show that the PA grafts of PS‐g‐PA6 graft copolymers, which are obtained directly by extracting homo‐PA6 out from the homo‐PA6/PS‐g‐PA6 blends, are in the form of wormlike structure. The wormlike PA6 domains can shrink into droplets after annealing at 250 °C for 15 min. The diameter of the droplet determined by TEM and SAXS is in the range of 50–60 nm. This article reports on a unique crystallization behavior of the PA6 grafts in PS‐g‐PA6 graft copolymers. In a DSC cooling scan, PA6 grafts do not crystallize from the melt with a cooling rate of 10 °C/min. However, there is a cold crystallization peak around 65 °C in the subsequent heating scan. This cold crystallization phenomenon, which has not yet been reported in the literature till now, follows well the homogeneous nucleation mechanism and is depressed at relatively slow cooling rates (2 °C/min) or even completely eliminated after annealing within a specific temperature range. It may be caused by the slow diffusion or transport rate of the less flexible PA6 grafts to the crystal fronts when crystallization takes place around its glass transition temperature. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 65–73, 2010 相似文献
998.
聚丙烯腈螯合纳米纤维的制备及其吸附性能研究 总被引:1,自引:0,他引:1
用羟胺试剂与聚丙烯腈纳米纤维通过化学反应将部分氰基转化为偕胺肟基团,制备一种改性的聚丙烯腈纳米纤维,并研究了该纤维对金属Pb2+的吸附性能.结果表明:改性的聚丙烯腈纳米纤维对Pb2+具有较好的吸附性能. 相似文献
999.
辛亥革命时期,孙中山以西方资产阶级伦理学说为理论武器,努力否定中国封建伦理对妇女的束缚。孙中山倡导男女平权,反对缠足恶俗对女子的形体压迫,尊重女性的人格尊严与权利,主张妇女成为具有独立人格与精神的新国民,提倡社会给予女性以特殊关爱。孙中山领导的辛亥革命促进中国妇女伦理发生历史性变革,有力推动了近代妇女解放和社会的文明进步。 相似文献
1000.
Three octacyanometallate‐based hetero‐bimetallic complexes, [Ln(H2O)4(CH3CN)2][M(CN)8] · CH3CN [Ln = La, M = Mo( 1 ), W( 2 ); Ln = Ce, M = W( 3 )], were synthesized and characterized structurally. Single‐crystal X‐ray analysis reveals that 1 – 3 are isomorphous and consist of infinite one‐dimensional (1D) 3,3 rope‐ladder chains, in which the 12‐membered puckered square Ln2M2(CN)4 is the basic building unit. The 1D chains are further linked through interchain hydrogen bonds, resulting in a three‐dimensional (3D) supramolecular network. 相似文献