Electronic Structure and Magnetic Properties of SmCo7-xZrx

The electronic structure and magnetism of SmCo_7-xZr_x alloy are investigated using the spin-polarized MS-X. method. The results show that a few of electrons are transferred to the Sm(5d⁰) orbital due to orbital hybridization between Sm and Co atoms. The exchange interactions between 3d and 5d electrons are more important than the polarization effects of the conductive electrons, thus it is the main reason resulting in the long-range ferromagnetic order in SmCo_7-xZr_x. The Curie temperature of SmCo_7-xZr_x is generally lower than that of corresponding pure Co, which may be explained by the weaker average coupling strength between Co lattices due to some negative couplings mainly occurring of 2e site. The calculated results for the Sm₅Co₃₂Zr₂ cluster may lead to a better understanding of why SmCo_7-xZr_x is stable phase. Since the spin-up DOS peak of d electrons at E_F arises and the bonding of electrons at E_F strengthens with increasing Zr concentration, which results in the internal energy of the system decrease, the stable ferromagnetic order forms in SmCo_7-xZr_x.     

发现一种声波传入内耳的新途径

对一位先天性外耳道缺失的患者调查发现，声波传入内耳，除了正常的骨传导和气传导以外，还存在着一种口鼻—咽—咽鼓管—中耳—内耳途径．     

为TP801单板机增加测频功能

电信号的频率是主要参数之一，对它的测量很重要，方法也很多。目前绝大多数采用数字式硬件电路来完成。但由于２８０—ＣＰＵ微处理器运算速度快，控制能力强，据测频原理，可采用软件秒脉冲和软硬件计数器来实现对频率的测量，为ＴＰ８０１单板机增加了测量功能，可一机多用。     

金汤桥开启系统的复原与改进

介绍了天津金汤桥活动跨开启系统的原貌、原状以及原缺陷，阐述了复原手动和电动开启系统的原则，并介绍了平转式开启桥的原理及构成．通过反复探索与研究，成功地复原了金汤桥活动跨手动和电动开启系统．提出了平转式活动跨机械传动系统的回转中心、活动跨的回转中心，以及桥墩中心的设计基准与安装基准必须服从三者同一性原理，并解决了这一平转式开启桥的难题．实践证明，复原后的活动跨开启系统安全、可靠、平稳、灵活．     

具有非常数回报率的证券指数跟踪问题的简单脉冲控制

运用随机脉冲控制理论讨论了均值 -方差模式的现金管理指数跟踪问题 ,在回报率随现金比重变化的情况下 ,讨论了证券指数跟踪最优化问题 ,得出了存在简单脉冲控制策略的充分性条件 .     

关于少数民族音乐教育中复合型架构模式的若干思考

少数民族音乐教育的属性是“复合性”。在人才培养、教师队伍建设等方面应按照复合型架构模式进行建设。即以汉族音乐教育为基础，少数民族音乐教育为特色，并借鉴西方音乐教育的建构模式，使少数民族专业音乐教育在多成分、多层次平衡发展的基础上，力求双向发展的最大值——向民族纵深和现代化尖端的两极扩展。     

三角形上拉普拉斯算子谱分析(Ⅱ)

运用Einstein级数的性质和Riemann-Mellin变换公式,得到了长方形和正三角形上Laplace算子的行列式和热方程核的前二项展开系数,发现它们与研究区域的面积和周长有关系.     

Novel photoswitching dithienylethenes with ferrocene units

Two novel dithienylethenes with ferrocene units were synthesized by Wittig reaction. The structure of 2a has been established by X‐ray diffraction studies. They could reversibly interconvert between two thermally stable forms, an open and a closed one, using light of different wavelengths as triggers. Copyright © 2006 John Wiley & Sons, Ltd.     

Simple synthesis of aminoquinoline/ethylaniline copolymer semiconducting nanoparticles

Pure copolymer nanoparticles from 8-aminoquinoline (AQ) and 2-ethylaniline (EA) were easily synthesized by a chemically oxidative polymerization in three different aqueous media. The potential and temperature of polymerization solution were used to successfully follow the polymerization progress. The molecular and morphological structures of the resulting AQ/EA copolymer particles were systematically characterized by IR, UV/Vis, NMR, gel permeation chromatography, laser particle-size analysis, atomic force and transmission electron microscopy. The oxidation potential of the monomers as well as the polymerization yield, structure, and properties of the particles were found to significantly depend on AQ/EA ratio, polymerization temperature and medium. It is surprisingly found that AQ homopolymerization and AQ/EA (50:50) copolymerization at 5 degrees C in HCl simply afford nano-ellipsoids with the major/minor axis diameters of 24/14 nm and 80/67 nm, respectively. A simple method of synthesizing semiconducting pure nanoparticles by introducing the AQ units with positively charged quaternary ammonium groups but in the absence of adscititious stabilizer or sulfonic substituent on the monomers is established first. Both the molecular weight and bulk electroconductivity of the copolymers exhibit a maximum at AQ content of 10 mol %. The solubility and film formability of the copolymers are good in highly polar solvents and reach the optimal at the AQ content of 20 and 10 mol %, respectively.     

Synthesis and electrospray ionization mass spectra of AZT/d4T boranophosphates

New anti-HIV prodrugs, conjugates of AZT and d4T with boranophosphates, were prepared by the H-phosphonate method. Their structures were determined by negative ion electrospray ionization mass spectrometry (ESI-MS) in conjunction with tandem mass spectrometry (MS/MS). The fragmentation pathways were investigated, and most of the fragment ions contained the boranophosphate or phosphinate group.