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951.
952.
Zhishen Mo Lixiao Wang Hongfang Zhang Ping Han Baotong Huang 《Journal of Polymer Science.Polymer Physics》1987,25(9):1829-1837
Wide-angle X-ray scattering from presumed block copolymers of polypropylene (PP) and ethylene-propylene copolymer (EPR), i.e., PP-EPR and PP-EPR-PP, synthesized by sequential polymerization with δ-TiCl3? Et2AlCl, was examined and compared with WAXS of mechanical blends and chain-transfer mixtures of PP and EPR with comparable compositions. The peak at 2θ = 20° for both the copolymers and the mixtures was attributed to the γ modification of PP in EPR. A strong variation in the ratio of diffraction intensities I040/I110 of PP in block copolymers and mixtures was explained in terms of crystallite growth in different directions. Analysis of the patterns and calculation of crystallinity, crystallite size, and lattice parameters led to the conclusion that block structure existed in the prepared copolymers. 相似文献
953.
Binyuan Liu Yang Li Boo‐Gyo Shin Do Yeung Yoon IL Kim Li Zhang Weidong Yan 《Journal of polymer science. Part A, Polymer chemistry》2007,45(15):3391-3399
Three novel functionalized polynorbornenes (PNB) with pendant dimethyl carboxylate group (carboxylates—acetate, propionate, and butyrate) are synthesized as a vinyl‐type with a palladium (II) catalyst in high yield. The effects of size of substitutents, molar ratio of monomer to catalyst, solvent polarity, reaction time, and temperature on the polymerization of exo‐norbornene dimethyl propionate were systematically investigated. The low molar ratio and temperature, as well as high polarity of solvent, and long reaction time, are favorable for the enhancement of the monomer conversion, especially, the solvent have an obvious effect on the catalyst activity. The resulting poly(cis‐norbornene‐exo‐2,3‐dimethyl carboxylates) (PNB‐dimethyl carboxylates) show good solubility in common organic solvent and high thermal stability up to 360 °C. The glass transition temperature was detected by DMA at 331, 324, and 318 °C for acetate, propionate, and butyrate, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3391–3399, 2007 相似文献
954.
The concept of crystallization dynamics method evaluating the miscibility of binary blend system including crystalline component
was proposed. Three characteristic rates, nucleation, crystal growth rates (N*, G*) and growth rate of conformation (G
c*) were used to evaluate the miscibility of PVDF/at-PMMA and PVDF/iso-PMMA by the simultaneous DSC-FTIR. N*, G* and G
c* depended remarkably on both temperature and blend fraction (ϕPMMA) for PVDF/at-PMMA system, which indicated the miscible system. PVDF/iso-PMMA showed small ϕPMMA dependency of N*, G* and G
c*, was estimated the immiscible system. The ΔT/T
m0 values, corresponding to Gibbs energy required to attend the constant G* and G
c*, evaluated from G* and G
c* showed the good linear relationships with different slope. The experimental results suggested that the concentration fluctuation
existed in PVDF/iso-PMMA system. 相似文献
955.
Zhang Yinhuo 《数学年刊B辑(英文版)》1991,12(2):152-156
The author concludes that every commutative ring with ascending chain condition an annihilator ideals has a Kasch quotient ring, which generalizes the Theorem^{[1]} that
every commutative noetherian ring has a Kasch quosient ring. If follows that if R is a commutative ting with acc^{\perp},then that Q(R) is semiprimary is equivalent to that it is perfect, or to that R satisfies regular condition. Besides, that Q(R) is quasi-frobenius equals that Q(R) is FPF or PF, and that Q(R) is artinian equals that R/N, are of finite dimension, i=1,2,\ldots,n. N_{i}=J^{i}\cap R. 相似文献
956.
957.
In this paper, by means of monotone iterative technique, a necessary and sufficient condition of the existence of positive solution for a class of nonlinear singular differential system is established, the results of the existence and uniqueness of the positive solution and the iterative sequence of solution are given. In the end, two classes extending boundary value differential systems are discussed and some further results are obtained. 相似文献
958.
The impoverishment of soil nutrients of nine gully head areas in Yuanmou Basin is assessed through an integrated evaluation method established on the basis of Fuzzy mathematics and multivariate mathematical theory. Results show that soil erosion of gully erosion area in Yuanmou basin has resulted in severe impoverishment of soil nutrients. All gully head areas are at high leves of impoverishment except for one at middle. By probing into and analyzing the mechanism of impoverishment of soil nutrients, we find that soil erosion has led to impoverishment of soil nutrients in a way of compacting soil, heightening position of obstacle horizon, and reducing the content of organic matter, as well as the direct loss of nutrient elements. Finally, this paper points out that soil and water conservation arming at the prevention of soil erosion is the most effective way against impoverishment of soil nutrients in Yuanmou basin. 相似文献
959.
Measurement of small-signal and large-signal responses of packaged laser modules at high temperature
Ning Hua Zhu Ji Min Wen Hai Peng Song Shang Jian Zhang Liang Xie 《Optical and Quantum Electronics》2006,38(15):1245-1257
In this paper, the pulsed injection method is extended to measure the chip temperature of various packaged laser modules,
such as the DFB laser modules, the FP laser modules, and the EML laser modules. An optimal injection condition is obtained
by investigating the dependence of the lasing wavelength on the width and period of the injection pulse in a relatively wide
temperature range. The small-signal frequency responses and large-signal performances of packaged laser modules at different
chip temperature are measured. The adiabatic small-signal modulation characteristics of packaged LD are first extracted. In
the large-signal measurement, the effects of chip temperature, bias current and driving signal on the performances of the
laser modules are discussed. It has been found that the large-signal performances of the EML modules depend on the different
red-shift speeds of the DFB and EAM sections as chip temperature varying, and the optimal characteristics may be achieved
at higher temperature. 相似文献
960.
Songqing Zhao Yuzi Liu Shufang Wang Zhen Liu Ze Zhang Huibin Lu Bolin Cheng 《Applied Surface Science》2006,253(2):726-729
B-doped ZnO thin films have been fabricated on fused quartz substrates using boron-ZnO mosaic target by pulsed-laser deposition technique, and the mechanical properties have been studied by nanoindentation continuous stiffness measurement technique and transmission electron microscope (TEM). Nanoindentation measurement revealed that the hardness of B-doped ZnO films, 9.32 ± 0.90 to 12.10 ± 1.00 GPa, is much greater than that of undoped ZnO films and very close to that of traditional semiconductor Si. The mean transmittance (%) is larger than 81% in the visible range (380-780 nm) for all the films, and the Hall effect measurement showed that the carrier density is around 2 × 1020 cm−3 and the resistivity lower than 3 × 10−3 Ω cm. TEM characteristics show undoped thin films have more amorphous area between grains while the B-doped ZnO films have thin grain boundaries. We suggest that the grain boundaries act as the strain compensation sites and the decrease in thickness of grain boundaries enhances the hardness of the B-doped ZnO films. 相似文献