互换性与测量技术基础试题库及软件开发

本着操作简单、方便、实用、功能强的原则,开发了《互换性与测量技术基础题库系统》软件,用此软件,使略有Ｗｉｎｄｏｗｓ操作基础的教师,在不到一的时间内就可以自动生成一份试卷。     

粘弹基上受压粘弹杆的稳定性

由纤维复合等材料研制的各种结构的广泛应用,使得其力学性能的研究日趋重要。由于这类材料具有明显的时间效应,因而,必须采用粘弹性理论研究其与时间相关的各种性质。利用动力学的观点和方法,研究了粘弹性基础上两端受压粘弹性直杆的动力稳定性。考虑杆的线性变形,将问题化为等价的四阶常微分方程,分析了方程不动点的稳定性,由此得到杆的蠕变及瞬时临界载荷,讨论了杆失稳的临界时间,并数值计算了杆的动力响应,得到了相应的     

坝面粘贴苯板保护层的拱坝温度荷载研究

寒冷地区拱坝的温度应力比南方大得多,温度荷载的可能大大超过水荷载的影响,为了降低温度荷载,减小拱坝厚度。本文求出了两种不同介质在外界气温作用下的解析解,并针对在拱坝下游面用苯板作为永久保护层,提出了确定温度荷载的设计计算新方法,给出的温度荷载计算图表可供工程设计直接使用。     

一种压电超声马达的工作原理

定性介绍了压电陶瓷技术研究所研制的一种压电超声马达的工作原理。通过定量建立和解压电定子的振动方程,得出定子驱动端轨迹为椭圆这一推动转子转动的关键,并对转子材料提出一些要求。     

基于分维计算的颗粒粒度分析方法

提出了一种基于分形检测超细颗粒粒度的新方法及实现算法,超细颗粒在一定条件下产生布朗运动,通过光电系统记录的图象可看成是群体颗粒无规则漫游的结果,从而可用分数布朗运动模型去描述,对所获取的超强微粒布朗运动图象进行处理,然后按以上分形模型进行逐点的分维计算,再用统计的方法转换为粒度信息,从而实现粒度测量,文中给出了具体的算法及算例。     

Flow injection spectrofluorimetric determination of reserpine in tablets by on-line acetone sensitized photochemical reaction

On-line photochemical reaction of reserpine in the presence of acetone was investigated. Acetone was found to speed up the on-line photochemical conversion of reserpine into an intensively fluorescent compound. Not only reaction acidity but also the acetate buffer concentration affected the on-line photochemical induced fluorescence signal. Based on the observation an automated flow injection photochemical fluorimetric approach was developed. An injected sample zone was carried by a water stream to be merged with a acetate buffer (pH 3.4) solution containing 0.02% acetone in a knotted PTFE reactor (KR), which was freely coiled around a 6-W low pressure mercury lamp. While passing the KR, reserpine was transformed into an intensively fluorescent compound. It was on-line detected in a flow-through cell at the emission wavelength of 490 nm and excitation wavelength of 386 nm. At optimized conditions, a detection limit 0.45 mug l(-1) was achieved at a sampling rate of 90 h(-1). Eleven determinations of a 0.5 mg l(-1) reserpine standard solution gave a R.S.D. of 0.3%. The linear dynamic range of reserpine calibration curve was 0.01-0.75 mg l(-1). The proposed method was applied to assay the reserpine content in tablets and to monitor the dissolution profile of reserpine tablets. Satisfactory results were obtained for both the assays and dissolution studies.     

Electrogenerated Chemiluminescence Based on Tris(2,2′-bipyridyl) Ruthenium(II) with Hydroxyl Carboxylic Acid

Upon the electrochemical oxidation of tris(2,2′-bipyridyl) ruthenium(II) [Ru(bpy)²⁺₃] and hydroxyl carboxylic acids, for instance, citric acid, tartaric acid, malic acid, and -gluconic acid, bright electrochemiluminescences (ECLs) were observed. Different luminescent reactions were presented depending on the applied potential. The light emission was mainly caused by the reaction between alkoxide radical ion and Ru(bpy)³⁺₃below the potential +1.80 V (vs Ag/AgCl). The luminescence intensity obviously increased because of the more complex reaction process. The luminescence wavelength of 608 nm, which could be found either at higher potential than +1.80 V or in the potential range from +1.30 to +1.80 V, confirmed that ECL was caused by Ru(bpy)²⁺₃*. The factors which affect the determination and HPLC separation of the four acids were also investigated.