首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   30074篇
  免费   3533篇
  国内免费   3151篇
化学   15577篇
晶体学   272篇
力学   1156篇
综合类   197篇
数学   2448篇
物理学   6518篇
综合类   10590篇
  2024年   132篇
  2023年   596篇
  2022年   970篇
  2021年   1019篇
  2020年   1141篇
  2019年   956篇
  2018年   823篇
  2017年   861篇
  2016年   1176篇
  2015年   1302篇
  2014年   1560篇
  2013年   2005篇
  2012年   2206篇
  2011年   2259篇
  2010年   1649篇
  2009年   1671篇
  2008年   1876篇
  2007年   1684篇
  2006年   1479篇
  2005年   1394篇
  2004年   1057篇
  2003年   1002篇
  2002年   1189篇
  2001年   1007篇
  2000年   795篇
  1999年   795篇
  1998年   516篇
  1997年   454篇
  1996年   458篇
  1995年   446篇
  1994年   381篇
  1993年   340篇
  1992年   268篇
  1991年   229篇
  1990年   252篇
  1989年   182篇
  1988年   163篇
  1987年   111篇
  1986年   82篇
  1985年   54篇
  1984年   46篇
  1983年   24篇
  1982年   20篇
  1981年   23篇
  1980年   12篇
  1979年   10篇
  1976年   11篇
  1975年   12篇
  1971年   7篇
  1957年   8篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
In this paper, we extend a classical result of Hua to arithmetic progressions with large moduli. The result implies the Linnik Theorem on the least prime in an arithmetic progression.  相似文献   
52.
The addition-hydrolysis reaction of benzimidazolium salt with some mono- and bifunctional amine nucleophiles is reported,and a novel method of biomimetic synthesis for formamides and heterocycle compounds is provided.  相似文献   
53.
In this Letter we consider the Abelian Chern–Simons vortices on a bounded simply connected domain. We establish the existence of solutions for the self-duality equations. We prove the uniqueness of solutions when all the vortex points are equal and the domain is star-shaped. We also show the radial symmetry of solutions on balls centered at the vortex point.  相似文献   
54.
Two quantities ηrel and are applied to study the nonideal acetone–water association mixture. An all-atom acetone model and a TIP5P water model have been adopted for molecular dynamics simulation. We study the transport properties of the system comparing the 's of strong hydrogen bond and weak contact based on transport properties, MD simulations together with NMR experimental data and find good agreement of concentration dependence, which exhibits the cooperation effect.  相似文献   
55.
Composite silica particles were synthesized by a two-step (acid-base) process in an aqueous solution with a mixture of organoalkoxysilane monomers. The two-step process separates the hydrolysis and condensation procedures to easily control condensation rate. In this study, the silane monomers used were phenyltrimethoxysilane (PTMS), vinyltrimethoxysilane (VTMS), methyltrimethoxysilane (MTMS), and tetraethyl-orthosilicate (TEOS). The physical properties of the resultant composite particles were investigated with the change in the molar ratio of monomers. The size of the particles increased with increasing the molar ratio of RaSi(OR)3/RbSi(OR)3 or RaSi(OR)3/TEOS (Ra: phenyl; Rb: vinyl, methyl).  相似文献   
56.
A series of polyimides were synthesized from 2,2‐Bis(3,4‐dicarboxyphenyl)hexafluoropropane, 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane, and 4,4′‐oxydianiline by chemical imidization. The effects of the diamine ratios on the properties of the films were evaluated through the study of their thermal, electrical, and morphological properties. All the polymers exhibited better solubility in most of the organic solvents and hence were easily processable. Polyimides with more 2,2‐bis(3‐amino‐4‐hydroxyphenyl)‐hexafluoropropane exhibited better solubility and a low refractive index, which is highly desired for microelectronic applications. The dielectric constant and birefringence were strongly dependent on the fluorine content. With an increase in the fluorine substitution, both the dielectric constant and birefringence decreased. All the polymers exhibited high thermal stability (>400 °C). The absence of crystalline melting in differential scanning calorimetry and broad wide‐angle X‐ray diffraction patterns revealed the amorphous nature of the polymers, which was due to the presence of bulky CF3 groups and hinged ether linkages of the diamine component. The residual stress values decreased with an increase in the 4,4′‐oxydianiline content, and the results were in agreement with the dielectric constant. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4303–4312, 2004  相似文献   
57.
 用2D3V PIC粒子模拟方法得到了超短脉冲超强激光与固体靶相互作用中高能离子产生的图像,并对其机理进行了研究。在靶前后表面都观察到了高能离子的产生,并诊断了离子能谱。模拟结果表明,在靶前表面所产生的高能离子,角分布较大,在向靶内输运过程中会损失能量;在靶后表面产生的高能离子,定向性很好,能获得很高的能量。模拟得到的离子能量和实验观测结果在量级上相符。  相似文献   
58.
Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae.  相似文献   
59.
60.
For two rational quadratic B-spline curves with same control vertexes, the cross ratio of four eollinear points are represented; which are any one of the vertexes, and the two points that the ray initialing from the vertex intersects with the corresponding segments of the twocurves, and the point the ray intersecting with the connecting line between the two neighboring vertexes. Different from rational quadratic Beeier curves, the value is generally related with the loeation of the ray, and the necessary and sufficient condition o5 the ratio being independent of the ray‘s loeation is showed. Alsn another cross ratio o5 the following four collinear points are suggested, i.e. one vertex, the points that the ray from the initlal vertex intersects respectivdy with the curve segmentt the line connecting the segments end points, and the line connecting the two neighboring vertexes. This cross ratio is concerned only whh the ray‘s location, butnot with the weights of the curve. Furthermore, the cross ratio is projective invariant under the projective transformation between the two segments.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号