Crosslinked epoxy materials exhibiting thermal remendablility and removability from multifunctional maleimide and furan compounds

Crosslinked polymeric materials, which exhibit thermal remendability and removability through Diels–Alder (DA) and retro‐DA reactions, were obtained from using multifunctional maleimide and furan compounds as monomers. The synthesized monomers possess low melting points and good solubility in organo solvents to show excellent processing properties. The performance of DA and retro‐DA reactions were demonstrated with DSC and FTIR measurements. High performance of thermal remendablility and removability of the crosslinked materials were observed with SEM and solvent tests. These materials were applicable in advanced encapsulants and structural materials. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 905–913, 2006     

Vinyl copolymers containing pendant 1,4‐distyrylbenzene and 1,3,4‐oxadiazole chromophores: Preparation and optoelectronic properties

We prepared two vinyl copolymers P1 and P2 containing pendant distyrylbenzene and aromatic 1,3,4‐oxadiazole derivatives, respectively, from their precursor poly(styrene‐ran‐4‐vinylbenzyl chloride) (M_w = 11,400, PDI = 1.18), which had been prepared by the controlled radical polymerization (RAFT). Two main chain polymers containing similar isolated distyrylbenzene ( P3) and aromatic 1,3,4‐oxadiazole ( P4 ) chromophores were also synthesized for comparative study. The resulted copolymers ( P1 – P4 ) are soluble in common organic solvents and are basically amorphous materials with 5% weight‐loss temperature higher than 360 °C. The PL spectral results reveal that the architecture of P1 prevents the formation of inter‐ or intramolecular interaction. The HOMO and LUMO levels of P2 , estimated from cyclic voltammetric data, are ?5.96 and ?3.81 eV, respectively, which are much lower than those of P1 (?5.12 and ?3.11 eV). The emission of blend from P1 and P2 are contributed mainly from distyrylbenzene fluorophore (～450 nm) owing to efficient energy transfer. Moreover, the blend exhibits three kinds of redox behavior depending on their weight ratios. The luminance and current efficiency of the EL device lpar;ITO/PEDOT/ MEH ‐ PPV + P2 /Al) are 503 cd/m² and 0.11 cd/A, which can be improved to 1285 cd/m² and 0.44 cd/A, respectively, as the weight ratio of P2 increases from 0 to 20%. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5362–5377, 2006     

Fluorometric study on the interaction between lomefloxacin and bovine lactoferrin.

The binding of lomefloxacin to bovine lactoferrin (BLf) in a dilute aqueous solution was studied using fluorescence spectra. The binding constant (K) and the number of binding sites (n) were obtained by a fluorescence quenching method. The binding distance (r) and energy-transfer efficiency (E) between lomefloxacin and bovine lactoferrin were also obtained according to the mechanism of Fo?rster-type dipole-dipole nonradiative energy-transfer. The effect of lomefloxacin on the conformation of bovine lactoferrin was also analyzed by synchronous fluorescence spectroscopy. The interaction between lomefloxacin and bovine lactoferrin is strong. Lomefloxacin can affect the conformation of bovine lactoferrin to some degree.     

危岩切割控制爆破方案设计

在建筑工程施工中，爆破是常用的解决石方开挖的手段之一。基于一定的力学原理，根据不同的作业环境，会产生不同的爆破方案。下面这个范例是一个比较典型的控制爆破的施工方案，整个方案的中心矛盾在于合理处理施工环境限制条件和比较紧张的工期限制条件的关系。     

应用程序与数据库的接口设计技术

在管理系统开发过程中，应用程序的编写和数据库的设计都是比较容易实现的，而应用程序与数据库的接口设计却难于实现且容易出错。文章就这一问题论述了几种常见的编程语言编写的应用程序与数据库间的接口设计方法与技巧。     

试论效用价值论的价值判断和客观基础

效用价值论作为一种价值理论,必然包含有价值判断,这种判断就是认为资本主义生产方式是合理的和永恒的.这决定了它不可能是科学的理论,但却并不能因此而否认它所包含的科学成分,它的客观基础在于效用与价值之间存在的联系.     

三角形上拉普拉斯算子谱分析(Ⅱ)

运用Einstein级数的性质和Riemann-Mellin变换公式,得到了长方形和正三角形上Laplace算子的行列式和热方程核的前二项展开系数,发现它们与研究区域的面积和周长有关系.     

环境因素对跳远踏板准确性的分析研究

采用实验法、数理统计法对江西省不同等级男子跳远运动员踏板准确性受环境因素影响进行研究.结果表明:塑胶跑道与煤渣跑道,顺风跑,逆风跑,阴天,大量观众,噪音对跳远踏板准确性都具有较明显的影响.跳远运动员踏板的准确性一般不受运动员等级水平的影响.     

Effect of the homogeneity of the column set on the performance of a simulated moving bed unit. I. Theory

Although it is impossible to manufacture identical columns for use in a simulated moving bed (SMB) process, theoretical studies assume that all the columns in an SMB unit have identical characteristics. In practice, calculations in modeling and optimization studies are made with the average values of each column parameter set. In this report, the effects on SMB process performance caused by column-to-column fluctuations of the parameters are discussed. As a first step, we show how the differences in porosity of the columns may be taken into account with a revised set of separation conditions. Reductions in the purity of the extract and the raffinate streams are quantitatively related to the column-to-column fluctuations of the retention times of the two components arising from these porosity differences. For the sake of simplicity, the discussion first addresses the case of a four-column SMB operating under linear conditions. Then, the scope is extended to the cases of SMB units incorporating several columns in each section and to SMB units operating under nonlinear conditions.     

二芳基乙烯类光致变色材料的合成概述

由于具有多种潜在的应用价值, 光致变色化合物作为高级功能材料的研究在国内外广受关注. 在众多的有机光致变色化合物中, 二芳基乙烯特别是二噻吩乙烯, 由于其具有良好的热稳定性和优良的耐疲劳度而成为这类化合物的杰出代表. 近年来, 有关二芳基乙烯类光致变色化合物的各种合成及性能方面的报道已涉及到信息存储、分子开关、逻辑电路、液晶显示、磁性材料等众多领域. 主要是从有机合成的角度, 对这类材料的合成进行了较为全面的概括, 对各种合成方法分别加以介绍和分析, 对其发展趋势予以探索和展望.