首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   163986篇
  免费   37793篇
  国内免费   33606篇
化学   64548篇
晶体学   1701篇
力学   6395篇
综合类   920篇
数学   12630篇
物理学   62059篇
综合类   87132篇
  2024年   684篇
  2023年   1492篇
  2022年   2472篇
  2021年   2686篇
  2020年   3384篇
  2019年   6132篇
  2018年   6026篇
  2017年   7254篇
  2016年   7589篇
  2015年   8461篇
  2014年   9286篇
  2013年   10858篇
  2012年   11233篇
  2011年   13014篇
  2010年   16085篇
  2009年   15922篇
  2008年   9638篇
  2007年   9009篇
  2006年   7793篇
  2005年   7404篇
  2004年   7873篇
  2003年   6042篇
  2002年   5784篇
  2001年   5654篇
  2000年   4466篇
  1999年   3912篇
  1998年   2901篇
  1997年   2654篇
  1996年   2762篇
  1995年   3180篇
  1994年   3245篇
  1993年   3392篇
  1992年   2916篇
  1991年   2603篇
  1990年   2114篇
  1989年   2201篇
  1988年   2222篇
  1987年   1365篇
  1986年   1382篇
  1985年   982篇
  1984年   1029篇
  1982年   925篇
  1981年   752篇
  1980年   783篇
  1979年   539篇
  1978年   540篇
  1977年   637篇
  1976年   1045篇
  1973年   439篇
  1972年   532篇
排序方式: 共有10000条查询结果,搜索用时 328 毫秒
61.
一个基于Exchange的企业办公自动化系统的实现   总被引:1,自引:0,他引:1  
介绍了一个基于Exchange的企业办公自动化系统的实现,其中包括系统目标、开发平台和工具的选择、系统的功能模块、关键技术以及系统的安全机制。  相似文献   
62.
用正交试验法优化手性镍催化二乙基锌对α,β不饱和酮的不对称麦克尔加成反应条件,优化后的不对称麦克尔加成反应的一般条件为:低温(近反应溶剂冰点),常压,非质子非极性溶剂(环己烷).  相似文献   
63.
按词目的编排方法分,词典可分为三大类:音序词典、形序词典和义序词典。这三类词典各有优点和缺点;它们之间的关系应该是“长期共存,互相补足”,而不是谁取代谁。以此取代彼,没有必要性,也没有可能性。  相似文献   
64.
Summary Carbon deposits on the surface ofRu/Fe2O3 catalysts used in the water-gas shift reaction have been investigated by Auger Electron Spectrometry. A correlation has been found between the thickness of the carbon deposit and the catalytic activity in WGSR. The carbon deposit covers the metallic active centers and blocks their contact with reagents. The dotting of the iron oxide support with sodium has been found to reduce the amount of carbon deposit. .   相似文献   
65.
In this paper,the new development of three basic theories of Extenics,incluing basic-element theory,extension set theory and extension logic theory ,has been introduced.And the new theoretical frame of Extenics has also been set forth.  相似文献   
66.
The tracing evaluation index system was designed to be used in virtual enterprise and established neural network trace evaluation model. As a result, it was more simple and nicer than the traditional method, so it had wider application foreground.  相似文献   
67.
Optimized combination of chemical agents was selected for sensitive electrochemical detection of dissolved ruthenium tris-(2,2′-bipyridine) (Ru-bipy). The detection was based on the chemical amplification mechanism, in which the anodic current of a redox-active analyte was amplified by a sacrificial electron donor in solution. On indium-doped tin oxide (ITO) electrodes, electrochemical reaction of the analyte was reversible, but that of the electron donor was greatly suppressed. Several transition metal complexes, such as ferrocene and tris-(2,2′-bipyridine) complexes of osmium, iron and ruthenium, were evaluated as model analyte. A correlation between the amplified current and the standard potential of the complex was observed, and Ru-bipy generated the largest current. A variety of organic bases, acids and zwitterions were assessed as potential electron donor. Sodium oxalate was found to produce the largest amplification factor. With Ru-bipy as the model analyte and oxalate as the electron donor, the analyte concentration curve was linear up to 50 μM, with a lower detection limit of approximately 50 nM. Preliminary work was presented in which a Ru-bipy derivative was attached to bovine serum albumin and detected electrochemically. Although the combination of Ru-bipy, oxalate and ITO electrode has been used before for electrochemiluminescent detection of Ru-bipy and oxalate, as well as electrochemical detection of oxalate, its utility in amplified voltammetric detection of Ru-bipy as a potential electrochemical label has not been reported previously.  相似文献   
68.
Introduction3D garment CAD tools are increasingly required byclothing industries to assist the cloth design andmanufacturing process for quick response when faced withrapidly changing in style and fabrics with variable materialproperties. In the context of virtual prototyping, modelingand simulation of garment fitting to mannequin areattracting more and more people from both research andindustrial communities.Different approaches and techniques can be used…  相似文献   
69.
高校图书馆数字化与现代化服务   总被引:1,自引:0,他引:1  
互联网改变了图书馆的运作方式,网络已成为高校图书馆信息采集、存储和传播的主要途径。介绍了高校图书馆数字化与现代化服务的主要内容,对高校图书馆数字化与现代化服务的功能与特点、技术关键、对策与措施及发展趋势进行了深入的探讨。  相似文献   
70.
The γcmc values of CTAB-SDS decrease from 63.67 mN/m at 10‡C to 36.38 mN/m at 90‡C, slightly lower than those of either CTAB or SDS. Correspondingly, the CMC of CTAB-SDS decreases almost by half. The increase of surface activity of CTAB-SDS can be attributed to the relatively weak electrostatic interaction at high temperature, which is supported by the increase of solubility of CTAB-SDS with rise in temperature. Catalytic effect on oxidation of toluene derivatives with potassium permanganate follows the order CTAB-SDS > SDS > CTAB. This is not caused by the dissociative effect of CTAB-SDS with low surface activity at low temperature, as seen from the fact that almost all oxidative products can be retrieved for different toluene derivatives and surfactants by mimicking the conditions of reaction. In the emulsifications of toluene derivatives at 90‡C, the time that turbid water layers of surfactant solutions take to become clear is the same as that of the catalytic effect on oxidation of toluene derivatives. Thus, it can be inferred that surfactants can improve the oxidation yields of toluene derivatives by increasing the contact between two reacting phases.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号