Ag~+,Sr~(2+),Yb~(3+)双掺杂对Ca_3Co_4O_(9-δ)热电性能的影响

采用溶胶-凝胶和冷压方法,在Ca3Co4O9-δ体系中引入不同量的Ag~+,Sr~(2+)或Yb~(3+)离子制备了可在300~870 K下稳定存在且热电性能优良的陶瓷材料Ca_(3-x-y)Ag_xSr_yCo_4O_(9-δ),Ca_(3-x-z)Ag_xYb_zCo_4O_(9-δ)和Ca_(3-y-z)Sr_yYb_zCo_4O_(9-δ)(x,y,z=0.1,0.15,0.2).通过X射线衍射(XRD)、傅里叶变换红外光谱(IR)和扫描电子显微镜(SEM)等手段对产物进行表征.结果显示,所制备的样品纯度较高,晶粒均匀,晶粒间较致密,适量的Ag~+,Sr~(2+),Yb~(3+)离子取代Ca~(2+)离子固溶到晶体中使制备的双掺杂材料晶胞体积发生了变化,但并未引起晶体对称结构的变化.电阻率和Seebeck系数结果表明,双掺杂优化了样品载流子的浓度,使样品电阻率不断减小,并使Seebeck系数的值不断增大.经过计算可知,Seebeck系数随电子有效质量的增大而增大.热导率结果表明,双掺杂的样品热导率随掺杂元素的不同而变化,计算结果显示声子热导依然在样品中占据主体贡献,这与Ca_3Co_4O_(9-δ)单掺杂Ag~+,Sr~(2+)或Yb~(3+)的结果吻合.随着温度的升高,双掺杂样品Ca_(2.7)Ag_(0.2)Yb_(0.1)Co_4O_(9-δ)在870 K下热电优值(ZT)值达到最大(0.18).     

Symplectic solution for three dimensional couple stress problem and its variational principle

A new state vector is presented for symplectic solution to three dimensional couple stress problem. Without relying on the analogy relationship, the dual PDEs of couple stress problem are derived by a new state vector. The duality solution methodology in a new form is thus extended to three dimensional couple stress. A new symplectic orthonormality relationship is proved. The symplectic solution to couple stress theory based a new state vector is more accordant with the custom of classical elasticity and is more convenient to process boundary conditions. A Hamilton mixed energy variational principle is derived by the integral method.     

大跨率桥梁直接考虑拟静力位移影响的随机地震反应分析

对 Duhamel积分引入了改进的脉冲响应函数 ,建立了激励演变谱矩阵与总动力响应演变谱之间的关系 ,并对实际大跨度斜拉桥进行了数值计算。这一成果实现了全面考虑各种地震动时空变化特性下的直接求解结构总动力响应的时域法和频域法计算列式 ,使得地震动多点激励下考虑拟静力位移影响的结构响应计算过程大为简化。     

ON GENERALIZED ORDERS AND GENERALIZED TYPES OF DIRICHLET SERIES IN THE RIGHT HALF-PLANE

In the paper, generalized orders and generalized types of Dirichlet series in the right half-plane are given. Some interesting relationships on maximum modulus, the maximum term and the coefficients of entire function defined by Dirichlet series of in the right half-plane are obtained.     

Fabrication of tungsten oxide microfibers with photocatalytic activity by electrospunning from PVA/H3PW12O40 gel

Regarding gel poly (vinyl alcohol)/H₃PW₁₂O₄₀ as precursor, the ultra-fine fibers tungsten oxide (WO₃) was prepared by using electrospinning and calcinating techniques. Scanning electron microscope (SEM) shows that the average diameter of fibrous WO₃ were changed from 200 nm to 600 nm after calcined PVA/H₃PW₁₂O₄₀ fibers at 600 and 800 °C, respectively. X-ray diffraction (XRD) and Raman spectroscope revealed that the fibrous WO₃ was monoclinic phase, and the band-gap energies were observed by UV-vis diffuse reflectance spectra. The small size WO₃ exhibits excellent photocatalytcic activity in degradation of Rhodamine B at 365 nm wavelength.     

线性调频Z变换在信号频谱分析中的应用

由于快速傅里叶变换（Fast Fourier Transform,FFT）算法不能精确反应信号的局部频谱特性,对此,本文以按时间抽取（DIT）的基-2FFT算法为基础,并参考基于FFT的布鲁斯坦（Bluestein）算法,设计了新的信号频谱分析软件,用于对实序列采样信号做线性调频Z变换,即频率抽样处在Z平面上,可沿任意螺线做频率抽样的频谱分析方法.结合工程实践对相同采样点数的信号在0—50Hz频率段做频谱分析,由频谱图可以看到,采用线性调频Z变换算法远比采用FFT变换算法求得信号的频谱更精确.     

船用起重机磁流变防摆装置动力学分析及实验验证

为了解决船用起重机在执行吊装转运作业时,货物出现摆动降低工作效率且极易造成安全事故的问题。将磁流变技术引入到船用起重机防摆领域,设计了一种机械式防摆装置。推导了船-起重机-吊点-防摆装置-吊重的三维动力学模型。对装置的防摆效果进行分析,结果表明,当输入给磁流变防摆装置恒定电流时,随着电流增大,防摆效果愈加明显,在设定工作背景下,当给定电流2A时,对面内角及面外角的抑制分别为75%、82%。为了优化控制策略,降低能耗,提高防摆的鲁棒性,设计了变论域模糊PID(VUFPID)控制器。采用VUFPID控制器时,防摆装置对吊重摆动的面内角及面外角的抑制分别为85%,83%,能耗约为113J;采用A组恒定电流时,防摆装置对吊重摆动的面内角及面外角的抑制分别为60%,68%,能耗约为140J;采用B组恒定电流时,防摆装置对吊重摆动的面内角及面外角的抑制分别为50%,58%,能耗约为110J。可见采用VUFPID后,能实现低能耗,效果明显的防摆作用。最后搭建实物样机,验证了磁流变防摆装置的有效性。     

船用起重机多绳系统同步运动控制策略

针对船用起重机在进行起升、变幅动作及受到外部扰动时,船用起重机多绳系统的减摇索之间无法实现同步运动的问题。首先建立了船用起重机多绳系统的运动学和动力学模型,接着提出了模糊PID控制策略,最后采用Matlab/Simulink软件进行仿真分析。结果表明:在模糊PID控制策略下,多绳系统期望绳长与实际绳长的误差逐渐趋向于零,期望绳长速度与实际绳长速度的误差逐渐趋向于零,相比于传统的PID控制效果,模糊PID控制策略具有更高的鲁棒性。