Study of conical columns with 10 degrees opening angle for preparative liquid chromatography

The efficiency and sample capacity of conical liquid chromatographic columns with 10 degrees opening angle were studied at different ratio of cross section areas of inlet to outlet (A(in)/A(out)) and column dimension. As the A(in)/A(out) ratio changed from 4 to 2.25, the reduced plate height (h) was reduced and the h value decreased 12% when the column dimension was scaled up proportionally because of relatively smaller dead volume on both end of the column. Compared to cylindrical columns having corresponding lengths and volumes, the conical columns with 10 degrees opening angle were superior in column efficiency, resolution and the maximum peak concentration at column outlet; the loadability of conical column was improved 30-40% on injection volume and 50-60% on sample mass, respectively, over cylindrical columns.     

HPLC method for the determination and pharmacokinetic studies on geniposide in rat serum after oral administration of traditional Chinese medicinal preparation Yin-Zhi-Ku decoction

A new HPLC method for the determination of geniposide in rat serum with solid-phase extraction (SPE) for preconcentration is described. Geniposide and an internal standard (paeoniflorin) were extracted from serum by SPE using C18 cartridges. Analysis of the extract was then performed on a reversed-phase C18 column using acetonitrile-water (16:84, v/v) as the eluting solvent system, and UV detection at 238 nm was used to measure the analyte with a limit of quantitation about 0.1 microg/mL. The calibration curve for geniposide was linear (r = 0.9993) in the concentration range 0.1-16.0 microg/mL. The intra- and inter-day precision of the geniposide were determined and their RSD did not exceed 10%. The validated method has been successfully applied for pharmacokinetic studies of geniposide from rat serum after oral administration of Yin-Zhi-Ku decoction.     

南海夏季风与登陆我国大陆初旋的关系

利用1948---2009年南海夏季风指数、NCEP/NCAR月平均再分析位势高度场、风场资料, 首次分析了南海夏季风与每年登陆中国大陆的首个热带气旋(初旋)的关系. 结果表明: 初旋的登陆日、登陆纬度、生成纬度与当年登陆中国大陆热带气旋的频数、活动期、强度等相关性较好; 强(弱)南海夏季风指数年份, 登陆大陆热带气旋数偏多(少)、初旋登陆日偏迟(早)、初旋登陆点偏南(北). 从流场上看, 强(弱)南海夏季风指数年份, 对应的季风槽偏强(弱), 其异常风场和初旋路径也截然不同. 从年际变化上看, 南海夏季风指数明显呈减弱趋势, 而初旋登陆点则有一定北移.     

基于TD-LMS算法的OFDMA上行链路载波频率偏移消除

提出了一种时域自适应最小均方误差算法(TD-LMS)来消除正交频分多址接入(OFDMA)系统上行链路的各载波频率偏移引起的干扰.该算法首先对OFDMA系统接收端的时域信号进行估计,并利用估计量来预消除载波频率偏移,然后在时域内进行残留频率偏移消除.仿真结果表明,在相同的仿真条件下,与最小二乘算法相比,该算法可以获得3dB的增益,且对各用户的频率偏移有明显的消除效果.     

四羟甲基四(1,4-二噻英)四氮杂卟啉锌的合成、表征与性能

采用模板法合成了四羟甲基四(1,4-二噻英)四氮杂卟啉锌ZnPz(CH_2OH-dtn)_4,结构经元素分析、UVVis、XPS和IR光谱的表征,通过循环伏安法测试了ZnPz(CH_2OH-dtn)_4的电化学性质.以罗丹明B(RhB)为降解模型分子,初步考察了ZnPz(CH_2OH-dtn)_4在温和条件下的光催化性能.研究表明:羟甲基四氮杂卟啉锌有较好的活化分子氧的能力.     

镍基耐蚀合金C-276铸锭元素偏析和均匀化工艺

利用光镜、扫描电镜和能谱仪等显微组织分析方法研究了镍基耐蚀合金C-276经真空冶炼+电渣重溶后铸锭的枝晶特点和元素偏析情况,根据残余偏析指数模型计算结果选取了四种均匀化实验制度,并通过均匀化实验后的组织分析和Gleeble1500试验机热模拟锻造实验验证,最终确立了适合C-276合金的均匀化工艺.结果表明:合金中偏析程度最严重的元素为Mo;在选取的四种均匀化制度中,采用1170℃下加热20h的处理方式不仅可以较好地实现成分均匀化,还能保证晶粒尺寸不过度长大,从而确保合金的热加工塑性,是最为合理的均匀化制度.实验也证明利用残余偏析指数模型,计算结果与实验结果基本吻合,在预测和评价C-276合金均匀化工艺上是可信的.     

Enhanced calcification ameliorates the negative effects of UV radiation on photosynthesis in the calcifying phytoplankter <Emphasis Type="Italic">Emiliania huxleyi</Emphasis>

The calcifying phytoplankton species,coccolithophores,have their calcified coccoliths around the cells,however,their physio-logical roles are still unknown.Here,we hypothesized that the coccoliths may play a certain role in reducing solar UV radiation(UVR,280-400 nm) and protect the cells from being harmed.Cells of Emiliania huxleyi with different thicknesses of the cocco-liths were obtained by culturing them at different levels of dissolved inorganic carbon and their photophysiological responses to UVR wer...     

电冰箱故障模拟控制电路的研究

通过控制电路模拟了电冰箱正常运行状态,分析了电冰箱电气控制的工作原理;模拟了电冰箱常见的电器元件及部分设备故障,并通过控制电路的分析对故障进行了诊断,为冰箱的排故提供了虚拟环境,避免了繁琐的元器件及实物设备故障的设置;也为其他制冷设备(如空调器)的故障模拟设计提供了参考。     

On Higher Order Pyramidal Finite Elements

In this paper we first prove a theorem on the nonexistence of pyramidal polynomial basis functions. Then we present a new symmetric composite pyramidal finite element which yields a better convergence than the nonsymmetric one. It has fourteen degrees of freedom and its basis functions are incomplete piecewise triquadratic polynomials. The space of ansatz functions contains all quadratic functions on each of four sub-tetrahedra that form a given pyramidal element.     

雷达辐射源识别数据融合基本概率分配函数建模

通过对全脉冲、批数据等各级数据进行分析,并与识别结果进行比对、核实和验证,发现复杂电磁环境下各独立侦察设备侦收到的数据和雷达辐射源识别信息具有模糊性和不完整性,造成识别过程中出现错误,甚至输出毫不相关的识别结果。针对这种情况,采用基于D-S证据理论数据融合的方法对雷达辐射源进行识别。此外,结合雷达辐射源识别问题的特点,借鉴信息论中熵的概念,对基本概率分配函数进行了建模。仿真结果表明该方法具有优良的性能。