Photochemistry of dibenzo-1,4-dioxins: intramolecular rearrangement-reduction through observable 2,2′-biphenylquinones

The photochemistry of dibenzo-1,4-dioxin (7) and 2,3,7,8-tetramethyldibenzo-1,4-dioxin (15) — both of which have the parent ring system of the well-known enrimental contaminant dioxin— has been studied in aqueous solution and in selected organic solvents. It is shown that a novel intramolecular photorearrangement is the major mode of reaction for 7 and the exclusive reaction for 15, giving rise to observable (by UV—Vis spectrophotometry) intermediate 2,2′-biphenylquinones. Subsequent reduction by the organic co-solvent gives rise to 2,2′-biphenols as major or exclusive product. Thus, photolysis of these compounds generates oxidizing agents in the biphenylquinones. Photolysis in the presence of added N_aBH₄ resulted is greatly enhanced yields of biphenols along with more than 90% material balance. These findings have relevance to dioxin photodecomposition, which can be used as a method for its destruction.     

INFLUENCE OF POLYMER CHARACTERISTICS AND MELT-SPINNING CONDITIONS ON THE PRODUCTION OF HIGH RANDOMNESS 60PHB/PET THERMOTROPIC LIQUID CRYSTAL COPOLYESTER FIBER

Six samples of linear high randomness 60PHB/ PET thermotropic liquid crystal copolyesters are made by melt copolymerization at 290℃ , whose randomness about 0.955 is measured by the discernible 'H-NMR spectrometer. High tenacity, high module fiber is prepared by melt spinning in liquid crystal phase. The effect of molecular weight, shear rate, temperature as well as spinning drawn ratio on the mechanical behavior of 60PHB / PET copolyester fiber are shown that, lower shear rate (2~ 10 s~(-1)), higher temperature melting (300℃ ), lower temperature spinning (280℃ ) and higher molecular weight are favourable to the increase of the fiber mechanical properties. With the variance of drawn ratio, fiber mechanical property has a transition point due to traversion from shear-orientation to drawn-orientation. The copolyester fiber has high crystallinity, high orientation at the crystalline region, high chain orientation and high regular fibrillar structure.     

从CET-4新题型看大学英语词汇教学

本文结合最新的四级题型,分析了大学英语新四级考试中词汇的测试特点,对大学英语词汇教学提出了一些有效的教学方法.     

三维空间线性规划问题的图解法

本文着重论述怎样利用几何作图,并通过计算,求三维空间线性规划问题的最优解。     

浅析邯郸农行金库盗窃案涉案巨款追缴

倍受关注的河北省邯郸市农业银行支行金库被盗案近期有了一审结果,任晓峰、马向景二人以贪污罪被判处死刑。任、马二人非法获取四千多万元巨款用于购买彩票,案件受害方邯郸农业银行能否向当地体彩中心索回任晓峰等人用于买彩票而支付的巨款?善意取得能否适用于该案?本文通过分析善意取得制度基本理论,结合新出台的物权法规定,指出此案不适用善意取得,巨款应予追缴返还给邯郸农业银行。     

双参数量子代数SUqs（1,1）的表示：正离散序列

本文通过构造双参数量子群ＳＵｑｓ（１，１）生成元的ｑｓ－Ｂｏｓｏｎ实现，给出了ＳＵｑｓ（１，１）的正离散序列表示。     

Chemical Speciation of Amphoteric Ions on Semi‐Dry Scrubber Residue and Bag‐House Ash from MSWI

Two series of size‐fractionated combusted residues, a bag‐house ash and a scrubber residue, from a municipal solid waste incinerator (MSWI) were prepared and extracted by means of sequential chemical extraction (SCE) procedures proposed by Tessier. Concentrations of water‐soluble phase, exchangeable phase, carbonated phase, Fe/Mn oxide phase, organic matter phase, and residual phase bound amphoteric metals (Pb and Zn) were obtained, and have been compared with those of single batch extraction of toxic characteristic leaching procedure (TCLP). In each size fraction of baghouse ash or scrubber residue, lead or zinc shows a common phenomena that the TCLP value is always lower than the content of the water‐soluble fraction. For lead, baghouse ash has a significant size‐dependent distribution on the water‐soluble phase to perform a size‐dependent test of lead in the TCLP test. The zinc TCLP data having less size dependence might be due to that neither the baghouse ash nor the scrubber residue has a size‐dependent distribution on the water‐soluble zinc phase.     

Aggregation Properties of an Amphiphilic Methanofullerene Derivative in THFH_2O Solvent Mixtures

Water-soluble fullerenes not only have a number of important applications in biological chemistry1, but also form ordered aggregate structures that can be utilized in materials science2. There are reports that some water-soluble fullerene derivatives can form ordered structures in water, such as vesicle, nanorod and nanoparticle2-5. However, relatively few reports on the aggregation process have been reported. Knowledge of factors that affect the cluster formation in solution is of consider…     

一种新型有机电致微腔结构的双模发射

采用结构Glass／DBR／ITO／NPB／NPB：Alq／Alq／Al制作了有机微腔电致发光器件。将空穴传输材料与发光材料以一定比例混合作为发光层，为了便于对比，在不改变有机层的膜厚的情况下同时制作了传统的异质结微腔器件，发现两种器件的发光光谱有很大不同，器件的复合效率与传统的异质结器件相比也得到了很大提高，这是因为将两种有机材料混合能消除界面势垒，提高器件的复合效率，从而提高了器件的发光性能，实现了微腔双模发射，且两个模式的半峰全宽分别为8nm和12nm。通过进一步优化器件结构可以实现微腔白光发射。