微波吸收法研究Mn,Cu掺杂对ZnS:Mn,Cu光生载流子复合过程的影响

采用微波吸收法，测量了ZnS:Mn,Cu粉末材料受到超短脉冲激光激发后，其光生电子和浅束缚态电子的衰减过程.发现Mn,Cu的浓度对导带电子的寿命有明显的影响，提高掺杂浓度会使光生电子的寿命大大缩短，还研究了掺杂浓度对光致发光强度的影响. 关键词： 发光材料 硫化锌 光电子 微波吸收技术     

Writing Fiber Grating of Different Wavelength Using the Same Phase Mask

Chirped fiber grating was used in dispersion compensator. We tried to use the same phase mask to write fiber grating of different wavelength with two methods to reduce the price of the fiber grating.     

Reactivities of tetraalkyltin complexes toward Pt/HY zeolite

Tetraalkyltin complexes, SnR₄ (R = Me, Et, Pr, Bu) could react with Pt/HY at 193, 243, 273 and 333 K, respectively. The reactions occurred on the surface of the zeolite and the organotin grafted zeolites were characterized in detail. The framework and the microporous structure of the grafted Pt/HY zeolites were retained. However, the modified zeolites showed better size selectivity in the absorption of hydrocarbons.     

矩阵的弱相似性及其应用

推广了矩阵环Mn(F)中相似性概念，提出了矩阵的弱相似概念，研究了它的基本性质，获得一些有趣结果，此外，指出了文[3]的一个错误，给出了Laffey-Choi一个关键引理的矩阵式的证明。     

Peritectic phase growth in directionally solidified Cu-70% Sn alloy

The growth mechanism of the peritectic η phase involving the peritectic reaction and peritectic transformation in Cu-70%Sn alloy was investigated under directional solidification. The results show that a major growth mechanism in thickening of the peritectic η-layer is not the peritectic reaction but the peritectic transformation. The transformation temperature and isothermal time play crucial roles in determining the volume fraction and the thickness of the peritectic η phase. With the increase of the temperature and isothermal time, the volume fraction of the peritectic η phase increases. The regressed data show that the relationship between the thickness of η phase (Δx) and the transformation temperature (T) meets the following equation In Δx=6.5−1673 1 / T. Additionally, there exists a relationship between the thickness of the η phase (Δx) and the isothermal time (t) at the 9 mm solidification distance below the peritectic reaction interface, Δx=0.72t ^1/2, which is consistent with the theoretical model. Supported by the National Science Foundation of China (Grant No. 50395102)     

高精度CCD尺寸自动检测系统的光学系统设计

介绍测量精度为±０．００３ｍｍ的ＣＣＤ尺寸检测系统的光学系统设计特点及远心物镜设计原理，并给出了测试结果。     

连铸小方坯的组织与性能研究

The hot cracking of the continuous casting bullit is connected with its macrostructure and mechanical property burnt. The macrostructure and the mechanical property of 0. 13 wt- %C continuous casting bullit was investigated. The results are as follows: 1) the classical representation of the casting bullit shows three distinct zones, a peripherial region of small equiaxed grains, a columnar zone, and a central equiaxed zone. The rapid increase of the under cooling layer thickness is the criterion of the transformation from the columnar zone to central equiaxed zone; 2) The hardness decreases with the reducing of the solidification speed; 3) The tensile strength decreases gradually from the peripherial equiaxed maximum principal strain zone to central equiaxed zone ,and increases with the drop of the temperature.     

高频单线圈双调谐NMR单晶探头的研制

本文报道了一种测角单晶NMR探头。该探头采用单线圃双调谐电路,工作频率在90MHz-110 MHz连续可调,可进行交叉极化大功率去耦实验。文中提出了一种简单而有效的测角装置,可使单晶绕三个互相垂直轴转动实现单晶的NMR测量。作为典型的应用例子,本文利用该探头实现了单晶DGO(2NH₂CH₂COOH·H₂C₂O₄)屏蔽张量的测量。     

二硅烯及其相关分子的量子化学计算研究

使用密度泛函法、MP2法和考虑组态相关作用的QCISD和CCD法,对重主族双键化合物二硅烯、二锗烯等进行了优化构型的量子化学计算.计算结果表明,H2X=XH2(X=Si,Ge,Sn,Pb)型分子均为非平面反式弯曲几何构型,亚甲基XH2的基态为单线态.利用计算的"单线态-三线态"能量差ΔEST和双键键能Eσ π分析并解释了非平面反式弯曲几何构型的形成条件和标题物中双键的相对强度.     

平衡规划问题的熵函数方法及其在混合交通流中的应用

将参变极值问题的极大熵函数方法应用到求解平衡规划问题中,通过先验分布信息和Kullback熵概念,给出了平衡规划问题基于Kullback熵表示的熵函数求解方法,并将平衡规划的极大熵函数方法应用于求解混合交通平衡分配问题．