Benzene and ethylene chemisorbed on transition metals; The measurement of energy level shifts which accompany chemisorption

Ultraviolet photoemission spectra for ethylene chemisorbed on Ag(110) and benzene on Ag(110) and Ru(001) indicate adsorption with minimal molecular distortions. A survey of the photoemission data for ethylene and benzene similarly adsorbed on transition metals indicate that the relaxation shift in the binding energy of molecular Orbitals not contributing to the chemisorption bond is essentially independent of the metal when obtained using the value of the work function when the surface is saturated with adsorbate. This observation is in agreement with a theoretical analysis where final state image charge screening is the dominant relaxation mechanism. These observations support the choice of the work function of the surface saturated with adsorbate as the approximation of the adsorption site potential.     

Investigation of persistent photoconductivity in Si-dopedn-Al x Ga1−x as grown by molecular beam epitaxy

The persistent photoconductivity effect in Si-dopedn-Al _x Ga_1?x As layers grown by molecular beam epitaxy on (100)GaAs substrates has been investigated by detailed Halleffect and capacitance measurements at 10–300 K. In the alloy composition range 0.25<x <0.40 the electrical properties ofn-Al _x Ga_1?x As are governed by a deep electron trap having an emission barrier of 0.34–0.40 eV (depending on the doping concentration), as determined by admittance measurements. The concentration of deep electron traps, deduced from low-temperature capacitance measurements, is found to coincide with the amount of persistent photoconductivity observed in the material. Consequently, the earlier proposed population of two-dimensional subbands at the Al _x Ga_1?x As/GaAs-substrate hetero-interface, i.e. charge separation bymacroscopic barriers, can not account for the measured high overall number of persistent photoexcited carriers. Instead, the vanishing small capture rates of photoexcited electrons result frommicroscopic capture barriers. The dominant deep electron trap, which we attribute to deep donor-type (DX) centers, is found to be homogeneously distributed throughout the Al _x Ga_1?x As layer depth. From our Hall effect measurements a trap depth of 0.05–0.12 eV (depending on the doping concentration) below the conduction band is derived. The capture barrier is thus in the order of 0.30 eV. This value is in excellent agreement with data obtained from liquid phase epitaxially grown Si-dopedn-Al _x Ga_1?x As.     

Waveform-controlled near-single-cycle milli-joule laser pulses generate sub-10 nm extreme ultraviolet continua

We demonstrate the generation of waveform-controlled laser pulses with 1?mJ pulse energy and a full-width-half-maximum duration of ～4 fs, therefore lasting less than two cycles of the electric field oscillating at their carrier frequency. The laser source is carrier-envelope-phase stabilized and used as the backbone of a kHz repetition rate source of high-harmonic continua with unprecedented flux at photon energies between 100 and 200?eV (corresponding to a wavelength range between 12-6?nm respectively). In combination we use these tools for the complete temporal characterization of the laser pulses via attosecond streaking spectroscopy.     

Carbon-13 Assignments and Revision of the Stereostructures of the Cadinanes 2-Hydroxy-8α-angeloyloxycalamenene and 2-Hydroxy-8α-hydroxycalamenene

The two known cadinanes 2-hydroxy-8α-hydroxycalamenene and 2-hydroxy-8α-angeloyloxycalamenene were isolated from a Louisiana population of Heterotheca subaxillaris.

Their ¹³C NMR spectra were fully assigned by the application of HETCOR, COLOC, COSY, NOESY and DEPT experiments. It was shown on the basis of NOESY experiments that both cadinanes require revision at the stereogenic centre C-7.     

On the changes in the microwave dielectric spectrum of aqueous phospholipid bilayer solutions at the ordered-fluid phase transition

The microwave part of the dielectric spectrum (ν ? 1 GHz) is considered of aqueous phospholipid solutions in the limit of high water content. A continuum model is presented which allows to calculate in the water relaxation region the frequency-dependent complex permittivity of solutions in which the bilayers form globular single-walled vesicles as well as multilamellar liposomes. The model is not only capable of explaining the strikingly small values of the extrapolated static permittivity and of the main dielectric relaxation time which became evident in many measurements on colloidal aqueous solutions of phospholipids. It also allows the positive and negative step-like changes in the dielectric properties of solutions, which have been found at the main (order-disorder) phase transition temperature of the bilayers, to be explained by dimensional changes as resulting from vesicle growth and fusion.     

Protein adsorption and interfacial rheology interfering in dilatational experiment

The static and dilatational response of β-lactoglobulin fibrils and native β-lactoglobulin (monomers) at water-air and water-oil interfaces (pH 2) was measured using the pendant drop method. The resulting adsorption behavior and viscoelasticity is dependent of concentration and adsorption time. The interfacial pressure of the β-lactoglobulin fibrils obtained in static measurements was 16–18?mN/m (against air) and 7?mN/m (against oil) for all concentrations. With higher concentrations, faster adsorption kinetics and slightly higher interfacial and surface pressure is achieved but did not lead to higher viscoelastic moduli. The transient saturation of the interface is similar for both the fibril solution and the monomers, however the fibril solution forms a strong viscoelastic network. To evaluate the superimposed adsorption behavior and rheological properties, the formed interfacial layer was subjected to dilatational experiments, which were performed by oscillating the surface area of the drop in sinusoidal and sawtooth (diagonal) deformation manner. The sinusoidal oscillations (time depended area deformation rate) result in a complex interfacial tension behavior against air and oil interfaces and show remarkable differences during compression and expansion as emphasized by Lissajous figures. For diagonal (constant area deformation rate) experiments, a slight bending of the interfacial tension response was observed at low frequencies emphasizing the influence of protein adsorption during rheological measurements.     

Properties of blends of poly(vinyl chloride) and chlorinated polyethylene. I. Optical methods of characterization of PVC multiphase systems

Hitherto it has not been possible to produce a microscopic image with adequate resolution of the high-impact two-phase system poly(vinyl chloride) (PVC)/chlorinated polyethylene (CPE) due to inadequate phase contrast. With the aid of various chemical staining methods and through ion etching, a way has been found for studying the microstructure of the PVC/CPE system by light microscopy and electron microscopy. These independent visualization techniques and scanning electron micrographs of fracture surfaces show, as the morphology with optimal mechanical and rheological properties, networklike distribution of the rubber phase and, imbedded in this, a PVC phase consisting of primary particles.     

Stabilisation of fcc cobalt layers by 0.4 nm thick manganese layers in Co/Mn superlattices

Epitaxial Co/Mn multilayers (0.75 to 6 nm Co, 0.4 nm Mn layer thickness) have been grown on mica substrates covered by a (0002) Ru buffer layer. The structural properties of these layers have been studied using X-ray diffraction, nuclear magnetic resonance (NMR), and high resolution transmission electron microscopy (HRTEM). The Co layers, grown as face centred cubic (fcc), were found to be stabilised by the very thin Mn layers. Data obtained using X-ray diffraction and NMR were analysed and found to be in good agreement, while Monte-Carlo simulations were used to interpret the data and calculate the expected diffracted intensity and NMR spectra. The HRTEM data show that the Mn layers give rise to a large strain contrast extending, in the growth direction, over a distance which exceeds the thickness of the Mn layers. The superlattices could be described as having an fcc structure containing randomly located stacking faults with varying densities. The results verify the presence of a dominant, almost perfect phase of fcc stacking, and of a faulted hcp phase, while the number of defects increases with the Co layer thickness. Received 27 October 1999 and Received in final form 29 May 2000