CuAl2Cl8. Darstellung und Kristallstruktur

CuAl₂Cl₈. Preparation and Crystal Structure. Crystals of CuAl₂Cl₈ have been prepared. Their remission spectrum agrees with that of gaseous CuAl₂Cl₈. The crystal structure (P2₁/c;a = 6.614, b = 7.376, c = 12.319 Å; β = 94.11°) shows a molecular lattice with Cu in square planar coordination, which is completed to a stretched octahedron (as in solid CuCl₂) by two Cl atoms from neighbour molecules. Al has tetrahedral coordination.     

Stereoelectronic control of exo/endo rate ratios in the solvolysis of 2-norbornyl p-toluenesulfonates

The variable exo/endo rate ratios observed in the solvolysis of 6-exo-substituted exo- and endo-2-norbornyl p-toluenesulfonates are due to differential transmission of polar effects in the transition state for ionization.     

Beim Nachweis von E 605 im Mageninhalt

Ohne Zusammenfassung     

The Nature of the vibronic intensity borrowing mechanism in the 1B3u(n)1Ag(X) transition of pyrazine

The transition intensities of the S₀S₁ gas phase absorption spectra of pyrazine-d₀ and -d₄ were carefully measured. A discussion of the various aspects of vibronic intensity borrowing for this unique case is presented using our new experimental results.     

Γ-Lakton-cis-anellierung an Δ2- und Δ3- Cholesten

γ-Lactone-cis-annulation to Δ²- and Δ³- Cholestene. From Δ²- and Δ³- cholestene the γ-lactones 11a , 11b , 12a , and 12b are synthesized through the dibromocarbene adducts 3 and 4 , the bromohydrines 5 and 6 , the oxapiropentanes 7 and 8 , and the cyclobutanones 9a , 9b and 10a , 10b , respectively. The ¹³C-NMR.-spectra of 1–8 and 11 as well as the ORD.-spectra of the cyclobutanones 9 and 10 are reported.