Antiferromagnetism of type II in nonstoichiometric YbP

A polycrystalline smaple of nonstoichiometric ytterbium phosphide, YbP_0.84, was investigated by neutron scattering, Mössbauer spectroscopy and bulk magnetic measurements. Neutron diffraction experiments prove the existence of antiferromagnetic type II ordering belowT _N =0.64 K, in contrast to the observed antiferromagnetic type III ordering in the stoichiometric Kondo-like compounds YbN and YbAs. The temperature dependence of the average ordered magnetic moment per Yb³⁺ ion with saturation value _Yb = 1.03(7) _B is similar to that of YbN. Mössbauer experiments prove the magnetic phase transition to be first order with different regions in the sample having slightly different transition temperatures. By means of inelastic neutron scattering the crystal-field level scheme was established to be ₆ – ₈(19meV) – ₇(43meV).     

V4S9Br4: a novel high-spin vanadium cluster thiobromide with square-planar metal core

The novel vanadium thiobromide, V4S9Br4, with a square-planar metal cluster core was synthesized and characterized by single-crystal X-ray diffraction, measurements of magnetic properties and the heat capacity, and DFT calculations of the electronic structure. At the room temperature, the compound displays paramagnetic properties with an independent spin on each V atom and with a weak exchange constant (J approximately 10 cm(-1)). The paramagnetic state is transformed into a low-spin state (AF-type ordering) at low temperatures. This change is accompanied by a heat-capacity anomaly. The observed magnetic and heat-capacity anomalies can be explained by the thermal excitation of electrons on the closely spaced molecular energy levels in the presence of the Jahn-Teller effect.