STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES

The photopolymerization of acrylonitrile (AN) initiated with phenyl hydrazine (PHZ) and its derivatives has been studied. The initiator exponent and monomer exponent were determined from the kinetic investigation to be 0.66th and 2.1th respectively and the overall activation energy was 33.4KJ/mol for the PHZ-AN system. Spectral analysis and other data indicate that a charge transfer complex between PHZ as a donor and AN as an aceeptor is formed. The initiation mechanism was proposed.     

The Photopolymerization Kinetics of Acryl amide Sensitized with Toluidine Blue-Alcoholamine Induced by He-Ne Laser

Toluidine blue(TB) is a good sensitizer for the polymerization of acrylnmide(AM) induced by He-Ne laser. With TB as a sensitizer and various alcoholamine as donors, the photoredox of TB and the polymerization kinetics of AM induced by He-Ne laser were investigated. It was found that either for the photoredox of TB or for the polymerization of AM, the activity of alcoholamine increases in the order of EOA相似文献   

A New Approach to α—Bromochalcones

α-Bromo benzolymethylene triphenylphosphorane 3 has been synthesized by the reaction of benzoylmethylene triphenylphosphorane 1 with N-bromosuccinimide in the yield of 87% and can react with aromatic aldehydes 4 to give α-bromochalcones 5 in good yields.     

Effect of substituents (NH_2,OH,F) on structures and stability of lithofluorosilylenoids

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高分辨率磁旋转编码器磁鼓材料的研制

采用磁浆涂布工艺制作了磁鼓涂层材料.研究了不同组分的配方对磁鼓涂层材料性能的影响,制备出性能良好的磁鼓.对Φ32～40mm的磁鼓进行了充磁测试,写入了128和256对极.采用金属薄膜磁电阻传感探头检测磁鼓表面分布磁场,信号通过电路放大、整形后接入示波器和计数器,结果显示输出信号波形良好,计数完整.     

激光热致相变核-壳微胶囊的合成与性能

以甲基丙烯酸甲酯作为主要的核单体，甲基丙烯酸缩水甘油酯作为壳单体，叔胺盐作为壳的改性剂，合成了平均粒径为55nm具有激光热致相变性能的核壳微胶囊。用红外光谱对其结构进行了表征；用透射电镜观察了微胶囊形貌；用示差量热分析法、热重分析法测定了热性能、接触角仪测定了相变前后的亲水性，探讨了对相变效果的影响因素。核聚合物的玻璃化转变温度为56.2℃，壳聚合物的玻璃化转变温度为85.3℃；该微胶囊感激光后发生相变，接触角由初始的20°变为93°。     

无线局域网的Wardriving入侵检测

为了对无线网络进行入侵检测,设计并实现了无线网络安全监控系统.利用Libpcap函数对无线传输的原始包进行捕获;根据IEEE 802.11 MAC层协议,对原始包进行协议解码;利用统计分析检测方法,对基于主动扫描的Wardriving入侵进行检测.测试结果表明,该系统能及时发现Wardriving入侵.     

黄芩苷提取液中鞣质和蛋白质的去除

本实验用膨润土负载壳聚糖絮凝提纯，以除去黄芩浸液中的鞣质等杂质；用半透膜再次提纯去除蛋白质等大分子物质。用标准曲线法定量计算鞣酸的脱出率为48．8％。     

陡坡台阶式溢洪道中的水翅现象

水翅是陡坡台阶式溢洪道在流量较小时出现的一种水流现象。模型试验表明:当斜坡角度为40°～60°时,水翅存在于几乎整个跌落水流范围内,甚至持续到过渡水流;随着溢洪道底坡的增大,水翅存在的流量变化范围增大、高度增加;随着台阶尺寸的减小,水翅高度降低,所存在的流量变化范围缩小。     

基于网络结构的安全管理信息系统设计

文章根据安全管理信息系统的实际需要，结合计算机、非接触式IC卡、网络、数据库等技术，提出了基于网络体系结构的安全管理信息系统设计与实现方法．在系统的设计与实现过程中，分析了系统的硬件拓扑结构、软件功能结构、系统所用到的关键技术，同时对系统的性能机制给予了相应的说明．系统的硬件拓扑结构在计算机端采用星型拓扑结构，在下位机端采用总线拓扑结构，两种拓扑结构之间采用485—232转换器进行连接．软件系统针对不同的功能需要采用B／S、C／S混合结构，该种软件结构充分利用的C／S、B／S两种结构的优势，使系统的安全性、稳定性得到很大程度的提高．该系统已在天津人民广播电台投入实际使用，取得了良好的实际效果．