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981.
Min Chen Xu‐Dong Chen Miao Du 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(12):m570-m572
The title complex, [CdCl(NCS)(C10H8N2)]n, represents an unusual CdII coordination polymer constructed by two types of anionic bridges and 2,2′‐bipyridyl (bipy) terminal ligands. These two types of bridges are arranged around inversion centers. The distorted octahedral coordination of the CdII center is provided by two chloride ions, one N‐ and one S‐donor atom from two thiocyanate ions, and a pair of N atoms from the chelating bipy ligand. Interestingly, adjacent CdII ions are interconnected alternately by paired chloride [Cd...Cd = 3.916 (1) Å] and thiocyanate bridges [Cd...Cd = 5.936 (1) Å] to generate an infinite one‐dimensional coordination chain. Furthermore, weak interchain C—H...S interactions between the bipy components and thiocyanate ions lead to the formation of a layered supramolecular structure. 相似文献
982.
采用固相反应法,制备了不同成分的稀释磁性半导体Sn1-xMnxO 2(x=002,004,006).利用x射线衍射和傅里叶变换红外光谱法证明 了锰均匀地掺杂到二氧化锡中.在室温下研究了掺锰二氧化锡基稀释半导体的磁性,发现它具有明显的铁磁性 ,同时对磁性的强弱与锰的含量和烧结温度的关系作了研究.
关键词:
稀释磁性半导体
掺杂
烧结
铁磁性
1-xMnx O2')" href="#">Sn1-xMnx O2 相似文献
983.
984.
近年来铁基超导材料的发现掀起了又一轮新型超导材料研究的热潮,各种配方的铁基超导材料不断被制备出来,转变温度也不断提高,中国科学家在该领域取得了十分突出的成果,制备出了多种铁基超导材料,但对其交流损耗特性研究鲜有报道,而实际应用中交流损耗的特性又十分重要,因此搭建了一套采用探测线圈法的交流损耗测量平台,测试了一种中国科学院电工研究所采用PIT工艺制作的单芯铁基超导带材的交流损耗。该文介绍了采用探测线圈法测量超导材料交流损耗的一种测量平台的搭建与标定,以及采用标定过的测量平台在液氦温度下测量的一种采用PIT工艺制作的单芯铁基超导带材的交流损耗;并与计算得到的铁基带材超导芯的磁滞损耗和包套的涡流损耗进行了比较分析,得出了其交流损耗与背景磁场频率成正比,其涡流损耗可以忽略的结论。 相似文献
985.
We investigate the influence of a shifting environment on the spreading of an invasive species through a model given by the diffusive logistic equation with a free boundary. When the environment is homogeneous and favourable, this model was first studied in Du and Lin (SIAM J Math Anal 42:377–405, 2010), where a spreading–vanishing dichotomy was established for the long-time dynamics of the species, and when spreading happens, it was shown that the species invades the new territory at some uniquely determined asymptotic speed \(c_0>0\). Here we consider the situation that part of such an environment becomes unfavourable, and the unfavourable range of the environment moves into the favourable part with speed \(c>0\). We prove that when \(c\ge c_0\), the species always dies out in the long-run, but when \(0<c<c_0\), the long-time behavior of the species is determined by a trichotomy described by (a) vanishing, (b) borderline spreading, or (c) spreading. If the initial population is written in the form \(u_0(x)=\sigma \phi (x)\) with \(\phi \) fixed and \(\sigma >0\) a parameter, then there exists \(\sigma _0>0\) such that vanishing happens when \(\sigma \in (0,\sigma _0)\), borderline spreading happens when \(\sigma =\sigma _0\), and spreading happens when \(\sigma >\sigma _0\). 相似文献
986.
以苯胺和乙醇为原料,采用RaneyNi为催化剂,合成了N-乙基苯胺,再在相转移催化剂作用下,经苄基化反应得到标题化合物,第一步合成方法的收率比通常方法的收率提高约30%。 相似文献
987.
T. A. Du Plessis N. G. Schnautz A. Lustig 《Journal of polymer science. Part A, Polymer chemistry》1975,13(8):1911-1919
The radiation-induced copolymerization of vinyl acetate with diethyl maleate and with diethyl fumarate was investigated in the temperature range from ?40 to 90°C over a wide range of comonomer compositions. Both the rates of copolymerization and the molecular weights of the resulting copolymers were found to depend strongly on the initial comonomer compositions. The apparent activation energy was found to change at 13°C with an increase in temperature from a value of 1.76 kcal/mole to a value of 4.31 kcal/mole in the copolymerization with diethyl maleate, while in the case of the copolymerization with diethyl fumarate the apparent activation energy changed at 21°C from a value of 1.76 kcal/mole to a value of 5.98 kcal/mole. Scavenger studies indicate that a free-radical mechanism prevails over the entire temperature range investigated in the case of both copolymerizations. 相似文献
988.
Chen Wang Cheng Chen Mingxuan Ma Zijie Feng Yingxiang Du 《Journal of separation science》2022,45(14):2708-2716
Metal organic frameworks have received great attention as the chiral stationary phase for racemic drug separation because of their fascinating structures and properties. However, the most homochiral metal organic frameworks were constructed by rare and precious chiral organic ligands. In this work, an achiral metal organic framework, together with a natural chiral selector carboxymethyl β-cyclodextrin built a synergistic separation system in the open tubular capillary electrochromatography. The novel coated columns were developed by inducing metal organic framework nanoparticles to grow on the imidazolyl functional capillary inner wall. The baseline separations of hydroxychloroquine, ofloxacin, and atenolol were achieved in the synergistic separation system. The effects of the concentration of chiral selector, pH, voltage, and the concentration of organic additives were studied. Compared with chiral selector auxiliary bare capillary, the resolutions of three drugs were remarkably improved. The relative standard deviations for the retention time of intraday (n = 6), interday (n = 6), and column-to-column were less than 2.1, 2.6, and 5.2%, respectively. These results demonstrate that affordable synergistic separation systems are prospective for racemic drug enantioseparation in capillary electrochromatography. 相似文献
989.
缺失功能性p35基因的苜蓿尺蠖核形多角体病毒(AcNPV)突变体(vΔP35K/pol+)感染草地夜蛾细胞(Sf9和Sf21)[1]及海灰翅夜蛾细胞(SL2)[2]时,引起细胞凋亡,从而使病毒的感染流产.我们发现海灰翅夜蛾核形多角体病毒(SlNPV)... 相似文献
990.
MA Jianhua LIN Weizhen DU Fuqiang HAN Zhenhui YAO Side & LIN Nianyun .College of Biology Engineering Jimei University Xiamen China .Laboratory of Nanobiomedicine & Laboratory of Radiation Chemistry Shanghai Institute of Applied Physics Chinese Acade Sciences Shanghai China 《中国科学B辑(英文版)》2005,48(4):292-296
Quinones including menadione are ubiquitous in nature. They play important roles in aerobic respira- tion and photosynthesis[1,2]. In addition, exogenous quinones are used as antibiotics and anticancer drugs. Their function is closely related to their red… 相似文献