Surface-enhanced Raman scattering study of polymer on metals. III. Chemisorbed polybenzimidazole and its corrosion-inhibiting properties at high temperature

Chemisorption of polybenzimidazole on silver and copper etched with nitric acid has been observed by surface-enhanced Raman scattering (SERS). The polymer is found to react chemically with silver, forming a complexed film on the surface. The SERS spectra show that polybenzimidazole film inhibits oxidation of the metal at high temperature, unlike chemisorbed benzimidazole, benzotriazole, and poly(4-vinyl pyridine). © 1992 John Wiley & Sons, Inc.     

论拓扑一般Boole格的同态的可逆性

本文评述了“拓扑空间概论”一书中的一点疏忽.讨论了拓扑序集同态可逆性定义及与其相关的一些基本定理.     

试述泰山碧霞元君演进的三个阶段

按照历史与逻辑相统一的方法，可将泰山碧霞元君的演化进程划分为三个阶段。最初，由曹操的名篇《气出唱》创造出泰山云霞仙境中的天仙玉女这一审芙意象，曹植、李白等诗人又不断加以描写、渲染，从而使泰山玉女在中固古代社会享有很高的知名度。然后，宋真宗为这位神女易玉像、砻石龛。引导泰山玉女从诗人的作品中走出，走进了香火缭绕的宫祠。最后。明宪宗修宫祠、赐颠名，其影响所度，使得明清时期的碧霞元君在京城及全国各地建庙，香火大盛，碧霞元君一名也沿用至今。与此同时，道士们一方面凭着斋醮科仪、住持焚修和承办庙套、营造节庆的狂欢气氛，对泰山玉女进行了卓有成效的炒作；另一方面凭着一片赤诚，兢兢业业，惨淡经营。博得了几代朝廷及地方官员对各种奉祭碧霞元君活动的赞赏和支持，这就使泰山碧霞元君成为中国道教的一大主神。     

桥头跳车原因分析及质量控制

文章针对桥头跳车原因的形成 ,就解决方法从施工工艺及质量控制方面作了介绍。     

Melt rheology of polylactide/montmorillonite nanocomposites

In this article, the linear and nonlinear shear rheological behaviors of polylactide (PLA)/clay (organophilic‐montmorillonite) nanocomposites (PLACNs) were investigated by an Advanced Rheology Expanded System rheometer. The nanocomposites were prepared by master batch method using a twin‐screw extruder with poly(ε‐caprolactone) (PCL) as a compatibilizer. The presence of org‐MMT leads to obvious pseudo‐solid‐like behaviors of nanocomposite melts. The behaviors caused by the formation of a “percolating network” derived from the reciprocity among the strong related sheet particles. Therefore, the storage moduli, loss moduli, and dynamic viscosities of PLACNs show a monotonic increase with MMT content. Nonterminal behaviors exists in PLACNs nanocomposites. Besides the PLACNs melts show a greater shear thinning tendency than pure PLA melt because of the preferential orientation of the MMT layers. Therefore, PLACNs have higher moduli but better processibility compared with pure PLA. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3189–3196, 2007     

Bis[μ‐1‐(1,10‐phenanthrolin‐2‐yl)‐2‐pyridone]bis{aqua[1‐(1,10‐phenanthrolin‐2‐yl)‐2‐pyridone]cadmium(II)} tetrakis(perchlorate)

In the title centrosymmetric binuclear complex, [Cd₂(C₁₇H₁₁N₃O)₄(H₂O)₂](ClO₄)₄, the Cd^II ion assumes a distorted octahedral geometry. There are π–π stacking interactions between the pyridine and 1,10‐phenanthroline ring systems of adjacent ligands at the same Cd^II centre. Intermolecular hydrogen bonds between the coordinated aqua ligand and the O atom of a keto group connect adjacent complex cations into extended chains. Hydrogen bonds also exist between the complex cations and the perchlorate anions. Compared with the fluorescence spectrum of the organic ligand, the complex displays strong fluorescent emission and an ipsochromic shift of the emission peaks, which may be attributed to the structural character.     

对军队院校任职教育综合实践性教学体系建设的思考

本文从提高军队院校开展任职教育工作的效果出发,阐述了军队院校任职教育综合实践性教学体系建设的基本原则;总体设计了综合实践性教学体系的基本内容;提出了发展和完善综合实践性教学体系的基本措施。     

应急照明设计及其实际应用

介绍了应急照明的概念及其分类、应急照明的照度、应急照明的转换时间和持续工作时间、应急照明的电源、疏散照明与安全照明的设置以及娱乐场所应急照明的设计等内容。     

射频溅射金属前驱体硫化法制备的Cu2ZnSnS4薄膜

采用射频溅射技术沉积Cu／Sn／Zn金属前驱体叠层结合硫化技术在玻璃衬底上成功制备了Cu2ZnSnS4薄膜。X-射线衍射分析表明，通过优化制备条件可以获得单一黝锡矿结构且具有（221）择优取向的Cu2ZnSnS4薄膜。霍尔效应和紫外可见透过谱测量表明，样品的薄膜电阻、吸收系数和光学带隙分别达到0．073Ω·cm，10^4cm^-1和1．53eV，具有适合作为薄膜太阳电池吸收层应用的可能性。     

硫酸钾水溶液热力学性质的研究

用钾离子选择性电极测定硫酸钾水溶液中缔合反应在不同温度、不同离子强度时△H°、△G°、△S°.