Melt rheology of polylactide/montmorillonite nanocomposites

In this article, the linear and nonlinear shear rheological behaviors of polylactide (PLA)/clay (organophilic‐montmorillonite) nanocomposites (PLACNs) were investigated by an Advanced Rheology Expanded System rheometer. The nanocomposites were prepared by master batch method using a twin‐screw extruder with poly(ε‐caprolactone) (PCL) as a compatibilizer. The presence of org‐MMT leads to obvious pseudo‐solid‐like behaviors of nanocomposite melts. The behaviors caused by the formation of a “percolating network” derived from the reciprocity among the strong related sheet particles. Therefore, the storage moduli, loss moduli, and dynamic viscosities of PLACNs show a monotonic increase with MMT content. Nonterminal behaviors exists in PLACNs nanocomposites. Besides the PLACNs melts show a greater shear thinning tendency than pure PLA melt because of the preferential orientation of the MMT layers. Therefore, PLACNs have higher moduli but better processibility compared with pure PLA. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3189–3196, 2007     

Bis[μ‐1‐(1,10‐phenanthrolin‐2‐yl)‐2‐pyridone]bis{aqua[1‐(1,10‐phenanthrolin‐2‐yl)‐2‐pyridone]cadmium(II)} tetrakis(perchlorate)

In the title centrosymmetric binuclear complex, [Cd₂(C₁₇H₁₁N₃O)₄(H₂O)₂](ClO₄)₄, the Cd^II ion assumes a distorted octahedral geometry. There are π–π stacking interactions between the pyridine and 1,10‐phenanthroline ring systems of adjacent ligands at the same Cd^II centre. Intermolecular hydrogen bonds between the coordinated aqua ligand and the O atom of a keto group connect adjacent complex cations into extended chains. Hydrogen bonds also exist between the complex cations and the perchlorate anions. Compared with the fluorescence spectrum of the organic ligand, the complex displays strong fluorescent emission and an ipsochromic shift of the emission peaks, which may be attributed to the structural character.     

现代工程图学教学方法及教学手段的研究与实践

根据现代工程图学课程特点及学生学习本门课程存在的问题,通过对传统教学和多媒体教学的利弊分析,提出了传统教学与多媒体教学有机结合是现代工程图学课堂教学有效的教学模式的观点,介绍了适应课堂教学的多媒体课件的制作方法.同时,提出了网络教学是远程学习、选修课学习和课外学习有效的教学模式的观点,介绍了网络教学的特点、教学方法及现代工程图学网络教学系统的内容.     

对军队院校任职教育综合实践性教学体系建设的思考

本文从提高军队院校开展任职教育工作的效果出发,阐述了军队院校任职教育综合实践性教学体系建设的基本原则;总体设计了综合实践性教学体系的基本内容;提出了发展和完善综合实践性教学体系的基本措施。     

Flow-injection spectrophotometric determination of sulfadiazine and sulfamethoxazole in pharmaceuticals and urine.

A rapid and sensitive flow-injection spectrophotometric method is proposed for the determination of sulfadiazine and sulfamethoxazole. This method is based on the diazotization of sulfonamide with sodium nitrite, and a coupling reaction of the diazo-compound with alpha-naphthylamine. The optimum experimental conditions are obtained by using the controlled and weighted centroid simplex method. The linear ranges for the determination of sulfadiazine and sulfamethoxazole are 0.2-20 microg ml(-1) and 0.1-20 microg ml(-1), and their detection limits are 0.06 microg ml(-1) and 0.05 microg ml(-1), respectively, and the sampling frequency is 130 samples per hour. The method has been used to determine sulfadiazine and sulfamethoxazole in pharmaceuticals and urine without separation. The results are in agreement with those obtained by a high-performance liquid chromatograph technique at the 95% confidence level.     

山西省部分非试点县农村新型合作医疗的调查

建立推广新型合作医疗的要点是:加大宣传力度;加强领导,发挥政府主导作用;强化监督,加强管理,确保基金安全平稳运行;创新服务机制,完善便民措施,实现服务管理一体化。     

浅论Simulink在抗震教学中的应用

建筑结构抗震教学中的难点之一在于运动微分方程的求解,同时,该课程存在着学时少、内容多的矛盾。本文在分析Simulink软件的主要特征的基础上,提出将该软件引入抗震多媒体教学中能起到积极作用。     

知识挖掘在电信业客户关系管理中的应用

介绍了基于知识挖掘的电信业客户关系管理,分别从潜在用户、业务流程、客户行为角度探讨了知识挖掘在客户关系管理中的应用。     

应急照明设计及其实际应用

介绍了应急照明的概念及其分类、应急照明的照度、应急照明的转换时间和持续工作时间、应急照明的电源、疏散照明与安全照明的设置以及娱乐场所应急照明的设计等内容。     

大学语文教材对象语言的选择与教材编写

本文从教材语言的特点来探讨大学语文教材对象语言的选择与教材编写问题。首先，结合教材语言的基础性与功能性特点来分析大学语文教材建设过程中存在的一些问题；其次，结合教材语言的有线性、有序性、通用性与专业性特点来具体探讨教材对象语言的选择问题；最后，结合大学语文教材语言的特点和大学语文课程的定位来谈谈大学语文教材编写的发展方向。