密封恒温分光光度法快速测定化学需氧量

建立了密封恒温消解样品,测定化学需氧量（CDDcr)的分光光度法。应用正交试验法确定了密封恒温法消解试样的最佳条件,此方法有机物的氧化率为98.33%-99.50%。CODcr值在0-800mg/mL范围内符合比耳定律。样品测定的相对标准偏差为0.39%（n=12),加标回收率为97.50%-99.56%。用该法测得的CODcr值与标准回流法所得结果一致。     

高负荷间歇运动对自发性伸指肌腱断裂的修复性能研究

研究高负荷间歇运动对自发性伸指肌腱断裂的修复性能,将某医院患有自发性伸指肌腱断裂的78位患者作为研究对象,随机将其划分成高负荷间歇运动组和对照组,对照组在实验期间不进行任何运动,高负荷间歇运动组在功率自行车上进行高负荷间歇运动。长期进行高负荷间歇运动后,运动组的IGF-1mRNA表达与对照组相比差异具有显著性,运动组自发性伸指肌腱断裂患者指关节活动评定结果明显优于未进行高负荷间歇运动的患者,且握力明显增加。说明高负荷间歇运动能够提高自发性伸指肌腱断裂患者肌力与手部的整体功能,能够提高自发性伸指肌腱断裂患者的修复性能。     

The Aldol Reaction of Allenolates with Aldehydes in the Presence of Magnesium Diiodide (MgI2) as Catalyst

Stereoselective synthesis of (Z)‐α‐(hydroxyalkyl)‐β‐iodoacrylates (=(2Z)‐2‐(hydroxyalkyl)‐3‐iodoprop‐2‐enoates) was achieved in a one‐pot coupling reaction from methyl prop‐2‐ynoate, Me₃SiI, and an alkanal under mild conditions with MgI₂ as catalyst (→ 1 – 9 ; see Table and Scheme 1). Baylis‐Hillman β‐iodo adducts were generated in excellent yields with high (Z)‐selectivity. The conversion of methyl prop‐2‐ynoate to an active methyl 3‐iodo‐1‐[(trimethylsilyl)oxy]allenolate intermediate in situ followed by carbonyl addition is proposed as the reaction sequence (Schemes 1 and 2).     

迈克尔逊干涉仪中补偿板与干涉条纹

通过分析缺失补偿板的迈克尔逊干涉仪中的附加光程差,推出干涉条纹满足的方程式,并用计算机模拟了动镜移动过程中变化的干涉条纹,与实验结果相一致.     

亚微秒脉冲下高梯度绝缘子的沿面闪络特性

介绍了一种由聚酰亚胺和不锈钢叠加而成的高梯度绝缘子的实验研究工作。该绝缘子样品的直径60 mm,厚度8 mm,在脉冲宽度120 ns(FWHM)的电压脉冲加载下最高获得了接近13 MV/m的绝缘强度。研究了测试方法以及绝缘层厚度与金属层厚度的比例对高梯度绝缘子绝缘强度的影响,并与相同尺寸的普通材料绝缘子的绝缘强度进行了对比。结果表明,高梯度绝缘子的绝缘强度明显高于仅由聚酰亚胺构成的普通绝缘子。     

Ka波段8路径向波导空间功率分配（合成）器

通过理论研究以及高频仿真相结合的方法分析设计了一款新型Ka波段8路径向波导空间功率分配（合成）器。研发的新结构输入输出段为标准矩形波导结构,代替了传统功率分配（合成）器输入输出段的同轴结构,这种新型全金属结构更加简单紧凑,更易于加工。仿真结果表明：功率分配（合成）器工作带宽达到了34%（12 GHz）,基本覆盖整个Ka波段;全频带内反射系数S11低于-20 dB,各支路的相位差均小于5。通过在同轴波导渐变段引入切比雪夫渐变结构,在减小了器件尺寸的同时,在整个频带内的网络S参数也不错。这款新型Ka波段8路径向波导功率分配（合成）器将应用于前级固态功率放大器,推动回旋行波管项目研发。     

Simultaneous determination of atropine,scopolamine, and anisodamine from Hyoscyamus niger L. in rat plasma by high‐performance liquid chromatography with tandem mass spectrometry and its application to a pharmacokinetics study

In order to investigate the pharmacokinetics of tropane alkaloids in Hyoscyamus niger L., a sensitive and specific high‐performance liquid chromatography with tandem mass spectrometry method for the simultaneous determination of atropine, scopolamine, and anisodamine in rat plasma is developed and fully validated, using homatropine as an internal standard. The separation of the four compounds was carried out on a BDS Hypersil? C₁₈ column using a mobile phase consisting of acetonitrile and water (containing 10 mmol ammonium acetate). Calibration curves were linear from 0.2 to 40 ng/mL for atropine, scopolamine, and from 0.08 to 20 ng/mL for anisodamine. The precision of three analytes was <5.89% and the accuracy was between ?1.04 to 2.94%. This method is successfully applied to rat pharmacokinetics analysis of the three tropane alkaloids after oral administration of H. niger extract. The maximum concentration of these three tropane alkaloids was reached within 15 min, and the maximum concentrations were 31.36 ± 7.35 ng/mL for atropine, 49.94 ± 2.67 ng/mL for scopolamine, and 2.83 ± 1.49 ng/mL for anisodamine. The pharmacokinetic parameters revealed areas under the curve of 22.76 ± 5.80, 16.80 ± 3.08, and 4.31 ± 1.21 ng/h mL and mean residence times of 2.08 ± 0.55, 1.19 ± 0.45, and 3.28 ± 0.78 h for atropine, scopolamine, and anisodamine, respectively.     

长叶烯通过异构化,氧化和Prins反应合成新型香料

本文报道综合利用长叶烯（１）催化异构化为异长叶烯（２）及合成系列香料的方法；通过氧化反应合成不同香型烯醇酯类等；Ｐｒｉｎｓ反应合成系列化合物。鉴定了１０种香料化合物的香型。