Effect of particle agglomeration and interphase on the glass transition temperature of polymer nanocomposites

In this article, we utilize finite element modeling to investigate the effect of nanoparticle agglomeration on the glass transition temperature of polymer nanocomposites. The case of an attractive interaction between polymer and nanofiller is considered for which an interphase domain of gradient properties is developed. This model utilizes representative volume elements that are created and analyzed with varying degrees of nanoparticle clustering and length scale of interphase domain. The viscoelastic properties of the composites are studied using a statistical approach to account for variations due to the random nature of the microstructure. Results show that a monotonic increase in nanofiller clustering not only results in the loss of interphase volume but also obstructs the formation of a percolating interphase network in the nanocomposite. The combined impacts lead to a remarkable decrease of T_g enhancement of clustering nanofillers in comparison with a well‐dispersed configuration. Our simulation results provide qualitative support for experimental observations that clustering observed at high nanofiller concentrations negatively impacts the effects of the nanofiller on overall properties. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011     

Oleanane‐Type Triterpenoids from the Endophytic Fungus Pestalotiopsis clavispora Isolated from the Chinese Mangrove Plant Bruguiera sexangula

Three new triterpenoid derivatives, named (15α)‐15‐hydroxysoyasapogenol B ( 1 ), (7β,15α)‐7,15‐dihydroxysoyasapogenol B ( 2 ), and (7β)‐7,29‐dihydroxysoyasapogenol B ( 3 ), were isolated from cultures of the plant endophytic fungus Pestalotiopsis clavispora. Their structures and relative configurations were elucidated by extensive spectroscopic analysis and X‐ray crystallography.     

A sharper uncertainty principle

The work strengthens the result established by L. Cohen on uncertainty principle involving phase derivative. We propose stronger uncertainty principles not only in the classical setting for Fourier transform, but also for self-adjoint operators. We also deduce the conditions that give rise to the equal relation of the uncertainty principle. Examples are provided to show that the new uncertainty principle is truly sharper than the existing ones in literature.     

Quantum superposition of localized and delocalized phases of photons

Based on a variant of 2-site Jaynes–Cummings–Hubbard model constructed using superconducting circuits, we propose a method to coherently superpose the localized and delocalized phases of microwave photons, which makes it possible to engineer the collective features of multiple photons in the quantum way using an individual two-level system. Our proposed architecture is also a promising candidate for implementing distributed quantum computation since it is capable of coupling remote qubits in separate resonators in a controllable way.     

K3PO4 promoted dipolar [3+3] cyclization: Direct synthesis of pyrazino[2,1-a]isoquinoline derivatives

A K₃PO₄ promoted dipolar [3+3] cyclization of dihydroisoquinoline imines and arylacyl bromides has been developed. This process realized the direct synthesis of pyrazino[2,1-a]isoquinoline derivatives in 44–69% yields. A head to tail dimerization was proposed as key step for this procedure.     

机械手模型的PLC控制系统设计

利用S7--300系列PLC对机械手进行控制，详细阐述了系统的主回路和控制回路工作原理以及接线图。     

Design study for the cascaded HGHG experiment based on the SDUV-FEL

Cascading stages of high-gain harmonic generation(HGHG) free electron laser(FEL) is a promising way to produce fully coherent X-ray radiation.As a test facility for modern FEL R&D,the Shanghai deep ultraviolet FEL(SDUV-FEL) is now under upgrading for the cascading two stages of HGHG experiment.Since the energy of the electron beam is as low as about 185 MeV after upgrade,the total harmonic number of this two stages HGHG is only 2×2,and the wavelength of the final radiation is 196.5 nm which is the 4th harmonic of the 786 nm seed laser.With help of three-dimensional simulation codes,design studies on the FEL physics for the cascaded HGHG experiment are present based on the parameters of the upgraded SDUV-FEL facility.It is found from the simulation results that the part of the electron beam which has been used in the first stage can still generate powerful radiation in the radiator of the second stage,and this radiation will be difficult to be separated from the radiation generated by the fresh part of the electron beam.To overcome this problem,a novel method based on the energy spectrum of the electron beam is proposed in this paper to demonstrate the "fresh bunch" technique.     

Expansion of potential 1/r12 of c‐spherical harmonics

The expansion coefficient C^D_|L| of Coulomb potential 1/r₁₂ of atomic system in hyper‐spherical harmonics is derived and the explicit expression is given.     

Synthesis, activity evaluation and 3D-QSAR study of some novel derivatives of 4, 5, 6, 7-tetrahydrothieno [3,2-c] pyridine

A series of novel derivatives of 4, 5, 6, 7-tetrahydrothieno [3,2-c] pyridine were synthesized and structurally characterized by 1H NMR and MS. Their in vivo anti-platelet aggregation activities were evaluated. A 3D-QSAR was performed using the CoMFA and the CoMSIA. This model provided useful guidelines for novel anti-platelet thienopyridines design.