乙酰苯胺衍生物的~1H和~(13)C NMR谱的研究

本文测定了10个乙酰苯胺衍生物的~1H,~(13)C NMR谱,采用质子自旋去偶,质子选择去偶,质子偏共振去偶,质子去偶的~(13)C DEPT和选择INEPT等技术对其谱线进行归属。系统地研究了围绕羰基碳氮键的受阻旋转,确认了该类化合物在溶液中存在E和Z型构象体,并探讨了各种取代基对形成异构体比例的影响。     

培养学生解决幂级数问题的思维能力

通过幂级数与初等函数两种形式互换,灵活运用公式,探索解题的方法和途径     

离子束增强沉积纳米Fe—N磁性膜

利用高能量（〉１５ｋｅＶ）、脉冲氮离子束增强沉积（ＩＢＥＤ）Ｆｅ－Ｎ磁性薄膜。合成了含有α－Ｆｅ、α″－Ｆｅ１６Ｎ２、γ＇－Ｆｅ４Ｎ和ε－Ｆｅ２￣３Ｎ相的纳米多晶薄膜。Ｆｅ－Ｎ薄膜的磁性取决于膜层的相结构及微观形貌。纳米尺度的α″－Ｆｅ１６Ｎ２和α－Ｆｅ相的混合物膜层的饱和磁性强度可达２４５ｅｍｕ／ｇ。多元ＩＢＥＤ Ｆｅ－Ｃｏ－Ｎ合金薄膜与相同制备条件下合成的Ｆｅ－Ｎ薄膜相比，其相结构相似，但饱和     

NMR研究溶剂与碱金属离子竞争配位过程

本文研究了锂、铵、钠、铯等盐类在21种溶剂中的~7Li、~(14)N、~(23)Na、~(133)Cs/NMR谱。考察了溶剂对碱金属离子化学位移的影响,求出了浓度系数。并研究了上述离子在15种二元溶剂体系中竞争配位过程,基于NMR数据,测定了等溶剂化点,交换过程平衡常数K及自由能变化△G等热力学参数。     

化学氧碘激光器非稳腔的研究

设计并研究了适合于连续波超音速化学氧碘激光器的正支共焦非稳腔，给出了放大率、输出功率和光束质量的实验结果。     

A smoothing Newton method for mathematical programs constrained by parameterized quasi-variational inequalities

We consider a class of mathematical programs governed by parameterized quasi-variational inequalities(QVI).The necessary optimality conditions for the optimization problem with QVI constraints are reformulated as a system of nonsmooth equations under the linear independence constraint qualification and the strict slackness condition.A set of second order sufficient conditions for the mathematical program with parameterized QVI constraints are proposed,which are demonstrated to be sufficient for the second o...     

Identification of Herbal Compound Imperatorin with Adverse Effects on ANO1 and CFTR Chloride Channels

Calcium-activated chloride channels(CaCCs) are the crucial regulators of transepithelial fluid secretion, smooth muscle contraction and sensory transduction. Recently, compelling evidence has indicated that TMEM16A(ANO1 or anoctamin-1) is a bona fide calcium-acvtivated chloride channel. A few small molecule CaCCs regulators are available for functional and therapeutic studies. We screened 126 natural compounds from Chinese herbs. Screening was performed with an iodide influx assay in Fischer rat thyroid epi...     

An adaptive version of ghost-cell immersed boundary method for incompressible flows with complex stationary and moving boundaries

An adaptive version of immersed boundary method for simulating flows with complex stationary and moving boundaries is presented.The method employs a ghost-cell methodology which allows for a sharp representation of the immersed boundary.To simplify the implementation of the methodology,a volume-of-fluid method is introduced to identify the immersed boundary.In addition,the domain is spatially discretized using a tree-based discretization which is relatively simple to implement a fully flexible adaptive refi...     

Electroless Nickel Plating and Electroplating on FBG Temperature Sensor

Metal-coated fiber Bragg grating（FBG）temperature sensors were prepared via electroless nickel（EN）plating and tin electroplating methods on the surface of normal bare FBG.The surface morphologies of the metal-coated layers were observed under a metallographic microscope.The effects of pretreatment sequence,pH value of EN plating solution and current density of electroplating on the performance of the metal-coated layers were analyzed.Meanwhile, the Bragg wavelength shift induced by temperature was monitored by an optical spectrum analyzer.Sensitivity of the metal-coated FBG（MFBG）sensor was almost two times that of normal bare FBG sensor.The measuring temperature of the MFBG sensor could be up to 280℃,which was much better than that of conventional FBG sensor.     

基于恒定应力加速寿命试验法评估深弹贮存寿命

深弹贮存寿命试验是考核产品寿命能否达到可靠性指标的关键内容,目的是检验在包装箱内、仓库保管条件下,深弹贮存寿命是否满足研制要求。贮存寿命试验方法的设计和实施直接影响试验的可靠性水平。目前,国外常用自然环境贮存试验监测法和加速寿命试验评估法估计深弹的贮存寿命。自然环境贮存试验数据真实可靠,试验周期长,难以实现;加速寿命试验是在既不改变产品的故障机制又不增加新的故障机制的前提下,提高试验应力,加速产品的故障进程,缩短试验时间,根据试验结果估计出正常应力下的产品寿命。针对影响深弹贮存寿命的主要因素和灵敏参量,依据深弹贮存寿命与温度等因素的关系,基于阿伦尼斯加速方程,设计了恒定应力加速寿命试验方法来评估深弹贮存寿命。