A new ent-labdane eiterpenoid lactone from Andrographis paniculata

A new ent-labdane diterpenoid lactone with a new natural product was isolated from Andrographis paniculata. Their structures were elucidated on the basis of spectral evidences including 2D NMR.     

First-principles calculation of core-level binding energy shift in surface chemical processes

Combined with third generation synchrotron radiation light sources, X-ray photoelectron spectroscopy (XPS) with higher energy resolution, brilliance, enhanced surface sensitivity and photoemission cross section in real time found extensive applications in solid-gas interface chemistry. This paper reports the calculation of the core-level binding energy shifts (CLS) using the first-principles density functional theory. The interplay between the CLS calculations and XPS measurements to uncover the structures,...     

Isolation and Purification of Unstable Iridoid Glucosides from Traditional Chinese Medicine by Preparative High Performance Liquid Chromatography Coupled with Solid-phase Extraction

An efficient preparative method was successfully developed for isolation and purification of unstable components from medicinal plant extracts, using a combined method of preparative high performance liquid chro-matography(HPLC) and solid-phase extraction(SPE). The aim of this study was to obtain an effective method with high preparative efficiency and importantly to avoid the transformation of unstable compounds. The preparative HPLC system was based on an LC/MS controlled four-channel autopurification sys...     

β-榄香烯振动光谱的量子化学从头计算

利用G98及GAMESS从头计算程序的RHF／6－31方法,对β－榄香烯的全部振动基频作了计算,并与实测红外光谱做了对比,归属了它们的振动模式,讨论了它们的特征基频,并对理论计算的振动频率进行了标度校正。     

The determination of atmospheric phosphine in Ny-lesund

Phoshpine (PH3), a volatile and toxic gas, has been proved to commonly exist in the environment.The determination of gaseous phosphine and its emission fluxes in Ny-lesund is reported in this paper.Results showed that gaseous phosphine exist in Arctic atmosphere commonly and the concentration of phosphine ranged from 16.3-600.2 ng/m3, with the maximum concentration of phosphine in tundra areas and the minimum in surface air of ocean.The concentration of phosphine ranged from 65.79-1259 ng/m3 in colliery at...     

辽南丘陵区小区域土地研究——以金县东南部为例

本文以金县东南部为例,采用定性与定量相结合的方法,对辽南丘陵区小区域土地的形成、分异、演化规律、土地的类型、结构特征、土地质量评价作了较为系统的研究,为辽南丘陵小区域土地研究提供了一个模式。文章在综合研究各土地要素特征及其相互关系的基础上,采用二级分类系统定性地划分出6个土地类,53个土地型。研究表明:丘陵区小区域土地分异的主导因素是中小地貌的差异。土地类型结构与地貌类型及其组合特征密切相关。在划分出宜农、宜林地的基础上,以土地型为评价单元,运用模糊聚类方法进行了土地资源质量分等评价,为合理利用土地资源、进行土地生态设计提供了科学依据。     

集散控制系统在面粉生产中的应用

从硬件、软件等方面介绍集控制系统在面粉生产中的应用情况。     

AI-2 Key Enzyme S-Ribosylhomocysteinase from Strain Klebsiella pneumoniae CICC 10011 Producing 2,3-Butanediol

S-Ribosylhomocysteinase(LuxS) is the key enzyme in the synthetic pathway of a quorum sensing autoinducer AI-2. LuxS from a 2,3-butanediol produced strain Klebisella pneumoniae CICC 10011 was cloned and characterized. The luxS gene is composed of 540 bp with 172 amino acids encoded. The Km value for S-ribosylhomo- cysteine(SRH) was (27±1) umol/L, kcat was (0.112±0.004) s-1 and kcat/Km was 4.4×103 L umol-1·s-1 at 25 ℃. LuxS was activated by divalent metal ions, the highest activity was detected with Co2+ form...     

电化学修形齿轮齿面微观形貌与摩擦学特性

以电化学修形前后的齿面微观不平度高度的特性和形状特性进行了分析和测算，研究了电化学表面平滑化对齿面摩擦，齿面闪温及润滑状态的影响；证明电化学修形能延长齿轮的使用寿命。     

关于P-Laplace方程解的梯度HOlder连续性的一个注记

对文献〔１—３〕中的结果：ｕｔ＝ｄｉｖ（｜ｕ｜ｐ－２ｕ）在ΩＴ＝Ω×（０，Ｔ）上弱解的空间梯度是Ｈｌｄｅｒ连续的做一个补充．在这个注记里，本文作者讨论条件Ｐ＞ｍａｘ｛１，２ＮＮ＋２｝是怎样由ｕ的性质所确定的．属于ＬＮｌｏｃ（ΩＴ）空间解的梯度是Ｈｌｄｅｒ连续的条件仅仅是Ｐ＞１．