化学反应速率的量子理论

本文分析了Eyring的绝对反应速率理论的假设基础,指出此理论的反应物与过渡态在反应过程中总是处于化学平衡的假设是不能成立的.文中由薛定谔的非定态方程推导了反应的微观速率常数,并由假定始态分子处于统计平衡。推导了化学反应的宏观速率常数的表达式.在主要特征上,此表达式同Eyring的公式是相同的,不同的是反应速率常数除了同反应的活化能有关外,还同过渡态到产物态的相互作用矩阵元有关.由此本文证明了在反应过程中轨道对称性守恒的定律.     

一种体系化分布式水下防御能力验证系统设计与仿真

 设计了一种基于真实-虚拟-构造（LVC）资源集成的体系化分布式水下防御能力验证系统；建立了系统的基本架构，设计了系统主要功能，根据功能需求设计了核心功能模型。同时，建立了基于各类影响因素的行动能力评估模型，能够辅助进行关键要素对行动能力影响的分析与研究。通过仿真试验，验证了系统的评估能力。     

关于《电路分析基础》教学的探讨

《电路分析基础》是电子信息专业、计算机科学与应用专业和通信工程专业等的专业基础课,比较难学难懂,学生做题时更是无从下手,没有思路。特别是学到正弦稳态电路分析内容时,更是如堕五里云雾中。本文通过借鉴一些有经验的教学方法与自己几年的教学经验相结合,采用了"触类旁通"、"习旧知新"等方法进行教学过程,为改善电路分析教学提供了新的思路。     

航空发动机主轴-轴承系统温度场分析

在对航空发动机主轴-轴承系统热力学分析基础上,对主轴-轴承系统的发热、传导、对流、辐射等进行了分析,利用热路网络热流量平衡原理,建立了相应的热平衡方程组,并用数值分析方法对系统温度场进行了数值求解。实例计算和试验测试结果对比分析表明：所选节点温度的计算值和实测值之间相差不足1．2％,反映出本文建立的航空发动机主轴-轴承系统温度场计算数学模型具有很高的精确度,完全适用于一般的主轴-轴承系统温度场理论计算与分析。     

熔石英相位共轭镜无损工作状态分析

基于非线性光学耦合波方程组建立了聚焦泵浦条件下熔石英玻璃材料中SBS过程的物理模型并编制了相应的数值求解程序,研究了SBS介质内激光场的时空发展特征,从而试图揭示SBS介质的内在破坏机制并寻求相应的加固措施.通过数值模拟程序研究了焦点处激光功率密度以及SBS反射率与激光能量的依赖关系,发现SBS对介质内的激光场具有"限幅"作用,即在注入能量大幅度提升的情况下,内部的激光场强度只有较小的增加,这种机制使大能量的固体介质PCM成为可能.分析激光脉宽以及耦合透镜焦距等参数对SBS过程的影响发现,精细选择系统参数,在熔石英玻璃材料中有可能无损伤地实现高效的SBS过程.     

Retention of configuration in the nucleophilic substitution reactions of some nine-membered ansa derivatives of cyclotriphosphazatriene

X-ray crystallographic evidence shows that nucleophilic substitution reactions of two different types of cyclophosphazene derivatives with relatively rigid nine-membered ansa rings leads to the first demonstration of retention of configuration in these molecular systems.     

Chiral polymers containing a carbohydrate moiety: synthesis

This paper reports the preparation of poly(acetal-ethers) by two alternative synthetic pathways (alkaline and acid-catalyzed conditions). Polycondensations of methyl 2,3:4,6-di-O-salicylidene-alpha-D-mannopyranoside (3) (mixtures of endo-H and exo-H dioxolan-2-yl-diastereomers) with 1,4-dibromobutane (4) (method I a and I b) were performed in solvents (DMF, butyl acetate/DMF, DMSO) and were catalyzed by K2CO3/KI or KOH. A similar polymer (6) was formed by the reaction of methyl alpha-D-mannopyranoside (1) and 1,4-bis(2-formylphenoxy)butane (7), catalyzed by p-toluenesulfonic acid (method II). Regardless of conversion or initial comonomer feed ratios, the composition of the polycondensates depended on the reaction conditions, leading to the formation of macrocyclic [1 + 1] (5) and [2 + 2] compounds, which were macromolecules with diverse molecular weights and optical properties. The regioselective polycondensation was examined by 1H NMR spectroscopy of selected polymers. In the case of 5-membered cyclic acetal units, mixtures of the endo-H and exo-H dioxolan-2-yl system, diastereomers were formed in the polymer chain. The macrocycles and linear oligomers were identified by NMR and electrospray mass spectrometry (ESI-MS). Thermodynamically controlled reactions for making macrocycles as well as oligomers in the absence of templates are also discussed.     

Proton source size measurements in the eA-->e'ppX reaction

Two-proton correlations at small relative momentum q were studied in the eA(3He,4He,C,Fe)-->e(')ppX reaction at E(0)=4.46 GeV using the CLAS detector at Jefferson Lab. The enhancement of the correlation function at small q was found to be in accordance with theoretical expectations. Sizes of the emission region were extracted, and proved to be dependent on A and on the proton momentum. The size of the two-proton emission region for He was measured in eA reactions for the first time.     

混合稀土对AB5贮氢合金织构生长特性影响的PLS研究

利用偏最小二乘法（PLS）研究混合稀土组成对贮氢合金的织构生长特性的综合影响,并提出了合金织构择优取向的判据。对于平行于柱状晶织构,择优取向（101） (201)晶面受Nd的影响最为敏感,Ce的影响最小,同时Ce对择优取向的作用与La,Pr,Nd的作用相反;对于垂直柱状晶织构,择优取向（200） (110)晶面受Pr的影响最为敏感,而受Nd的影响最小。     

新疆若羌县赤石山变质核杂岩研究

新疆北山裂谷带西缘若羌县赤石山地区存在大型变质核杂岩构造。其下拆离盘为古元古界结晶基底杂岩 ,上拆离盘为中元古界白湖群变质岩系 ,滑脱拆离带为已变形的大型韧性正断层。核杂岩南、北侧发育上叠盆地 ,北侧形成“年轻”正断层及同构造期岩浆岩。变质核杂岩的形成与晚古生代北山陆内裂谷区域伸展有直接联系。该区变质核杂岩的首次厘定 ,对深化北山裂谷的研究具有重要意义