弹性球体在冲击载荷下的应力波传播

给出了弹性球体在冲击载荷下应力波传播的解析解。该解法是利用特征函数展开法，将动力学的一般解分解为满足非齐次边界条件的准静态解和仅满足齐次边界条件的自由振动解，其中准静态解满足欧拉方程，而自由振动解满足贝塞尔(Bessel)方程。利用分离变量法，贝塞尔(Bessel)方程的解是一个由球贝塞尔函数构成的级数形式解，然后将此解和准静态解叠加，可得弹性动力学问题的解。与特征线法，积分变换法，广义射线法相比具有物理意义更加明确，数学解法更加简明的优点，同时这一解法可以推广到任意载荷下，各向同性弹性动力学中的一般球对称问题。     

扇、轮和完全图的r(2)点色数

提出了图的r(2)点染色的概念,研究了扇Fn、轮Wn、完全图Kn的r(2)点染色问题,并得到了它们的r(2)点色数.     

城市化进程中上海植被的多样性、空间格局和动态响应(Ⅰ):上海佘山地区残存自然植被种子植物区系及其50年的动态变化特征

通过对上海余山地区残存自然植被的区系分析,研究了城市化与片断化过程中自然植物种类的变化特征.利用样线法对十座山体进行调查,共记录野生种子植物85科235属350种,地理成分分布类型上共划分为13个分布区类型和10个变型.研究发现:佘山地区山体物种数与面积之间存在显著相关;作为天目山的余脉,佘山地区植物区系与天目山植物区系存在有极强的近缘关系;相比于1950年代的植物名录,佘山地区有178种自然种子植物未被发现,以多年生草本为主.     

光声喇曼光谱的理论分析

对光声喇曼光谱(PARS)作了系统的理论分析,分别导出固体和液体介质中的光声喇曼光谱的信号表达式,并进行了数值估算。 关键词：     

Solvent and concentration effects on the properties of electrospun poly(ethylene terephthalate) nanofiber mats

This study describes the preparation and characterization of nanofibrous mats obtained by electrospinning poly(ethylene terephthalate) (PET) solutions in trifluoroacetic acid/dichloromethane (TFA/DCM). Special attention was paid to the effect of polymer concentration and solvent properties on the morphology, structure, and mechanical and thermal properties of the electrospun nonwovens. The results show that the spinnable concentration of PET solution in TFA/DCM solvents is above 10 wt %. Mats have nanofibrous morphology with fibers having an average diameter in the range of 200–700 nm (depending on polymer concentration and solvent composition) and an interconnected pore structure. Higher solution concentration favors the formation of uniform fibers without beads and with higher diameter. Morphology and fiber assembly changed with the solvent properties. Solvent mixtures rich in TFA, i.e., those with higher dielectric constant and lower surface tension, originated fibers with small diameter. However, due to the lower volatility, those solvent mixtures also produced more branched and crosslinking fibers, with less morphologic uniformity. Mechanical properties (Young's modulus, ultimate strength, and elongation at break) and thermal properties (glass transition, crystallization, and melting) have been studied for the PET electrospun nanomats and compared with those of the original polymer. Solvent effect on fiber crystallinity was not significant, but a complex effect was observed on the mechanical properties of the electrospun mats, as a consequence of the different structural organization of the fibers within the mat network. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 460–471, 2008     

香豆素类化合物的一种新合成方法

香豆素类化合物是一类重要的有生物活性的天然产物,也可用作香料、阻凝剂和三线态光敏剂。用 Meldrum 酸合成该类化合物,已有一些报道。我们在研究 Meldrum 酸系列     

十二烯基丁二酸改性氧化锆色谱固定相性能研究

本文用十二烯基丁二酸（DSA）改性氧化锆得到一种新的锆基质色谱固定相。改性前后的红外光谱的差异表明，DSA以两个羧基与氧化锆结合，由于多位点结合方式提高了固定相的稳定性，因此固定相可以在碱性（pH8．5）条件下稳定使用。锆基质色谱固定相具有较强的疏水性，用于中性及碱性化合物的分离取得了满意的结果。     

龙爪芦荟和库拉索芦荟中微量锗的测定与红外光谱区别

采用吸光光度法对龙爪芦荟和库拉索芦荟中的微量锗进行了测定,并探讨了两种芦荟的红外光谱的区别。结果表明,龙爪芦荟中含锗量在26.1～28.6μg·g-1,回收率为91.6%～97 5%。库拉索芦荟中含锗量在16.8～20.0μg·g-1,回收率为87.1%～94.5%。两种芦荟的FT IR光谱图在2100cm-1处有明显差异,由此可区别两种芦荟。     

微波促进的N-取代2,3,3a,4,7,7a-六氢异吲哚-1,3-二酮的Beller法合成

A rapid and facile synthesis of N-substituted 2,3,3a,4,7,7a-hexahydroisoindole-l,3-dione derivatives via microwave-promoted Beller three-component domino reaction of α,β,-unsaturated aldehydes, amides and N-substituted maleimides was described.