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101.
Nyangulu JM Galka MM Jadhav A Gai Y Graham CM Nelson KM Cutler AJ Taylor DC Banowetz GM Abrams SR 《Journal of the American Chemical Society》2005,127(6):1662-1664
An affinity probe has been developed for isolation of receptor proteins that bind the plant hormone abscisic acid (ABA). The structural features required for biological activity have been preserved, and the probe has been demonstrated to bind to known ABA-binding proteins. 相似文献
102.
Isaacs SR Cutler EC Park JS Lee TR Shon YS 《Langmuir : the ACS journal of surfaces and colloids》2005,21(13):5689-5692
This paper shows that an introduction of thiosulfate anions in place of bromide anions greatly improves both chemical and thermal stability of tetraoctylammonium-protected gold nanoparticles. Tetraoctylammonium thiosulfate [(Oct)4N+-O3SS]-protected gold nanoparticles are synthesized by the reduction of (Oct)4N+-AuCl4 to Au(I)-SSO3-, followed by the addition of sodium borohydride. The presence of thiosulfate anions instead of bromide anions on the surface of gold nanoparticles results in a significant dampening of the surface plasmon band of gold at 526 nm due to the strong interaction between thiosulfate and the gold nanoparticle surface. Cyanide decomposition and heating treatment studies suggest that (Oct)4N+-O3SS-protected nanoparticles have much higher overall stability compared to (Oct)4N+-Br-protected gold nanoparticles. 相似文献
103.
Silver staining has been the method most commonly employed for high sensitivity staining of proteins following two-dimensional gel electrophoresis. Whilst this method offers detection in the nanogram range it does have major drawbacks including a lack of linearity, nonstoichiometric staining of proteins, a lack of compatibility with the microchemical preparation of proteins for identification by mass spectrometric techniques, and a highly subjective assessment of the staining endpoint. SYPRO Ruby is a relatively new, ruthenium complex-based stain which is reported to offer advantages over silver, particularly in overcoming the limitations cited above. We describe a series of experiments where several protein staining procedures commonly employed are compared. To enable optimization of the in situ digestion procedure, a statistical approach has been undertaken. The effects of a variety of staining, digestion, and analysis protocols on the downstream processing of a test radiolabeled protein were studied. The data confirms that as well as offering sensitivity similar to silver, SYPRO Ruby staining is reproducible, linear, and offers a higher level of compatibility with the identification of proteins by mass spectrometry. 相似文献
104.
105.
Melvin Cutler 《Journal of Non》1976,21(1):137-141
Bond orbital considerations show that a third covalent band in tellurium is unstable unless the concentration of threefold bonded (3F) tellurium atoms is smaller than the concentration of dangling bonds. At low hole concentrations, the formation of 3F atoms is inhibited further because of non-linear screening of their positive charge, which results in a large electrostatic energy. Consequently 3F bonding becomes important only in liquids whose electrical conductivity is higher than an estimated value . 相似文献
106.
Liliana Mou Petra Martini Gaia Pupillo Izabela Cieszykowska Cathy S. Cutler Renata Mikoajczak 《Molecules (Basel, Switzerland)》2022,27(5)
Is the 67Cu production worldwide feasible for expanding preclinical and clinical studies? How can we face the ingrowing demands of this emerging and promising theranostic radionuclide for personalized therapies? This review looks at the different production routes, including the accelerator- and reactor-based ones, providing a comprehensive overview of the actual 67Cu supply, with brief insight into its use in non-clinical and clinical studies. In addition to the most often explored nuclear reactions, this work focuses on the 67Cu separation and purification techniques, as well as the target material recovery procedures that are mandatory for the economic sustainability of the production cycle. The quality aspects, such as radiochemical, chemical, and radionuclidic purity, with particular attention to the coproduction of the counterpart 64Cu, are also taken into account, with detailed comparisons among the different production routes. Future possibilities related to new infrastructures are included in this work, as well as new developments on the radiopharmaceuticals aspects. 相似文献
107.
The Maximum Number of Complete Subgraphs of Fixed Size in a Graph with Given Maximum Degree
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In this article, we make progress on a question related to one of Galvin that has attracted substantial attention recently. The question is that of determining among all graphs G with n vertices and , which has the most complete subgraphs of size t, for . The conjectured extremal graph is , where with . Gan et al. (Combin Probab Comput 24(3) (2015), 521–527) proved the conjecture when , and also reduced the general conjecture to the case . We prove the conjecture for and also establish a weaker form of the conjecture for all r. 相似文献
108.
Rojas-Pierce M Titapiwatanakun B Sohn EJ Fang F Larive CK Blakeslee J Cheng Y Cutler SR Cuttler S Peer WA Murphy AS Raikhel NV 《Chemistry & biology》2007,14(12):1366-1376
ATP-binding cassette (ABC) transporters have been implicated in a multitude of biological pathways. In plants, some ABC transporters are involved in the polar transport of the plant hormone auxin and the gravitropic response. We previously identified Gravacin as a potent inhibitor of gravitropism in Arabidopsis thaliana. We demonstrate that P-glycoprotein19 (PGP19) is a target for Gravacin and participates in its inhibition of gravitropism. Gravacin inhibited the auxin transport activity of PGP19 and PGP19-PIN complexes. Furthermore, we identified E1174 as an important residue for PGP19 activity and its ability to form active transport complexes with PIN1. Gravacin is an auxin transport inhibitor that inhibits PGPs, particularly PGP19, which can be used to further dissect the role of PGP19 without the inhibition of other auxin transporters, namely PIN proteins. 相似文献
109.
Zhang K Cutler JI Zhang J Zheng D Auyeung E Mirkin CA 《Journal of the American Chemical Society》2010,132(43):15151-15153
A novel method for synthesizing polymer nanopods from a linear polymer bearing pendant propargyl ether groups, using gold nanoparticles as both the template and the catalyst for the cross-linking reaction, is reported. The transformations involved in the cross-linking process are unprecedented on the surface of a gold particle. A tentative cross-linking mechanism is proposed. 相似文献
110.
Özek G Ishmuratova M Tabanca N Radwan MM Göger F Özek T Wedge DE Becnel JJ Cutler SJ Can Başer KH 《Journal of separation science》2012,35(5-6):650-660
Gas chromatographic analysis revealed that the oil of Crinitaria tatarica was rich in sabinene (32.1%), β-pinene (8.8%), and two unknown (M+200) compounds (I) and (II) (21.4% and 3.4%). One-step multiple fractionation of the oil and separation of two unknown constituents were performed using preparative capillary gas chromatography connected to preparative fraction collector system. This combination allowed separation and recover of sufficient quantities of two unknown compounds with high purity from complex oil matrix. Separation conditions (column temperature, cooling temperature, flow rate, injection volume, cut time) were optimized to achieve the best isolation and successful collection. The target compounds were separated from the oil using a HP Innowax (Walt & Jennings Scientific, Wilmington, DE, USA) preparative capillary column in rapid one-step manner with 95.0% purity. Trapping of the isolated compounds in collector system was facilitated by cooling with liquid nitrogen. Structure determination was accomplished by spectral analysis including ultraviolet, nuclear magnetic rezonance, and high-resolution electrospray ionization mass spectrometry. Z- (I) and E-artemidin (II) were isolated for the first time from this species. Crinitaria tatarica oil and Z- (I) and E-artemidin (II) were evaluated for biological activity. 相似文献