离子色谱脉冲安培法测定蜂蜜中的葡萄糖、果糖、蔗糖

利用离子色谱脉冲安培检测器对蜂蜜中葡萄糖、果糖、蔗糖的测定方法进行了研究。采用CARBOPAC^TM PAl分离柱和脉冲安培检测器,对淋洗分离条件进行了实验,选择50mmol/L NaOH作淋洗液,可使蜂蜜中的葡萄糖、果糖、蔗糖很好地分离。检出限分别为：葡萄糖2μg/kg,果糖2μg/kg,蔗糖5μg/kg。加标回收率为90％－108％。该方法只需简单的前处理、无基体干扰,分离效果好,测定准确率高,适用于蜂蜜中葡萄糖、果糖、蔗糖的测定。     

基于隐马尔可夫模型的公交乘客出行链识别方法

以公交IC卡数据为基础,结合公交站点周边土地类型及乘客时空转移序列构建隐马尔可夫模型对乘客的出行目的进行识别,继而实现完整乘客公交出行链的提取。采用石家庄某一工作日的公交IC卡数据来实现模型,并与同日期的公交乘客出行调查数据对比,结果表明模型与实际调查结果较为吻合,工作日公交乘客出行链以通勤类出行链为主,总占比达81.87%,通勤活动具有很强的时效性。本文模型为公交IC卡数据的深度研究提供了一定的基础。     

覆盖型岩溶塌陷临界水位降幅模型试验研究

在考虑覆盖型岩溶塌陷各种影响因素的基础上,通过理论分析和室内模型试验,定量化的研究水位下降对岩溶塌陷的影响及其变化规律。结果表明,急剧的水位变化是影响覆盖型岩溶塌陷的重要因素,受覆盖层土体性质、溶洞内气压、溶洞开口大小等因素的影响。提出了水位下降过程中临界水位降幅公式;并以室内模型试验为例,对该公式进行验证评价,计算所得的塌陷临界水位降幅与实际情况符合较好。     

陶瓷非物质文化遗产保护传承中瓷都高校之作用浅析

在产业化大生产以及现代社会追求速食经济的双重影响之下,融合传统手工制瓷工序和传统陶瓷文化的作品已难得一见,对陶瓷非物质文化遗产的保护传承已经迫在眉睫。经过多年教育改革和发展的景德镇地区高校对于保护和传承陶瓷非物质文化遗产具有重要意义,理应有所作为。     

Theoretical studies on the mechanism of acid-promoted hydrolysis of N-formylaziridine in comparison with formamide

[reaction: see text] We present an ab initio study of the acid-promoted hydrolysis reaction mechanism of N-formylaziridine in comparison with formamide. Since the rate of amide hydrolysis reactions depends on the formation of the tetrahedral intermediate, we focused our attention mainly on the reactant complex, the tetrahedral intermediate, and the transition state connecting these two stationary points. Geometries were optimized using the density functional theory, and the energetics were refined using ab initio theory including electron correlation. Solvent effects were investigated by using polarizable continuum method calculations. The proton-transfer reaction between the O-protonated and N-protonated amides was investigated. In acidic media, despite that the N-protonated species is more stable than the O-protonated one, it is predicted that both N-protonated and O-protonated pathways compete in the hydrolysis reaction of N-formylaziridine.     

A novel 2,6-dicarbonylpyridine-based fluorescent chemosensor for Co2+ with high selectivity and sensitivity

A novel fluorescence chemosensor based on 2,6-dicarbonylpyridine was designed and synthesized and its photophysical properties were characterized. Upon coordination of Co(2+) by the central 2,6-dicarbonylpyridinyl functional group, the chemosensor 2,6-bis(4-diphenylamino-styrylcarbonyl)pyridine (PhPy) showed nearly complete fluorescence quenching, while no fluorescence response was seen towards other competing cations. The experimental results show the chemosensor is highly selective and sensitive towards Co(2+) in the presence of competing ions, even in the ppb range. Job plot analysis was carried out and the results suggested that the binding of PhPy and Co(2+) was probably a 2?:?1 stoichiometry.     

Existence of Matrix-Valued Multiresolution Analysis-Based Matrix-Valued Tight Wavelet Frames

In this article, we introduce and study the matrix-valued tight wavelet frames for analyzing matrix-valued signal based on matrix-valued multiresolution analysis (MMRA). We put our emphasis on the existence of the MMRA-based matrix-valued tight wavelet frames by establishing the correspondence with their the unitary extension principle (UEP). Here in particular we introduce the square brackets product and the quasi-interpolatory operator, which makes the certificating process for UEP become relatively simple. Some interesting byproducts, such as features on the quasi-interpolatory operator 𝒫_n in the matrix-valued function space case, are the critical foundation for our main work.     

新型爆炸二极管及其机理研究

针对工业上起爆网路的早爆问题, 设计并研制了一种可控单向传爆的新型爆炸二极管, 通过一系列理论计算以及对称结构正反起爆实验, 研究了该爆炸二极管的正向稳定传爆及反向可靠隔爆机理和限制因素。结果表明：该爆炸二极管可实现正向稳定传爆, 反向可靠隔爆, 二者对应的限制因素分别为激发药药量和延期体长度。理论分析得到的激发药的极限药量和延期体的临界尺寸与实验结果较为吻合。

     

KTP(001)晶体分光性能研究

根据同步辐射光源对软X射线分光晶体的性能要求,分析了软X射线能区常用分光晶体的性能优劣,指出对于晶格常数值大的分光晶体,KTP(KTiOPO₄)(011)是该能区比较理想的分光晶体. 同时提出了一种利用同步辐射光源测量晶体衍射效率的实验方法,指出光源的发散度与晶体的衍射效率密切相关. 测量了KTP(011)晶体的晶格常数,给出了KTP(011)晶体的实测衍射效率. 关键词： 同步辐射 KTP(011)晶体 衍射效率 光源发散度