单重态氧化学VIII.类卟啉稀土配合物光敏化产生单重态氧的ESR研究

用电子自旋共振(ESR)方法研究类卟啉稀土配合物([CO2H-APPC)Gd]Cl2)光敏产生单重态氧的II型机制。利用2,2, 6, 6-四甲基哌啶(TEMP)对单重态氧的捕捉, 测定所生成的氮氧自由基的ESR信号, 经加NaN3和CD3OD的实验, 证实了([CO2H-APPC)Gd]Cl2)光敏作用可有效地产生单重态氧, 并观察到在实验所用的浓度范围内, 随着光敏剂浓度加大, 生成的单重态氧也增加, 同时比较了几种不同稀土离子配合物产生单重态氧的差别。结合氧的消耗和氮氧自由基的ESR线宽变化对氧浓度的依赖性, 证明了类卟啉稀土配合物光敏化生成单态氧的II型反应在光动力光疗中起关键作用。     

Ljunggren 定理的一个应用

运用Ljunggren定理解决了一个有关Smarandache平方余函数的Diophantine方程问题.     

MSM结构GaAs探测器的抗辐照性能

研究一种双金属接触的GaAs半导体探测器在14MeV中子辐照下的性能.测量了探测器经过10¹²n/cm²中子辐照剂量后的反向漏电流、电荷收集效率和最小电离粒子能谱,并且与⁶⁰Co 1.25MeV光子辐照的测量结果相比较.对中子辐照引起探测器时间性能变化和辐照损伤机制进行了探讨.并根据实验结果提出了这种双金属接触GaAs探测器灵敏层分布的一种假设,理论计算和实验数据相符合.     

我国证券市场风险计量模型的构建

证券风险的计量准确与否,是证券组合理论能否有效运用的前提,在现有研究成果的基础上,结合我国证券市场的特点,选取“流通市值”作为影响我国证券风险的第二个因素,建立了证券风险计量模型,并使用统计软件对模型的适用性进行了检验．     

关于Diophantine方程x3+1=Dyn

设D是不能被形如6k+1的素数整除的正整数,文章证明了:方程X3+1=Dyn仅当D=20时 有正整数解(x,y,n)=(19,7,3)适合x>1以及n>2。     

X光图像增强处理的研究

X线图像有很宽的动态范围,而人眼不能分辨这样微小灰度的差别。为了提高组织结构细节的显示,文中提出了一种自适应的直方图均衡算法,实验证明,该算法能够有效的提高图像的对比度,同时抑制噪声的放大。     

关于Euler一致型方程x2-D1y2=2s2和x2-D2y2=-2t2

设D1,D2是无平方因子正奇数.证明了:当D2 ±1(mod 8)或D2 1,3(mod 8),则方程组x2-D1y2=2s2和x2-D2y2=-2t2没有本原整数解(x,y,s,t).     

Calculation of α decay half-lives for superheavy elements using the double folding model＊

α decay half-lives of some new synthesized superheavy elements, possibly synthesized superheavy elements and decay products are calculated theoretically within the WKB approximation by using microscopic α-nucleus interaction potentials. These nuclear potentials between the α particle and daughter nuclei are obtained by using the double folding integral of the matter density distribution of the α particle and daughter nuclei with a density-dependent effective nucleon-nucleon interaction, in which the zero-range exchange term is supplemented. The calculated α decay half-lives are compared with those of the different models and experimental data. It is shown that the present calculation successfully provides the half-lives of the observed decays for some new superheavy elements and therefore gives reliable predictions for α decay of possibly synthesized superheavy elements in future experiments.     

Synthesis, Characterization, Crystal Structure and Stability of a Ternary Cu(Ⅱ) complex with 1,10-Phenanthroline and L-Valinate

Introduction It is important to research the mixed-ligand copper complexes containing bioligands,such as amino acids, nucleic acids and proteins,in exploring the functional mechanism of microelement copper in organism because the reaction of any micronutrient with two or more bioligands in the concentrated bioligands background gives mixed-ligand ternary complexes, which are more stable[1]and related with storage of substance and transportation of metal ions in the life process.     

GC-MS分析氧化亚铁硫杆菌培养液的挥发性成分

GC- MS联用技术对耐强辐射微生物氧化亚铁硫杆菌 [Thiobacillus ferroxidans(T.f) ]的挥发性代谢产物进行了研究 ,发现 4 3种代谢物 ,由标准谱图鉴定了其中 2 3种化合物。