Facile one-step synthesis of a thia-bridged bis-1,10-phenanthroline macrocycle

An efficient one-pot synthesis of a macrocyclic ligand, consisting of two 1,10-phenanthroline nuclei bridged by sulfur, is described. A spectrophotometric investigation reveals the isolated compound to be the mono-trifluoroacetate salt. Symmetrical NH- and S-bridged tetradentate ligands were also synthesized by the new method.     

Periodic solutions of a second order forced sublinear differential equation with delay

In this paper, existence criteria are established for the existence of periodic solutions of a second order sublinear differential equation with delay and forcing function. Our method is based on careful a priori estimation and continuation theorems, and our sublinear condition is an improvement of the boundedness condition in some recent results.     

Optimal shape design for packaging containing heating elements by inverse heat transfer method

The present study is concerned with the determination of the optimal shape for a package containing multiple heating elements. The optimization tool has been developed based on the inverse heat transfer (IHT) approach, incorporating a direct problem solver, a numerical grid generator, a direct-differentiation sensitivity analyzer, and the conjugate gradient method. Shape design that leads to a specified outer surface temperature distribution is predicted by the approach. In this study, the effects of internal heat generation on optimal shapes of the packagings have also been evaluated. Several practical cases with various imbedded heating elements and thermal conditions are studied. Results show that the approach provides an efficient computer-aided design scheme for the shape profile determination.     

Two-function upward-downward minimax theorems

Two-function upward-downward minimax theorems are derived which contain Simons upward-downward minimax theorem as well as Domokos minimax theorem as special cases. Here the convexity assumptions on two functions are given by mixing up their values as means proposed by Lin and Quan.     

浅谈铁路运输实践课的教学

通过对铁路车站行车工作细则业务的系统分析和对铁路运输生产和组织管理的理论研究表明:铁路运输实践课为铁路运输专业学生提供了理论联系实际的平台,对培养学生独立分析和解决铁路行车方案问题的能力有着重要的意义。     

KxCoO2·yH2O(x《0.2,y≤0.8)的晶体结构、输运及磁学性质

利用熔融KOH和Co3O4在较低温度(480℃)下反应制备出K0.36CoO2,然后用高锰酸钾溶液和饱和的过硫酸钾溶液进行氧化处理.氧化的同时伴随有水分子嵌入.K0.36CoO2用高锰酸钾和过硫酸钾溶液处理后分别得到K0.12CoO2·0.8H2O和K0.16CO2·0.6H2O.这两种化合物都属于六角晶系,表现出金属行为,脱水后主相变为正交结构并且呈现出半导体特性.K0.16CoO2·0.6H2O在56K附近可能存在自旋玻璃转变行为或其他涨落.随着钾含量的减少和水含量的增多,样品的自旋玻璃行为受到抑制或发生磁性相分离.样品K0.12CoO2·0.8H2O在零场冷却和有场冷却曲线上的分叉现象基本上消失.还讨论了产生KxCoO2与NaxCoO2体系结构和物性差别的原因.     

35Cr25Ni12奥氏体耐热钢中碳化物的电子显微分析

应用扫描电镜（SEM）和透射电镜（TEM）研究了长期使用前后的35Cr25Ni12奥氏体耐热钢中的碳化物演变行为；该钢固溶时效后的组织由初晶奥氏体及M23C6共晶碳化物组成，奥氏体基体中析出了二次M23C6，二次碳化物总是与基体保持立方－立方取向关系；长期使用（3、5年）后，奥氏体中析出的二次碳化物量明显增加，部分M23C6已转变为M6C，M6C与奥氏体基体以及二次碳化物M23C6保持[001]M6C//[221]A//[221]M23C6孪晶取向关系。     

我国国内旅游需求影响因素分析及规模预测

近20年来我国国内旅游业发展之所以形成高潮,一方面由于我国实行改革开放的结果,而另一方面更在于近年我国居民可支配收入和闲暇时间的增多.2003年上半年,中国旅游业遭受SARS的沉重打击,2003年下半年国内旅游业经历了迅速恢复期,2004年已经表现出很强的增长势头.就影响我国国内旅游业发展的主要因素进行分析,并对未来五年我国国内旅游发展规模进行预测.     

CVC轧机的应用及技术问题分析

文章主要分析了CVC轧机的板形控制原理,应用中轴向力、磨损、轧辊热凸度及设备结构等技术问题。