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661.
3族新的不含紧优与几乎紧优的有向双环网络无限族 总被引:2,自引:0,他引:2
给出了3族新的不含紧优与几乎紧优的有向双环网络. 相似文献
662.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
663.
Hydroxyapatite coating on porous silicon substrate obtained by precipitation process 总被引:2,自引:0,他引:2
Chen Shaoqiang Zhu Ziqiang Zhu Jianzhong Zhang Jian Shi Yanling Yu Ke Wang Weiming Wang Xiaohua Feng Xiao Luo Laiqiang Shao Li 《Applied Surface Science》2004,230(1-4):418-424
Hydroxyapatite Ca10(PO4)6(OH)2 (HAP) is known as a bioactive and biocompatible material, HAP coatings were used to improve the biocompatible of substrate by many researcher, In this work, HAP thin films on porous silicon (PS) substrates have been prepared by aqueous precipitation method with rapid thermal annealing (RTA) processes. The HAP films had been prepared under the annealing temperature ranging from 300 to 1000 °C. By the measurement of X-ray diffraction (XRD), it was found that for the crystallinity optimization, the heat-treatment at 850–950 °C for 1 h would be favorable. Atomic force microscopy (AFM) and scanning electron microscope (SEM) measurements reveal a dense and smooth surface of the HAP film, and tightly adherence of the coating on porous silicon substrate after sintered. Thus, by this method, porous silicon could be increased its bioactivity and so that could be used in the biomedical area. 相似文献
664.
Renhe Chu Jichang Yan Suoyuan Lian Yuehong Wang Fucheng Yan Dawei Chen 《Solid State Communications》2004,130(12):789-792
The interesting shape (shuttle-like, sphere with needles, uniform particles) rutile titania were prepared by the hydrolysis of TiCl4 in high acidic aqueous solution in the absence or presence of PEG-1000. PEG-1000 acted as dispersant, which could control the shape and size of the precipitate of titania. As a result, shuttle-like nanocrystalline appeared and the aggregation was improved with the increase of the amount of acid and the decrease of the concentration of TiCl4 in the absence of PEG-1000. Uniform nanoparticles were obtained in the presence of PEG-1000 and the diameter of the particles decreased with increasing the amount of PEG-1000. This process simplification will lower production cost and make continuous process possible. The products were analyzed using X-ray diffractometer, transmission electron microscopy. 相似文献
665.
用方差定义的激光束横向尺寸,有着普适、简单和便于利用光学元件并行运算功能的特点.本文提出一种借助改变柱形容器内吸收液浓度来直接测量各种波长激光束横向尺寸的理论和方法. 相似文献
666.
利用带约束的Kantorovich不等式获得了一般Gauss-Markov和方差分量模型中最小二乘的相对效率的下界.这些下界比采用无约束的Kantorovich不等式得到的下界更好 相似文献
667.
描述了Laminin五肽(YIGSR)对胃癌细胞系MGc-803的体外抑制作用,在多肽浓度为1mg/ml时抑制率高达73%.抑制作用的机理可能是Laminin五肽竞争了肿瘤细胞上Laminin受体,从而封闭了肿瘤细胞对基底膜的结合及增殖.因此,利用Laminin五肽一类的药物有可能为肿瘤术后防止扩散提供一个新方法. 相似文献
668.
The mode coupling in a helical fibre with a circular cross-section undergoing perturbations is investigated in the Serret-Frenet frame. The coupled-mode equations have been derived and are compared with the conventional ones. Applying the coupled-mode equations to a helical fibre with an elliptical core deformation, we obtained, for the first time, a rigorous analysis of the transmission characteristics of the fibre. The numerical examples show that the mode ellipticity and elliptical birefringence increase as the core ellipticity increases and also vary as the pitch or the core offset change. 相似文献
669.
常压催化加氢合成邻氨基苯酚的研究 总被引:1,自引:0,他引:1
用硅溶胶改性的漆原镍催化剂,在常压液相催化条件下,氢化邻硝基苯酚制备邻氨基苯酚的反应过程,可分为诱导期、恒速吸氢阶段、吸氢衰减期3个反应阶段.恒速吸氢阶段的吸氢速率为5×102mol/(kg·min)且与体系的温度无关,诱导期随温度的增加而变短,吸氢衰减期的长短随溶剂量的变化而变化.实验结果表明,邻氨基苯酚的收率在95%左右. 相似文献
670.
AN EFFECTIVE APPROACH FOR TWO-DIMENSIONAL POLARONS IN AN ASYMMETRIC QUANTUM DOT 总被引:1,自引:0,他引:1 下载免费PDF全文
Within the framework of Feynman-Haken path integral theory, we calculate the ground-state energy of two-dimensional polarons in asymmetric quantum dots for arbitrary electron-phonon coupling constants. From a general three-dimensional Hamiltonian, some interesting problems, such as polarons in quasi-one-dimensional quantum wires and quasi-zero-dimensional asymmetric or symmetric quantum dots can be easily discussed only by taking different limit in the whole coupling regime. After the numerical calculation, we find that the relative polaronic correction increases monotonically with the decrease of effective dot size, and it becomes more pronounced with increasing dimension and asymmetry. Moreover, despite the insensitivity of relative polaronic enhancement to the variation of coupling constant at weak coupling, the correction is related to the coupling constant as the latter becomes larger. 相似文献