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961.
Dr. Chi‐Ming Ho Chi‐Kit Wong Dr. Sammi King‐Woon Yau Dr. Chun‐Nam Lok Prof. Chi‐Ming Che 《化学:亚洲杂志》2011,6(9):2506-2511
We have recently reported a kinetic and mechanistic study on oxidative dissolution of silver nanoparticles (AgNPs) by H2O2. In the present study, the parameters that govern the dissolution of AgNPs by O2 were revealed by using UV/Vis spectrophotometry. Under the same reaction conditions (Tris‐HOAc, pH 8.5, I=0.1 M at 25 °C) the apparent dissolution rate (kapp) of AgNPs (10±2.8 nm) by O2 is about 100‐fold slower than that of H2O2. The reaction rate is first‐order with respect to [Ag0], [O2], and [Tris]T, and inverse first‐order with respect to [Ag+] (where [Ag0]=total concentration of Ag metal and [Tris]T=total concentration of Tris). The rate constant is dependent on the size of AgNPs. No free superoxide (O2−) and hydroxyl radical (⋅OH) were detected by trapping experiments. On the basis of kinetic and trapping experiments, an amine‐activated pathway for the oxidation of AgNPs by O2 is proposed. 相似文献
962.
Luo X Liu Y Kubicek S Myllyharju J Tumber A Ng S Che KH Podoll J Heightman TD Oppermann U Schreiber SL Wang X 《Journal of the American Chemical Society》2011,133(24):9451-9456
Histone methylations are important chromatin marks that regulate gene expression, genomic stability, DNA repair, and genomic imprinting. Histone demethylases are the most recent family of histone-modifying enzymes discovered. Here, we report the characterization of a small-molecule inhibitor of Jumonji C domain-containing histone demethylases. The inhibitor derives from a structure-based design and preferentially inhibits the subfamily of trimethyl lysine demethylases. Its methyl ester prodrug, methylstat, selectively inhibits Jumonji C domain-containing his-tone demethylases in cells and may be a useful small-molecule probe of chromatin and its role in epigenetics. 相似文献
963.
针对仅以地震波作用中最后时刻或加速度值最大时刻的安全系数作为评价标准的问题,通过强度折减法,借助数值计算获得了地震载荷作用下安全系数的时程曲线。对于使用有限元强度折减法的失效准则,采用三种常用判据相结合的方法来确定安全系数,通过不同模型计算结果的比较,研究了动安全系数与动载荷时程和结构面数量之间的关系。计算结果表明:含结构面的岩质边坡最小安全系数出现时刻较地震波减速度最大值时刻超前,且结构面的存在对于边坡稳定性有着重要影响。最后分析了地震载荷作用下坡高、坡度、结构面倾角对动安全系数的影响,应用极限平衡理论部分验证了数值计算结果,所得安全系数时程曲线可为岩质边坡在地震载荷下的稳定性判断提供参考。 相似文献
964.
Zal?U’yun?Wan?MahmoodEmail author Che?Abd.?Rahim?Mohamed Abdul?Kadir?Ishak Nita?Salina?Abu?Bakar Kamaruzzaman?Ishak 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(3):953-959
Marine sediment cores were collected from two stations at East Malaysia coastal waters on June 2004. Activity concentrations
of 210Pb in sediment core were ranged from 11 Bqkg−1 to 84 Bqkg−1 dry wt. for SR 01 and 4 Bqkg−1 to 66 Bqkg−1 dry wt. for SB 03. Meanwhile, activity concentrations of 226Ra in sediment core were varied significantly depending on the sampling location of SR 01 and SB 03 with ranged 17–26 Bqkg−1 dry wt. and 8–11 Bqkg−1 dry wt., respectively. The activity ratios of 210Pb/226Ra were no significantly different at all sampling stations with an average of 1.78. Refer to the entire results; the activities
of 210Pb and 226Ra were higher at station SR 01 than station SB 03, but contrast with ratio of 210Pb/226Ra. The reasons of different 210Pb and 226Ra activity concentration and distribution of their ratios were strictly related to their half lives, environment origin,
potential sources and behavior. 相似文献
965.
Sheng Ouyang Lei Wang Qing-Wen ZhangGuo-Cai Wang Ying WangXiao-Jun Huang Xiao-Qi ZhangRen-Wang Jiang Xin-Sheng YaoChun-Tao Che Wen-Cai Ye 《Tetrahedron》2011,67(26):4807-4813
Six new monoterpenoid indole alkaloids along with four known analogues were isolated from the aerial part of Gelsemium elegans. Their structures with absolute configurations were elucidated by NMR, HRESIMS, X-ray diffraction, CD spectra, and molecular modeling calculation. Among them, gelselenidine (1) is a new gelsedine-type alkaloid with a 2,3-epoxybutane unit. Gelseziridine (2) is the first example of monoterpenoid indole alkaloids with an oxaziridine residue. Compounds 6 and 7 are a pair of N4 epimers of humantenine N4-oxide. A plausible biogenetic pathway for compounds 1-4 was also proposed. 相似文献
966.
Lin H Liu H Qian X Lai SW Li Y Chen N Ouyang C Che CM Li Y 《Inorganic chemistry》2011,50(16):7749-7753
We described a new structure photodetector, which is constructed by p-n heterojunction nanowire arrays of PANI (polyaniline)/CdS. The nanowire arrays exhibit excellent rectifying features and a diode nature and show a sensitive spectral response to blue light under 420 nm. The rectification ratio plots of different illumination intensities show straight line behavior, implying that the quantitative detection of illumination intensity can be achieved. The p-n heterojunction nanowire array is a great candidate for applications in high-sensitivity and high-speed blue light photodetectors. 相似文献
967.
Xiu Hui Lu Xin Che Jun Feng Han Le Yi Shi Zhen Xia Lian 《International journal of quantum chemistry》2011,111(10):2306-2310
The mechanism of the oxide extraction reaction between singlet silylene carbene and its derivatives [X2Si = C: (X = H, F, Cl, CH3)] and ethylene oxide has been investigated with density functional theory, including geometry optimization and vibrational analysis for the involved stationary points on the potential energy surface. The energies of the different conformations are calculated by B3LYP/6‐311G(d,p) method. From the potential energy profile, it can be predicted that the reaction pathway of this kind consists two steps, the first step is the two reactants firstly form an intermediate (INT) through a barrier‐free exothermic reaction; the second step is the INT then generates a product via a transition state (TS). This kind reaction has similar mechanism, when the silylene carbene and its derivatives [X2Si = C: (X = H, F, Cl, CH3)] and ethylene oxide close to each other, the shift of 2p lone electron pair of O in ethylene oxide to the 2p unoccupied orbital of C in X2Si = C: gives a p → p donor–acceptor bond, thereby leading to the formation of INT. As the p → p donor–acceptor bond continues to strengthen (that is, the C? O bond continues to shorten), the INT generates product (P + C2H4) via TS. It is the substituent electronegativity, which mainly affects the extraction reactions. When the substituent electronegativity is greater, the energy barrier is lower, and the reaction rate is greater. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
968.
Sildenafil analogues have been found adulterated in herbal preparations and food products that claim to have natural aphrodisiacs. In this study, a gas chromatography-mass spectrometry (GC-MS) assay was developed for the screening and identification of thioketone analogues of sildenafil. Thiopyrazolopyrimidine, a precursor or a cleavage product of thioketone analogue, exhibited characteristic fragment ions of m/z 328 and m/z 299 was found to be the best marker to screen the presence of general thioketone analogues. Identification by GC-MS assay was rapid and specific as all the studied thioketones showed characteristic mass fragmentations including their intact molecular ions. The developed GC-MS assay had successfully identified thiosildenafil, thiohomosildenafil and thiodimethylsildenafil in herbal preparation and food products. 相似文献
969.
T. Toliński G. Che?kowskaM. Falkowski A. Kowalczyk 《Journal of magnetism and magnetic materials》2011,323(12):1678-1681
The compounds Ce(Cu1−xNix)4Ga crystallize in the hexagonal CaCu5-type structure for the whole doping range 0≤x≤1. The border compounds CeCu4Ga and CeNi4Ga represent a heavy fermion and fluctuating valence systems, respectively. We report on the studies of the valence evolution in Ce(Cu1−xNix)4Ga employing the X-ray photoemission spectroscopy (XPS) and magnetic susceptibility measurements. The photoemission of the Ce 3d peaks shows a gradual decrease of the occupation of the f states with Ni content. Simultaneously, the hybridization strength and the low temperature magnetic susceptibility are reduced. Within the valence band spectrum a transition from the dominance of the Cu 3d to the dominance of the Ni 3d states is well visible with the traces of the Ce 4f1 states for up to x=0.5. 相似文献
970.
Przemys?aw Che?miniak 《Physics letters. A》2011,375(35):3114-3118
The time course of random processes usually differs depending on the topology of complex networks which are a substrate for the process. However, as this Letter demonstrates, the first-return as well as the survival probabilities for random walks on the scale-free (SF) trees decay in time according to the same invariant power-law behavior. This means that both quantities are independent of the node power-law degree distributions which are distinguished by different scaling exponents. It is also shown here that the crucial property of the networks, affecting the dynamics of random walks, is their tree-like topology and not SF architecture. All analytical results quantifying these predictions have been verified through extensive computer simulations. 相似文献