[Cu(DPPZ)(L-Ser)]+与DNA的相互作用及其分析应用研究

研究了DNA与铜(Ⅱ)-L丝氨酸-二吡啶并[3,2-a:2',3'-c]吩嗪配合物[Cu(DPPZ)(L-Ser)-]+相互作用的共振光散射光谱和紫外可见吸收光谱,通过研究体系与溴化乙啶相互作用的荧光光谱特征,证明其作用方式为插入作用.在pH 7.2的缓冲溶液中,[Cu(DPPZ)(L-Ser)]+由于插入作用而在DNA表面聚集,使体系的共振光散射强度增强,最大敞射峰在400 nm处.在最佳实验条件下,共振光散射增强的强度与浓度在0.42～4.20 ng·mL1范围的DNA具有良好的线性关系.方法的检出限为0.29 ng·mL-1.该法用于DNA样品的测定,回收率在97.8%～106.0%之间.     

线-板式脉冲电晕放电反应器的发射光谱研究

以发射光谱法为基础,检测了常压状态线-板式脉冲电晕放电过程OH自由基在反应器内的空间分布;研究了线电极直径,线线间距以及线板间距对生成OH自由基的影响;从而明确脉冲电晕放电反应器的性能。结果显示:OH自由基浓度沿线电极X轴方向逐渐降低,活化区域半径20mm左右,沿Y轴方向先升高后降低,活化区域半径大于30mm;线电极的直径小于2mm时,OH自由基的光谱强度基本不变,线电极直径继续增大,发射光谱强度随之迅速下降。线线间距逐渐增大,OH自由基的发射光谱强度随之增强。OH自由基的发射光谱强度随着线板间距的增大而降低。     

An almost second order uniformly convergent scheme for a singularly perturbed initial value problem

In this paper a nonlinear singularly perturbed initial problem is considered. The behavior of the exact solution and its derivatives is analyzed, and this leads to the construction of a Shishkin-type mesh. On this mesh a hybrid difference scheme is proposed, which is a combination of the second order difference schemes on the fine mesh and the midpoint upwind scheme on the coarse mesh. It is proved that the scheme is almost second-order convergent, in the discrete maximum norm, independently of singular perturbation parameter. Numerical experiment supports these theoretical results.     

Stabilized quantum coherence and remote state preparation in structured environments

The radiation decay of a two-level atom could be inhibited within structured environments even under longtime evolution. We investigate the stabilized quantum coherence of composite systems undergoing local dissipation and exploit it further as a resource for remote state preparation. We focus on outputs of quantum states with solely quantum discord (i.e., without entanglement) and demonstrate that they could be resulted from various initial states providing specific spectral structure of the reservoir. In detail, we elaborate the behavior of stabilized quantum discord and the corresponding fidelity for remote state preparation in connection with structural spectra of Ohmic class reservoir and of photonic band gap mediums.     

Perturbation solution to heat conduction in melting or solidification with heat generation

The Stefan problem involving a source term is considered in this technical note. As an example, planar solidification with time-dependent heat generation in a semi-infinite plane is solved by use of a perturbation technique. The perturbation solution is validated by reducing the problem to the case without heat generation whose exact solution is available. An application to the case with constant heat generation is presented, for which a closed-form solution is obtained. The effects of heat generation and Stefan number on the evolution of solidification are examined using the perturbation solution.     

四阶奇异摄动边值问题在自适应网格上的一致收敛分析

we study a difference scheme for the fourth-order singular pertur-bation differential equation on the Bakhvalov-Shishkin grid by Green‘‘s function.The method is shown to be uniformly convergent with respect to the perturbation parameter,of order N^-2 in the maxmum norm on Bakhvalov-Shishkin meshes.Numerical results support our theoretical results.     

广西白蜡生产失败原因剖析

广西白蜡生产失败的主要原因是，首先，年降雨量超过１５５２ｍｍ，间接或直接地引起大批白蜡虫死亡；其次，对白蜡虫具有毁灭性的白蜡虫寄生蜂不采取任何防治措施，致使种虫寄生率高达９２．９％。因此，白蜡生产遭受失败。广西气候多种多样，年降雨量、在１５５２ｍｍ以下有２２个县，发展白蜡生产是有潜力的，可逐步恢复和发展白蜡生产。     

气体示踪法研究燃烧器横向湍流混合扩散特性

用气体示踪法对侧边风燃烧器弱旋流一次风和侧边直流二次风横向湍流混合扩散特性进行了详细研究，讨论了各截面混合物浓度分布规律及混合强度分布规律，分析对燃料着火的影响，同时利用湍流运动方程反算气体湍流扩散系数     

Textile/Metal–Organic‐Framework Composites as Self‐Detoxifying Filters for Chemical‐Warfare Agents

The current technology of air‐filtration materials for protection against highly toxic chemicals, that is, chemical‐warfare agents, is mainly based on the broad and effective adsorptive properties of hydrophobic activated carbons. However, adsorption does not prevent these materials from behaving as secondary emitters once they are contaminated. Thus, the development of efficient self‐cleaning filters is of high interest. Herein, we report how we can take advantage of the improved phosphotriesterase catalytic activity of lithium alkoxide doped zirconium(IV) metal–organic framework (MOF) materials to develop advanced self‐detoxifying adsorbents of chemical‐warfare agents containing hydrolysable P? F, P? O, and C? Cl bonds. Moreover, we also show that it is possible to integrate these materials onto textiles, thereby combining air‐permeation properties of the textiles with the self‐detoxifying properties of the MOF material.