光学导引系统的建模与仿真

在整个定点着舰过程中，飞机着舰下滑阶段的操纵难度和危险系数都是最高的，如何解决光学导引仿真中模型的准确度和视景特效的逼真度。是定点着舰仿真应用的重中之重。为了解决上述问题，根据光学导引秉统成像原理以及飞机、舰之间的几何关系，实时计算光学下滑道，建立了仿真平台的数学模型，并给出了状态方程。在基于VP平台的视景系统中，采用“立体光面”和动态缩放光晕的方法建立菲涅尔助降灯阵和迎角指示器的模型，保证了模拟着舰过程中飞行员视觉的逼真度。以美F-16飞机模型，进行了多次计算机仿真着舰，试验数据表明：在理想条件下光学导引仿真平台模型正确可信，飞行员着舰质量明显提高，能够起到导引着舰的作用。     

Efficient inverse radiation analysis of temperature distribution in participating medium based on backward Monte Carlo method

An efficient numerical inverse radiation analysis based on the backward Monte Carlo (BMC) method is presented to determine the three-dimensional (3-D) temperature distribution in a large rectangular enclosure containing the participating medium, using radiative intensities in the visible range received by charge-coupled device (CCD) cameras. For large radiative sources and small detectors, when the radiation onto a small spot and onto a small direction cone is desired, the BMC method is more efficient than the forward Monte Carlo (FMC) method. Because the temperature reconstruction from the measured radiative intensities is an ill-posed inverse problem, least-square QR decomposition (LSQR) method is introduced to determine the meaningful temperature distribution. In order to gain insight into the effects on the accuracy of temperature distribution reconstruction, the detailed analyses are made using numerical simulations. The results show that the temperature distribution can be reconstructed accurately for the exact and noisy data.     

Characterization and catalytic behavior of silica-supported copper catalysts prepared by impregnation and ion-exchange methods

Two kinds of Cu/SiO₂ catalysts were prepared by impregnation (IM) and ion-exchange (IE) methods, and tested in dehydrogenation of 2-butanol to methyl-ethyl-ketone. Some kinds of Cu²⁺ on the IE catalyst could not be reduced during the reaction, and it produced the butene. The copper oxide over the IM catalyst could be reduced during the reaction, and showed stable dehydrogenation activity for 2-butanol.     

B超探头压放试验诊断脐带绕颈的价值

目的评价B超探头压放试验诊断脐带绕颈的价值。方法将127例经B超探头压放试验诊断为脐带绕颈的病例行彩色多普勒超声复查，并对结果进行比较分析。结果127例经B超探头压放试验诊断为脐带绕颈的病例中经彩色多普勒超声证实为脐带绕颈的有125例，诊断准确率为98.4%。结论B超探头压放试验能准确诊断胎儿脐带绕颈，为尚未普及彩色多普勒超声的医院的临床医生制定治疗方案提供了可靠依据，有助于降低围产儿死亡率。     

Geometrically nonlinear analysis with a 4-node membrane element formulated by the quadrilateral area coordinate method

Recently, a 4-node quadrilateral membrane element AGQ6-I, has been successfully developed for analysis of linear plane problems. Since this model is formulated by the quadrilateral area coordinate method (QACM), a new natural coordinate system for developing quadrilateral finite element models, it is much less sensitive to mesh distortion than other 4-node isoparametric elements and free of various locking problems that arise from irregular mesh geometries. In order to extend these advantages of QACM to nonlinear applications, the total Lagrangian (TL) formulations of element AGQ6-I was established in this paper, which is also the first time that a plane QACM element being applied in the implicit geometrically nonlinear analysis. Numerical examples of geometrically nonlinear analysis show that the presented formulations can prevent loss of accuracy in severely distorted meshes, and therefore, are superior to those of other 4-node isoparametric elements. The efficiency of QACM for developing simple, effective and reliable serendipity plane membrane elements in geometrically nonlinear analysis is demonstrated clearly.     

A second-order difference scheme for a parameterized singular perturbation problem

In this paper we consider a singularly perturbed quasilinear boundary value problem depending on a parameter. The problem is discretized using a hybrid difference scheme on Shishkin-type meshes. We show that the scheme is second-order convergent, in the discrete maximum norm, independent of singular perturbation parameter. Numerical experiments support these theoretical results.     

Ferric nitrate-catalyzed aerobic oxidation of benzylic sp3 CH bonds of ethers and alkylarenes

A simple catalytic oxidation system was developed for the selective aerobic oxidation of structurally diverse benzylic sp³ CH bonds of ethers and alkylarenes. The reactions were performed with Fe(NO₃)₃·9H₂O as the catalyst, KPF₆ as the additive and molecular oxygen as the terminal oxidant without any ligands. Under the optimal reaction conditions, a number of isochromans, xanthenes and thioxanthenes can be converted to their corresponding esters or ketones in good to excellent yields.     

[Cu(DPPZ)(L-Ser)]+与DNA的相互作用及其分析应用研究

研究了DNA与铜(Ⅱ)-L丝氨酸-二吡啶并[3,2-a:2',3'-c]吩嗪配合物[Cu(DPPZ)(L-Ser)-]+相互作用的共振光散射光谱和紫外可见吸收光谱,通过研究体系与溴化乙啶相互作用的荧光光谱特征,证明其作用方式为插入作用.在pH 7.2的缓冲溶液中,[Cu(DPPZ)(L-Ser)]+由于插入作用而在DNA表面聚集,使体系的共振光散射强度增强,最大敞射峰在400 nm处.在最佳实验条件下,共振光散射增强的强度与浓度在0.42～4.20 ng·mL1范围的DNA具有良好的线性关系.方法的检出限为0.29 ng·mL-1.该法用于DNA样品的测定,回收率在97.8%～106.0%之间.     

线-板式脉冲电晕放电反应器的发射光谱研究

以发射光谱法为基础,检测了常压状态线-板式脉冲电晕放电过程OH自由基在反应器内的空间分布;研究了线电极直径,线线间距以及线板间距对生成OH自由基的影响;从而明确脉冲电晕放电反应器的性能。结果显示:OH自由基浓度沿线电极X轴方向逐渐降低,活化区域半径20mm左右,沿Y轴方向先升高后降低,活化区域半径大于30mm;线电极的直径小于2mm时,OH自由基的光谱强度基本不变,线电极直径继续增大,发射光谱强度随之迅速下降。线线间距逐渐增大,OH自由基的发射光谱强度随之增强。OH自由基的发射光谱强度随着线板间距的增大而降低。     

An almost second order uniformly convergent scheme for a singularly perturbed initial value problem

In this paper a nonlinear singularly perturbed initial problem is considered. The behavior of the exact solution and its derivatives is analyzed, and this leads to the construction of a Shishkin-type mesh. On this mesh a hybrid difference scheme is proposed, which is a combination of the second order difference schemes on the fine mesh and the midpoint upwind scheme on the coarse mesh. It is proved that the scheme is almost second-order convergent, in the discrete maximum norm, independently of singular perturbation parameter. Numerical experiment supports these theoretical results.